Nano fibrillated cellulose-based foam by Pickering emulsion: Preparation,characterizations, and application as dye adsorbent

An ecofriendly and biodegradable porous structure was prepared from drying aqueous foams based on nano fibrillated cellulose (NFC), extracted from softwood pulp by subcritical water/CO₂ treatment (SC-NFC). The primary aim of this work was to use the modified SC-NFC as stabilizer for a water-based Pickering emulsion which upon drying, yielded porous cellulosic materials, a good dye adsorbent. In order to exploit the carboxymethylated SC-NFC (CMSC-NFC, with a degree of substitution of 0.35 and a charge density of 649 μeqv/g) as a stabilizer for water-based Pickering emulsion in subsequent step, an optimized quantity of octyl amine (30 mg/g of SC-NFC) was added to make them partially hydrophobic. A series of dry foam structures were prepared by varying the concentrations of treated CMSC-NFCs and 4 wt% was found to be the optimum concentration to yield foam with high porosity (99%) and low density (0.038 g/cc) along with high compression strength (0.24 MPa), superior to the conventionally extracted NFC. The foams were applied to capture as high as 98% of methylene blue dyes, making them a potential green candidate for treating industrial effluent. In addition, the dye adsorption kinetics and isotherms were found to be well suited with second order kinetics and Langmuir isotherm models.     

Hydrothermally treated chitosan spontaneously forms water-soluble spherical particles stable at a wide pH range

The authors report the spontaneous formation of water-soluble chitosan-tartaric acid (CS-TA) spherical particles. Particles are formed by heating chitosan in the presence of tartaric acid under hydrothermal conditions. Tartaric acid serves as an ionic cross-linker, a depolymerizing agent, and a particle stabilizer in aqueous phase. The CS-TA particles exhibit superior colloidal stability at a wide pH range due to their surface charge tunability, which is due to the colocalization of surface hydroxyl, amine, and carboxyl groups. At physiological pH condition, particles have zwitterionic structure as determined by the zeta potential measurements. Still, CS-TA maintains colloidal stability at neutral pH due to the abundance of surface hydroxyl groups. As a proof-of-concept study, the CS-TA particles were labeled with a model insoluble cargo (fluorescein isothiocyanate [FITC]) to demonstrate their capacity for solubilizing hydrophobic drugs. The CS-TA/FITC conjugates were found to remain well dispersed at neutral pH, while maintaining FITC fluorescence properties.     

An NTU- model for alternative refrigerants

This paper presents a steady state simulation model to predict the performance of alternative refrigerants in vapour compression refrigeration/heat pump systems. The model is based on the NTU- method in analysing the heat exchangers following an elemental approach. The model extends its applicability to new refrigerants including hydrocarbons and uses a large database of REFPROP package for refrigerant properties. The main inputs to the model include the physical details of the heat exchangers, compressor efficiency, mass flow rates of heat transfer fluids and their inlet temperatures to the evaporator and the condenser, the pressure drops across the heat exchangers and the capacity of either the evaporator or condenser (in kW). The model results are validated with a wide range of experimental data of HCFC22 and propane (HC290) on a heat pump test facility for a number of parameters, e.g. coefficient of performance, condenser capacity, mass flow rate of the refrigerant and compressor discharge temperature. Although the model is currently tested for pure refrigerants using compact brazed plate (counter flow type) heat exchangers, it can also be applied to mixture of refrigerants as well as to other types of heat exchangers.

Résumé

Dans cet article, on présente un modèle de simulation de régime permanent pour prédire la performance des frigorigènes de remplacement dans les systèmes frigorifiques ou les pompes à chaleur à compression de vapeur. Fondé sur la méthode NTU- utilisée pour analyser les échangeurs de chaleur, ce modèle emploie une approche élémentaire. Ce modèle étend la méthode aux nouveaux frigorigènes, y compris deees hydrocarbures, et utilise une base de données étendue, celle de REFPROP, pour les propriétés des frigorigènes. Les principaux paramètres du modèle comprennent des détails physiques sur les échangeurs de chaleur, le rendement des compresseurs, et les débits massiques des fluides de transfert de chaleur et leurs températures à l'entrée de l'évaporateur ou du condenseur, la chute de pression à travers les échangeurs de chaleur et la puissance soit de l'évaporateur, soit du condenseur (exprimés en kW). Les résultats obtensus en utilisant ce modèle sont validés pour une large gamme de données expérimentales obtenus avec le HCFC22 et avec le propane (le HC290) sur un banc d'essai de pompe à chaleur et pour un certain nombre de paramètres, par exemple le coefficient de performance, la puissance du compresseur, le débit massique du frigorigène et la température du frigorigène à la sortie du compresseur. En ce moment, le comportement des frigorigènes purs utilisés dans des échangeurs de chaleur compacts à plaques brasées (de type contre-courant) est en train d'être étudié; le modèle peut également être appliqué aux mélanges de frigorigènes et à d'autres types d'échangeurs de chaleur.     

