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Kaur Navneet Jindal Neeru Singh Kulbir 《Multimedia Tools and Applications》2020,79(43-44):32037-32063
Multimedia Tools and Applications - With the technology progress, a plethora of freely accessible software has questioned the authenticity of digital images. This field is continuously creating... 相似文献
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A.R. Jayakrishnan Kevin V. Alex Athul Thomas J.P.B. Silva K. Kamakshi Navneet Dabra K.C. Sekhar J. Agostinho Moreira M.J.M. Gomes 《Ceramics International》2019,45(5):5808-5818
This work reports the composition dependent microstructure, dielectric, ferroelectric and energy storage properties, and the phase transitions sequence of lead free xBa(Zr0.2Ti0.8)O3-(1-x)(Ba0.7Ca0.3)TiO3 [xBZT-(1-x)BCT] ceramics, with x?=?0.4, 0.5 and 0.6, prepared by solid state reaction method. The XRD and Raman scattering results confirm the coexistence of rhombohedral and tetragonal phases at room temperature (RT). The temperature dependence of Raman scattering spectra, dielectric permittivity and polarization points a first phase transition from ferroelectric rhombohedral phase to ferroelectric tetragonal phase at a temperature (TR-T) of 40?°C and a second phase transition from ferroelectric tetragonal phase - paraelectric pseudocubic phase at a temperature (TT-C) of 110?°C. The dielectric analysis suggests that the phase transition at TT-C is of diffusive type and the BZT-BCT ceramics are a relaxor type ferroelectric materials. The composition induced variation in the temperature dependence of dielectric losses was correlated with full width half maxima (FWHM) of A1, E(LO) Raman mode. The saturation polarization (Ps) ≈8.3?μC/cm2 and coercive fields ≈2.9?kV/cm were found to be optimum at composition x?=?0.6 and is attributed to grain size effect. It is also shown that BZT-BCT ceramics exhibit a fatigue free response up to 105 cycles. The effect of a.c. electric field amplitude and temperature on energy storage density and storage efficiency is also discussed. The presence of high TT-C (110?°C), a high dielectric constant (εr ≈?12,285) with low dielectric loss (0.03), good polarization (Ps ≈?8.3?μC/cm2) and large recoverable energy density (W?=?121?mJ/cm3) with an energy storage efficiency (η) of 70% at an electric field of 25?kV/cm in 0.6BZT-0.4BCT ceramics make them suitable candidates for energy storage capacitor applications. 相似文献
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The present study reports the preparation and application of a novel biopolymer-based composite hydrogel (BCH) for removal of synthetic dye rhodamine 6G (Rh6G). BCH was prepared from biopolymer chitosan and acrylic acid monomer, in the presence of initiator (K2S2O8) and cross-linker thiourea using microwave irradiation. Synthesized chitosan-based composite hydrogel was characterized by using analytical techniques including Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), derivative thermogravimetric analysis (DTA) and differential thermal analysis (DTG). The stability of the adsorbent was demonstrated from its water uptake capacity. The dynamics of water sorption study showed the Fickian behavior. The investigations were continued to assess the adsorption potential of BCH for removal of Rh6G from aqueous solution. The effect of process parameters affecting the adsorption of rhodamine 6G (Rh6G), such as adsorbent dose, initial concentration of pollutant, contact time and pH of the solution was evaluated. Removal efficiency of chitosan-based composite hydrogel (BCH) was found to be 87.31% at pH 7 for BCH dose of 1 g/L after 8 h. The obtained data were fitted to adsorption isotherms and kinetics models. The adsorption equilibrium isotherm and kinetics studies indicated that the pseudo-second-order model and the Freundlich model well described the adsorption equilibrium of Rh6G on BCH. 相似文献
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The dielectric properties of Mg substituted Ni-Li spinel ferrites synthesized by sol-gel auto combustion process have been studied using impedance measurements in the frequency range from 10 Hz to 10 MHz and in the temperature range from 310 K to 473 K. The effect of frequency, temperature and composition on dielectric constant (?′), dielectric loss (tan δ) and conductivity (σ) has been discussed in terms of hopping of charge carriers between Fe2+ and Fe3+ ions. The electrical modulus formulism has been employed to study the relaxation dynamics of charge carriers and the results indicate the presence of non-Debye type of relaxation in the present ferrites. Similar values of activation energies for dc conduction (Edc) and for conductivity relaxation (EM″) reveal that the mechanisms of electrical conduction and dielectric polarization are same in these ferrites. A single ‘master curve’ for normalized plots of all the modulus isotherms observed for a given composition indicates the temperature independence of dynamical process for charge carriers. The saturation magnetization and coercivity have been calculated from the hysteresis loop measurements and show striking dependence on the composition. 相似文献
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Pooja Sarotra Gayatri Sharma Shevali Kansal Anjana Kumari Negi Ritu Aggarwal Rajat Sandhir Navneet Agnihotri 《Lipids》2010,45(9):785-798
n-3 Polyunsaturated fatty acids (PUFA) have a chemopreventive effect while n-6 PUFA promote carcinogenesis. The effect of
these essential fatty acids may be related to oxidative stress. Therefore, the study was designed to evaluate the effect of
different ratios of fish oil (FO) and corn oil (CO) in the prevention of colon cancer. Male Wistar rats were divided into
control, dimethylhydrazine dihydrochloride (DMH) treated, FO + CO (1:1) and FO + CO (2.5:1). All the groups, except the control
received a weekly injection of DMH for 4 weeks. The animals were sacrificed either 48 h later (initiation phase) or kept for
16 weeks (post initiation phase). DMH treatment in the initiation phase animals showed mild to moderate inflammation, decreased
ROS and TrxR activity, increased antioxidants, apoptosis and ACF multiplicity. The post initiation study showed severe inflammation
with hyperplasia, increased ACF multiplicity and ROS levels, a decrease in antioxidants and apoptosis. The FO + CO (1:1) treated
animals showed severe inflammation, a decrease in ROS, an increase in antioxidants and apoptosis in the initiation phase.
FO + CO (1:1) in the post initiation phase and FO + CO (2.5:1) in the initiation showed mild inflammation, increased ROS,
apoptosis and decreased antioxidants. There was a decrease in ACF multiplicity and ROS levels, increased antioxidants and
apoptosis in the post initiation phase study. The present study suggests that FO has a dose- and time-dependent chemopreventive
effect in colon cancer mediated through oxidative stress and apoptosis. 相似文献
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Due to variety of materials available to any designer for a particular application, there is a need for a proper technique to select. This paper focuses on the optimum selection of materials for electrostatic microactuators using Ashby approach. In this work, performance indices and material indices have been developed for electrostatic actuators and thereafter material selection chart is plotted. The selection chart shows that for high actuation voltage and high actuation force, diamond is the best possible candidate followed by silicon carbide and silicon nitride. On the other hand, if high speed electrostatic actuator is desired, then aluminum is the best possible candidate followed by nickel and copper. 相似文献