Environmental effects on the strength and impact damage resistance of alumina based oxide/oxide ceramic matrix composites

In this study the effects of high temperature and moisture on the impact damage resistance and mechanical strength of Nextel 610/alumina silicate ceramic matrix composites were experimentally evaluated. Composite laminates were exposed to either a 1050°C isothermal furnace-based environment for 30 consecutive days at 6 h a day, or 95% relative humidity environment for 13 consecutive days at 67°C. Low velocity impact, tensile and short beam strength tests were performed on both ambient and environmentally conditioned laminates and damage was characterized using a combination of non-destructive and destructive techniques. High temperature and humidity environmental exposure adversely affected the impact resistance of the composite laminates. For all the environments, planar internal damage area was greater than the back side dent area, which in turn was greater than the impactor side dent area. Evidence of environmental embrittlement through a stiffer tensile response was noted for the high temperature exposed laminates while the short beam strength tests showed greater propensity for interlaminar shear failure in the moisture exposed laminates. Destructive evaluations exposed larger, more pronounced delaminations in the environmentally conditioned laminates in comparison to the ambient ones. External damage metrics of the impactor side dent depth and area directly influenced the post-impact tensile strength of the laminates while no such trend between internal damage area and residual strength could be ascertained.     

Synthesis of magnetic nanocomposite microparticles for binding of chlorinated organics in contaminated water sources

In this work, the development of novel magnetic nanocomposite microparticles (MNMs) via free radical polymerization for their application in the remediation of contaminated water is presented. Acrylated plant-based polyphenols, curcumin multiacrylate (CMA) and quercetin multiacrylate (QMA), were incorporated as functional monomers to create high affinity binding sites for the capture of polychlorinated biphenyls (PCBs), as a model pollutant. The MNMs were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy, dynamic light scattering, and UV–visible spectroscopy. The affinity of these novel materials for PCB 126 was evaluated and fitted to the nonlinear Langmuir model to determine binding affinities (K_D). The results suggest the presence of the polyphenolic moieties enhances the binding affinity for PCB 126, with K_D values comparable to that of antibodies. This demonstrates that these nanocomposite materials have promising potential as environmental remediation adsorbents for harmful contaminants.     

Polyphenol conjugated poly(beta-amino ester) polymers with hydrogen peroxide triggered degradation and active antioxidant release

Oxidative stress has been implicated as a primary or secondary player to numerous diseases. A potential approach to control oxidative stress induced diseases is to deliver small antioxidant compounds to compromised sites at equivalent rates of reactive oxygen species (ROS) generation. This becomes a complicated task as antioxidant molecules typically have poor bioavailability and stability. Antioxidants synthesized into poly(beta-amino ester) (PBAE) crosslinked polymers have shown improved delivery by enhancing stability while allowing controlled release through hydrolysis. The tunable crosslinked networks show significant response to specific oxidizing environments, where free radicals can be present. Curcumin conjugated PBAE bulk films have proportional rates of accelerated degradation, thus faster release of curcumin, in a range of low concentrations of hydrogen peroxide (H₂O₂)_, where 2′2-azobis(2-amidinopropane) dihydrochloride has no substantial impact. This effect suggests the possibility to create a system that releases its therapeutic agent in direct relationship to the need through ROS signaling. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48647.     

Effect of silane structure on the properties of silanized multiwalled carbon nanotube-epoxy nanocomposites

Multiwalled carbon nanotubes (MWCNTs) were functionalized with aminosilanes via an aqueous deposition route. The size and morphology of siloxane oligomers grafted to the MWCNTs was tuned by varying the silane functionality and concentration and their effect on the properties of a filled epoxy system was investigated. The siloxane structure was found to profoundly affect the thermo-mechanical behavior of composites reinforced with the silanized MWCNTs. Well-defined siloxane brushes increased the epoxy T_g by up to 19 °C and significantly altered the network relaxation dynamics, while irregular, siloxane networks grafted to the MWCNTs had little effect. The addition of both types of silanized MWCNTs elicited improvements in the strength of the nanocomposites, but only the well-defined siloxane brushes engendered dramatic improvements in toughness. Because the silanization reaction is simple, rapid, and performed under aqueous conditions, it is also an industrially attractive functionalization route.     

A Quantitative Study of the Relationship between Project Performance and BIM Use on Commercial Construction Projects in the USA

This article reports the findings of a quantitative study on the relationship between various project performance outcomes and the use of Building Information Modeling (BIM), within the commercial construction industry. The literature review identified inconsistent results among prior qualitative and quantitative work concerning the relationships of key project performance measures and BIM use. Data on 13 variables from 93 completed construction projects were collected and examined through a causal comparative research design. Projects that used BIM (in design or construction) were not found to experience significant performance outcomes when controlling for the contribution of other independent variables and covariates at the 95% confidence level (CL). At the lower 90% CL, however, projects using BIM in construction experienced significantly higher levels of schedule growth than projects that did not use BIM in construction. Recommendations are made for training of construction management staff as a step to avoid unwanted schedule growth associated with BIM use during construction. This study is one of a very small group of rigorous quantitative analyses of BIM project performance outcomes conducted to date; additionally, it is the only study that has analyzed BIM in a multivariate context that controlled for the contribution of other project variables not directly related to BIM use.     

