Analyzing the nanoindentation response of carbon black filled elastomers

Carbon black (CB) filled elastomers are structurally complex materials that offer unique properties at different length scales. They have tremendous potential applications in a number of fields including the automotive and aerospace industries and for designing innovative smart materials such as artificial muscles but their applications remain limited primarily due to inadequate understanding of their unique mechanical properties. Here, using the Berkovich technique to probe the surface mechanical properties at different scales the nanoindentation response of a series of composites made by homogeneously dispersed CB nanoparticles inside a semicrystalline copolymer matrix has been explored. While the measured loading part of the force–displacement curves is well described by Meyer's empirical power relation, the inverted methodology (IM) approach to deal with the unloading part has been considered and its outcome has been compared with that obtained from the standard Oliver–Pharr's method. The results were consistent with the observed increase of hardness when the applied displacement decreases for all composite samples over a large range of CB volume fraction. Zhang and Xu's model is demonstrated to produce experimentally consistent explanation of this indentation size effect. X-ray photoelectron spectroscopy (XPS) spectra also show composition gradients with depth up to 100 nm. Furthermore, the effect of CB content, surface features, and length scale-dependent deformation on the hardness–displacement behavior have been considered. These findings highlight the possibility of attaining a diverse set of mechanical properties by a better understanding of the nanoindentation response of CB filled elastomers which can be useful for material selection and design improvements in a number of practical applications.     

Optimization of Preparation Conditions to Control Structural Characteristics of Silicon Dioxide Nanostructures Prepared by Magnetron Plasma Sputtering

In this work, highly-pure silicon oxide nanostructures were prepared by a closed-field unbalanced magnetron plasma sputtering technique. These nanostructures were characterized by Fourier-transform infrared spectroscopy, UV-visible spectroscopy, x-ray diffraction, scanning electron microscopy, energy-dispersive x-ray spectroscopy and atomic force microscopy in order to determine the optimum preparation conditions. Minimum particle size of 20 nm was determined for the samples prepared at an inter-electrode distance of 4 cm, Ar:O₂ gas mixing ratio of 70:30, total gas pressure of 0.08 torr, discharge voltage of 2.5 kV, discharge current of 35 mA, anode temperature of 27 ^°C (room temperature) and cathode temperature of about 40 ^°C. These conditions are optimized to control the structural characteristics of such nanostructures and hence to satisfy certain requirements and purposes in spectroscopic and photonic applications of SiO₂ nanostructures.     

An Efficient Backoff Algorithm for IEEE 802.15.4 Wireless Sensor Networks

IEEE 802.15.4 is one of the most prominent MAC protocol standard designed to achieve low-power, low-cost, and low-rate wireless personal area networks. The contention access period of IEEE 802.15.4 employs carrier sense multiple access with collision avoidance (CSMA/CA) algorithm. A long random backoff time causes longer average delay, while a small one gives a high collision rate. In this paper, we propose an efficient backoff algorithm, called EBA-15.4MAC that enhances the performance of slotted CSMA/CA algorithm. EBA-15.4MAC is designed based on two new techniques; firstly, it updates the contention window size based on the probability of collision parameter. Secondly, EBA-15.4MAC resolves the problem of access collision via the deployment of a novel Temporary Backoff (TB) and Next Temporary Backoff (NTB). In this case, the nodes not choose backoff exponent randomly as mentioned in the standard but they select TB and NTB values which can be 10–50 % of the actual backoff delay selected by the node randomly. By using these two new methods, EBA-15.4MAC minimizes the level of collision since the probability of two nodes selecting the same backoff period will be low. To evaluate the performance of EBA-15.4MAC mechanism, the network simulator has been conducted. Simulation results demonstrate that the proposed scheme significantly improves the throughput, delivery ratio, power consumption and average delay.     

On the Performance of FFT/DWT/DCT-based OFDM Systems with Chaotic Interleaving and Channel Estimation Algorithms

The efficiency of data transmission over fading channels in orthogonal frequency division multiplexing (OFDM) systems depends on the employed interleaving method. In this study, we propose an improved chaotic interleaving scheme which aims to improve the performance of OFDM system under fading channel. In the proposed scheme, the binary data is interleaved with chaotic Baker map prior to the modulation process. In the sequel, significant degree of encryption is being added during data transmission. The performance of the proposed approach is tested on the conventional fast Fourier transform OFDM, discrete wavelet transform OFDM, and discrete cosine transform OFDM with and without chaotic interleaving. Furthermore, an expectation–maximization (EM) algorithm is proposed for improving channel impulse response (CIR) estimation based on a maximum likelihood principle. The proposed scheme makes use of EM algorithm to update the channel estimates until convergence is reached. The simulation results show the efficiency of the proposed algorithms under Rayleigh fading environments where the symbol error rate essentially coincides with that of the perfect channel case after the fifth EM iteration.     

