Viscoelastic characterization of moderately concentrated polystyrene solutions by dynamic light scattering

The dynamic light scattering measurements were performed for moderately concentrated entangled solutions of atactic polystyrene in benzene (BZ) at 25.0 °C, in cyclohexane (CH) at 34.5 °C (Θ), and in diethyl malonate (DEM) at 35.0 °C (Θ) to characterize their viscoelastic properties. The results have shown that while the mutual diffusion coefficient D increases in the BZ solutions and decreases in the CH and DEM solutions with increasing polymer mass concentration c, the friction coefficient ζ for the three solutions increases with c showing the same power-law behavior irrespective of the weight-average molecular weight M_w and solvent quality. It has been found that the instantaneous longitudinal modulus L₀ for the CH and DEM solutions increases in proportion to c², obeying the familiar relation for the plateau value (4/3)G_N of the longitudinal stress relaxation modulus, but the L₀ values for these solutions are somewhat smaller than the values predicted from the relation. The terminal relaxation time τ_m for the two Θ solvent systems has been found to follow the power-law τ_m∝c^2.7, showing good correspondence to the relation established by rheological measurements.     

Connection structures between type-I and type-II defects in neutron irradiated beta-Si3N4

High-resolution electron microscopy (HREM) observation clarified that various types of interstitial dislocations were induced into beta-Si3N4 by high-dose neutron irradiation, and two of them have been analysed and reported in our previous papers. These two defective structures are called type-I and type-II. They are interstitial dislocation loops introduced into [100] and [110] planes, respectively. In this study, it was found that some of these dislocation loops connected with each other. The connections of type-I-L2-type-II-B and type-I-R2-type-II-A dislocations were observed by HREM. Tetrahedral arrangements of the connected parts are proposed, based on the simplified crystal structure model of beta-Si3N4. In addition, a new type of defect, type-III, was found. Type-III is an interstitial dislocation loop introduced into [100] planes. It was also found that type-I-A and type-III dislocations connected with each other.     

Densification of magnesia-based inert matrix fuels using asbestos waste-derived materials as a sintering additive

A new concept for densification of minor actinide-containing inert matrix fuels (IMFs) using asbestos waste-derived materials was proposed for the effective utilization of resources and health protection of the general public. In this concept, magnesium silicates, which are mainly generated by the decomposition of asbestos in low temperature heat-treatments, are used as a sintering additive to achieve high density magnesia (MgO) -based IMFs at relatively low sintering temperature. In the present study, preliminary fabrication tests of MgO-based IMFs with magnesium silicates were carried out using cerium oxide (CeO₂) as a representative of minor actinide oxides. The sintered densities of MgO-based IMFs increased with use of the additives. The sintering behavior of MgO-based IMFs with magnesium silicate additives was discussed from the viewpoints of the effects of magnesium silicates on the densification of the MgO and CeO₂.     

Recovery of neutron-induced damage of SiC by thermal annealing up to 1400 °C

Recovery of the specimen length of neutron-irradiated SiC was observed using a precision dilatometer. The specimens were heated isothermally and isochronally. The accuracy of length measurement at high temperature using the dilatometer was compared with that of length measurement at room temperature using a micrometer. It was clarified that the dilatometer method showed high accuracy and stability. The dilatometer method was applied to observe length recovery by isothermal annealing at 1200 °C of the neutron-irradiated SiC, and at least two recovery rates were clarified.     

Electrochemically instantaneous reduction of conducting polyaniline-coated latex particles dispersed in acidic solution

A cathodic voltammetric wave was observed in an aqueous suspension of mono-dispersed, spherical polyaniline-coated polystyrene particles, whereas no anodic wave was detected. This irreversibility was common to particles with eight different diameters ranging from 0.2 to 7.5 μm. Such irreversibility cannot be found at polyaniline-coated electrodes, and thus is a property of the dispersion of polyaniline latex. The reduction current was controlled by diffusion of dispersed particles. The reduction, being the conversion from the electrical conducting state to the resistive one, should begin at a point of contact between the conducting particle and the electrode in order to be propagated to the whole particle rapidly. In contrast, the oxidation proceeds slowly with the propagation of conducting zone, during which Brownian motion lets the particle detach from the electrode. The number of loaded aniline units per particle, determined by weight analysis, ranged from 6 × 10⁶ (Ø 0.2 μm) to 3 × 10¹¹ (Ø 7.5 μm) and was proportional to 2.9 powers of the particle diameter. The diffusion-controlled current of the cathodic wave was proportional to 2.4 powers of the diameter. The difference in these powers, 0.5, agreed with a theoretical estimation of the diffusion-controlled current, the diffusion coefficient for which was given by the Stokes-Einstein equation.     

Effects of External Stress on Defect Annihilation and Bubble Swelling During Annealing of Neutron-Irradiated Silicon Carbide

Silicon carbide ceramics fabricated by three different methods were neutron-irradiated in the Japan Materials Testing Reactor and were subsequently annealed free from stresses or under compressive external stresses. The macroscopic length monotonically decreased with annealing above the irradiation temperature, when annealing was performed below ∼1300°C. This decrease was not affected by the external stresses. However, annealing above ∼1300°C led to an increase in length in B-containing SiC. The expansion was caused by the formation and growth of He bubbles at grain boundaries. The growth occurred by flow of vacancies into bubbles. The compressive stress retarded the expansion along the loading direction. This retardation was compensated by a length incrase along the lateral direction. The effect of external stresses was discussed by considering differently oriented He bubbles. One bubble was stress favored and the other stress unfavored. The stress determined the diffusional flow of vacancy-He atom complexes between the favored and unfavored bubbles which were caused by anisotropic expansion under a directional stress.     

Evolutionary synthesis method of energy integrated distillation separation process

A two-stage evolutionary method is developed to synthesize an optimal energy integrated distillation separation process: the search of the separation sequence, and the introduction of energy integration to the given separation sequence. For the former an evolutionary procedure first generating initial separation sequences and then evolving them is developed. For the latter an evolutionary procedure, first indicating the direction of the evolution by the thermodynamic analysis and then estimating it based on the objective function, is developed. An example problem of a five-component separation demonstrates the effectiveness of this proposed method.     

Relations of flow languages to Petri net languages

A.C. Shaw has introduced the concept of the flow expression which is an extended regular expression and state several results with some conjectures. His conjecture that the flow expressions define context-sensitive languages has been answered negatively by two of the present authors, that is, the flow languages are recursively enumerable.In this paper, it is shown that flow languages for some restricted class of flow expressions are equivalent to Petri net languages. Some related decision problems for flow expressions are also discussed.     

Oxidation mechanisms of SiC-fiber–reinforced Si eutectic alloy matrix composites at elevated temperatures

SiC-fiber–reinforced binary Si eutectic alloy composites have been developed for aerospace applications using the melt infiltration method. In this study, the oxidation mechanisms of various binary Si eutectic alloys were evaluated at elevated temperatures. We suggest that the oxidation resistance of eutectic alloys could be predicted using the Gibbs energy change for the oxidation reaction. Based on these calculations, eutectic alloys of Si-16at%Ti, Si-17at%Cr, Si-22at%Co, Si-38at%Co, and Si-27at%Fe were prepared. These alloys produced uniform SiO₂ layers and showed the same oxidation resistance as Si at 1000°C under humid conditions. Therefore, SiC composites using Si alloys with excellent oxidation resistance can be predicted using thermodynamic calculations.