Coupling of a Conventional Spectrofluorimeter with Stopped‐Flow Devices

Abstract

Experimental techniques and instruments have emerged profusely to the aid of experimental scientists. The mechanical part of research can be said to have simplified much, with the advent of various instruments for different fields of study. In this paper, we describe a simple idea of coupling two separate instrumental entities to develop a complete set‐up for doing stopped flow fluorescence experiments. The main components in the set‐up are one spectrofluorimeter and stopped‐flow devices, and the interface, being made by using optical fiber bundles. Experimental data are also shown in support of the successful interfacing of the devices to obtain useful results.     

Production of Vegetable Protein from Rapeseed Press-Cake Using Response Surface Methodology,Weighted Multivariate Index,and Desirability Function: A Way to Handle Correlated Multiple Responses

The majority of present day industrial processes/products are defined by several quality characteristics, for which the process variables need to be precisely modulated to meet the required specifications. Hence, the multi-response process optimization has become an increasingly important and demanding task. In practice, many of these quality characteristics under consideration show conflicts among themselves, which need to be simultaneously satisfied. This situation is aggravated when the quality characteristics show correlation. To remedy this shortfall, we present a novel multi-objective process optimization approach, based on weighted principal components (principal component scores weighted by their respective eigen values), response surface methodology and desirability function. The implementation of the suggested approach is presented on a study that discusses the optimization of light-colored and reduced phytate containing protein extraction process from rapeseed press-cake. The effectiveness of the said approach was confirmed by performing additional confirmatory experiments at the predicted optimal condition. Furthermore, this study suggests the feasibility of the exploitation of the waste oilseed cake for extraction of high quality vegetable protein, using viable process and simple computational procedure. This study also briefly highlights performance analyses in cross-flow batch extraction scheme using optimized condition.     

Influence of green extraction process of nano fibrillated cellulose using subcritical water/CO2 on its properties and development of its bio composite

The study proposes a new green extraction method of producing nano fibrillated cellulose (NFC) from softwood pulp (SWP) by using subcritical water/CO₂. Subcritical water/CO₂ led to a controlled hydrolysis of SWP and the treated SWP was fibrillated by sonication to produce NFC. Effect of process parameters (time, temperature, and pressure) on the crystallinity and thermal properties of NFC was studied to optimize the process conditions for controlled hydrolysis. The influence of the extraction process on the properties of prepared NFC was studied. Nanocellulosic materials were characterized by using field emission scanning electron microscopy, transmission electron microscopy, Fourier-transform infrared spectroscopy, wide-angle X-ray diffraction, and thermo gravimetric analysis. The NFC obtained at optimum process conditions (100 bar, 145°C, and 30 min) showed significantly high crystallinity (66%) and high yield (75–80%) compared to the NFC prepared by conventional mechanical grinding method. The present method of producing NFC uses water and pressurized CO_2, and therefore, eliminate use of acids and chemicals. Plasticized poly vinyl alcohol (p-PVA) based nano composite with NFC shows significant improvement in thermal stability (36%), tensile strength (77%) with reduced water vapor transmission rate as compared to virgin p-PVA indicating their potential as nanofiller for making bio composites.     

An experimental study on HC290 and a commercial liquefied petroleum gas (LPG) mix as suitable replacements for HCFC22

This paper presents an experimental study on the performance of hydrocarbon refrigerants, namely propane and a liquefied petroleum gas (LPG) mix as suitable replacements for the widely used refrigerant HCFC22 in refrigeration and heat pump applications. A cylinder of commercially available LPG from New Zealand market was obtained for this study. The composition of the specific LPG mix (by mass fraction) was propane (HC290)—98.95%, ethane (HC170)—1.007%, iso-butane (HC600a)—0.0397% and other constituents in small proportions. Experiments were carried out in a laboratory heat pump test facility with maximum condenser capacity of approximately 15 kW. Condensing temperatures were held constant at 35, 45 and 55°C, while evaporating temperatures were varied over a wide range from − 15 to + 15°C. All tests were carried out at constant degree of superheat (about 1 K) and subcooling (about 8 K). All appropriate precautions were observed against any leaks or fire.The analysis revealed that the hydrocarbon refrigerants performed better than HCFC22 but with a small loss of condenser capacity. The mass flow rate and compressor discharge temperature were found to be significantly lower than HCFC22. The performance of the specific LPG mix tested was found to be better than HC290 at higher condensing temperatures but poorer at a lower condensing temperature. No adverse effects were found with the LPG mix despite the presence of little moisture (less than 0.01%) in its composition. The study reveals that LPG of the tested composition (i.e. predominantly a mixture of propane, ethane and iso-butane) can be an excellent refrigerant in heat pump/refrigeration applications.