Thermal analysis of randomly oriented carbon nanotube reinforced functionally graded timoshenko beam

The unique thermal properties of carbon nanotubes (CNT) are utilized to increase the use of functionally graded material (FGM) at higher temperatures which resulted in introduction of a new type of material called as functionally graded carbon nanotube-reinforced composites (FG-CNTRCs). To use the FG-CNTRCs at elevated temperatures, their thermal analysis is very important. In this context, this article presents the thermal analysis of a CNT based FG Timoshenko beam. Material properties distribution is assumed to vary along the thickness direction according to power law distribution and linear distributions. Finite difference method is implemented to find out the temperature distribution. Using first order shear deformation theory (FSDT), expressions for strains and stresses are obtained. The results are compared with temperature distribution according to power law. The effect of CNT distribution on strains and stresses is also observed. Based on these results important conclusions have been drawn.     

Incorporating in-cylinder pressure data to predict NOx emissions from spark-ignition engines fueled with landfill gas/hydrogen mixtures

A 0.745 L 2-cylinder spark-ignition engine was operated with compressed natural gas and with simulated landfill gas (60% CH₄ and 40% CO₂ by volume) containing hydrogen concentrations of 0, 30%, 40%, and 50% (by volume of the CH₄ in the fuel) at constant rpm. This empirical data was compared with predictions from three existing semi-empirical engine models, using a first-law-based finite heat release model to correlate measured in-cylinder pressure data and burn rate for each fuel mixture. Of the three models only a two zone model incorporating thermal and prompt NO_x came within 25% of predicting the measured NO_x emissions.     

Room-Temperature Solid-Matrix Luminescence Spectroscopy of Pyrene and 1-Hydroxypyrene from Optically Clear Sugar Glasses

Room-temperature solid-matrix luminescence was investigated for two model compounds pyrene and 1-hydroxypyrene from optically clear sugar glasses. Several glasses were investigated. Novel glasses were prepared for the first time from binary mixtures of sugars for spectroscopy. Glasses were prepared from glucose/xylose and glucose/maltose. The glucose/maltose gave a superior glass compared to glucose/xylose. The glucose/maltose glass gave the best room temperature phosphorescence (RTP) for pyrene compared to glasses of glucose and maltose without a heavy atom. The RTP was weak for both pyrene and 1-hydroxypyrene without a heavy atom in the glucose glass. The addition of a heavy atom (12% NaI) gave a 44-fold increase in RTP of pyrene and a 10-fold increase in the RTP of 1-hydroxypyrene. Room temperature fluorescence (RTF) of pyrene and 1-hydroxypyrene were easily observed from all the glass systems studied. However, the pyrene RTF intensity varied with the different sugar glass systems studied. Furthermore, a polymer, polyacrylic acid (PAA), was added to the sugar matrix at the level of 1% and 2% to improve the rigidity of the glass matrix. The observed phosphorescence was weak for pyrene at both the 1% and 2% PAA concentrations. A glass prepared with 2% PAA gave the strongest RTP for pyrene. Addition of 12% NaI with 1% polyacrylic acid did improve the RTP of pyrene but it was less than the RTP of pyrene from a glucose glass with 12% NaI by a factor of 2.7. A glucose glass with 12% NaI was the best system for RTP of pyrene.     

Metal interactions in contaminated freshwater sediments from the fly river floodplain,Papua New Guinea

Field data for sediment pH, Eh, sulphur and organic matter were analysed to determine their relationship with measured dissolved and particulate metals from sites in the Fly River affected by mine‐derived wastes. The above‐background concentrations of dissolved metals correspond to various concentration groups as demonstrated by copper for background (< 70 mg/kg), moderate (70–500mg/kg) and severe (> 500mg/kg), respectively. Dissolved Cu (r = 0.7431, p < 0.0005) and Mo (r = 0.7133,/> < 0.0005) were significantly correlated with their sediment component. Dissolved Al, Cd, Cu and Mo were positively correlated with sediment pH. Significant negative correlation between dissolved copper and sediment (SOM) organic matter (r = ‐0.3821, p < 0.05), and positive correlation with dissolved Al (r = 0.9358, p < 0.0005) suggest that dissolved Cu is present as a complex with either organic matter, Al/Fe oxyhydroxides, or oxyhydroxide‐organic matter colloids. Significant interrelations between dissolved Al, Cu and Mo with organic matter and the ratio of Fe/SOM also suggests that sediment physico‐chemical characteristics are important in the processes occurring in the Fly River floodplain sediments. These processes appear to be responsible for the significantly increased metal concentration in the water column.