Co-eye: a multi-resolution ensemble classifier for symbolically approximated time series

Machine Learning - Time series classification (TSC) is a challenging task that attracted many researchers in the last few years. One main challenge in TSC is the diversity of domains where time...     

Discoloration of a red cationic dye by supported TiO(2) photocatalysis

The degradation under UV, visible and sunlight irradiation of C.I. Basic Red 46 (BR 46) dye used for acrylic fibers dyeing has been studied in a lab-scale continuous system with two different immobilized TiO(2) systems. Catalyst I was based on TiO(2) particles deposited on cellulose fibers; Catalyst II combined TiO(2) particles deposited on a layer of cellulose fibers (as in Catalyst I) with a layer of carbon fibers and finally a layer of cellulose fibers. The treatment of aqueous dye solutions and industrial wastewater contaminated with the same dye has been evaluated in terms of color removal and chemical oxygen demand (COD) decrease. With UV light, aqueous solutions containing dye were decolorized slightly more rapidly with Catalyst II than with Catalyst I. Sunlight was also very effective and experiments involving sunlight irradiation showed Catalyst II to be the more efficient, giving more than 90% discoloration after 20 min of treatment. Comparing the discoloration yield by adsorption or under visible light for both catalysts, it was observed that the difference between them is below 5%. The adsorption kinetics was found to follow a second-order rate law for Catalyst I and a first-order rate law for Catalyst II. The kinetics of photocatalytic degradation under UV or sunlight were found to follow a first-order rate law for both catalytic systems. Under sunlight the COD removal yield for textile wastewater reaches 33% with Catalyst I against 93% with Catalyst II.     

Deformation and Mechanical Characteristics of Compacted Binary Mixtures of Plastic (Microcrystalline Cellulose), Elastic (Sodium Starch Glycolate), and Brittle (Lactose Monohydrate) Pharmaceutical Excipients

This work studies the tensile strength, coherence, elastic, and plastic energy of single and bi-component compacted tablets consisting of (i) microcrystalline cellulose (MCC) PH 102 as a plastic material, (ii) (SSG) as an elastic material, and (iii) alpha lactose monohydrate as a brittle material by direct compression. Compacted tablets were studied with various mass ratios formed at an ultimate compaction stress of 150 MPa. The loading and unloading stages of the compaction process for the single and binary tablets were evaluated based on the energies derived from the force-displacement data obtained. The resulting tablet quality was measured in terms of the tensile strength. Material that exhibit predominantly plastic deformation (MCC) shows a dominant property over elastically deforming sodium starch glycolate (SSG) and brittle (lactose) materials during the loading and unloading stages of the compaction process. In conclusion, the tensile strength of the formed tablets depends directly on the plastic energy and indirectly on the elastic energy and is negatively affected by the presence of a brittle material.     

Photocatalytic reaction intensification using monolithic supports designed by stereolithography

An original photocatalytic reactor for the treatment of polluted air is designed. The titanium dioxide is supported on various supports that consist in photopolymers and are built using the stereolithography technique and placed in a glass tube illuminated from the outside, while the air containing the pollutant to be removed flows through the glass tube and the photocatalyst support. It is shown that the gas–solid mass transfer plays a role only at the very smallest gas velocities investigated. The global depollution kinetics are then determined for the different geometrical forms of the photocatalyst support and the efficiency of the forms compared.     

Data Traffic Management Based on Compression and MDL Techniques for Smart Agriculture in IoT

Wireless Personal Communications - When dynamic nature, autonomous, self- configured types nodes are combined together and make contact with each other for the purpose of communication and data...     

Associations between CD133, CK19 and G2/M in cirrhotic HCV (genotype-4) patients with or without accompanying tumor

Hepatitis C virus (HCV)-cirrhotic patients have the highest threat of developing hepatocellular carcinoma (HCC) and may be at risk of extra hepatic cancer. The present study was designed to investigate CD133 and CK19 in HCV (genotype-4)-cirrhotic patients with/without HCC or extra hepatic cancer, to assess the degree of their correlation with cell cycle abnormalities and finally to assess the role of their combination as diagnostic tool for discrimination of cirrhotic patients with HCC from those with extra hepatic cancer. The study included 77 HCV-cirrhotic patients and 20 healthy non-disease control group. Patients were categorized histo-pathologically into: 24 have only liver cirrhosis, 26 with HCC, and 27 patients with extra hepatic cancer. Cell cycle abnormalities, CD133 and CK19 were determined by flow cytometry technique. CD133 and CK19 showed marked elevation in HCC and extra hepatic cancer compared with liver cirrhosis and control subjects (p<0.0001). Positive associations were noted between CK19, CD133 and G2/M. They were gradually increased with progression from liver cirrhosis to HCC. Combination of the three showed the best AUC (0.978) and accuracy (92.5%) for discrimination of HCC from extra hepatic cancer. Combined CD133 with G2/M and CK19 comprises an excellent diagnostic panel for discrimination of HCV-cirrhotic patients with HCC from those with extra hepatic cancer.