Brominated flame retardants in Belgian home-produced eggs: levels and contamination sources

The extent and the sources of contamination with brominated flame retardants (BFRs), such as polybrominated diphenyl ethers (PBDEs) and hexabromocyclododecane (HBCD), in home-produced eggs from free-foraging chicken of Belgian private owners were investigated. Various factors, such as seasonal variability, exposure of chickens through diet (kitchen waste) and soil, and elimination of BFRs through eggs and faeces were assessed. PBDEs were more important than HBCD in terms of concentrations and detection frequency. Concentrations of PBDEs and HBCD in Belgian home-produced eggs were relatively low and comparable with reported levels from other European countries and the US. The concentrations of PBDEs (sum of 13 congeners, including BDE 209) ranged between not detected and 32 ng/g lipid weight (lw), with medians of 3.0 and < 2.0 ng/g lw for the autumn 2006 and spring 2007 campaigns, respectively. When present, BDE 209 was the major PBDE congener (45% of sum PBDEs). When BDE 209 was not detected, the PBDE profile was composed of PentaBDE (BDE 99 and BDE 47), with, in some cases, higher contribution of OctaBDE (BDE 183 and BDE 153). HBCD was also detected (< 0.4 and 2.9 ng/g lw for the autumn 2006 and spring 2007 campaigns, respectively), but at lower detection frequency. The highest HBCD value was 62 ng/g lw. The similarity between profiles and seasonal variations in the concentrations of BFRs in soil and eggs indicate that soil is an important source, but not the sole source, for eggs laid by free-foraging chicken. The contamination of eggs with PBDEs and HBCD appears to be of low concern for public health and the contribution of eggs to the total daily intake of PBDEs appears to be limited (10% for chicken owners and 5% for the average Belgian consumer).     

Photo-vulcanization using thiol-ene chemistry: Film formation,morphology and network characteristics of UV crosslinked rubber latices

The photo-vulcanization with versatile thiol-ene chemistry represents an innovative approach to crosslink diene-rubber materials both in latex and in solid film state. In this work, the structure of elastomer-based thiol-ene networks and the morphology after film formation are studied in detail using electron microscopic techniques, atomic force microscopy and multiple-quantum solid-state NMR spectroscopy. Additionally, film formation properties and corresponding macroscopic properties of photo-vulcanized natural rubber (NR) latex and its synthetic counterpart, isoprene rubber (IR) latex, are determined in dependence on the curing procedure (pre- and post-vulcanization). The results reveal that thiol-ene cured elastomers comprise homogenously distributed crosslinks with a low amount of short chain defects. Whilst photochemically pre-cured NR latex particles provide coherent films, the film formation and mechanical properties of IR are strongly governed by the crosslink density of the latex particles. In film state, photo-vulcanization promotes narrow crosslink distributions and excellent tensile properties of both NR and IR.     

Effect of muscle,ageing time and modified atmosphere packaging conditions on the colour,oxidative and microbiological stability of packed beef

The objective of this study was to evaluate the influence of two different vacuum ageing times (7 and 14 days) and the impact of the modified atmosphere packaging (MAP) configuration (gas/product ratios: 0.5 and 1 and gas composition: 70% O₂ + 30% CO₂ and 40% O₂ + 30% CO₂ + 30% N₂) on the quality of fresh beef during subsequent storage at 4 °C. For this purpose, three separate experiments were performed. For each experiment, two different muscles (Longissimus dorsi and Biceps femoris) were sampled from four double‐muscled Belgian Blue beef carcasses. Next to colour, also the evolution in microbial load, pH, O₂ and CO₂ in the headspace and lipid oxidation at the meat surface were evaluated. A vacuum ageing for 14 days compared with 7 days resulted in a higher initial microbial load on the day of MAP packaging, which resulted finally in a significantly shorter shelf life. This ageing effect was less pronounced on the colour stability and lipid oxidation of the meat samples. No significant influence of the packaging configuration on any of the analysed parameters (colour, microbial load, pH and lipid oxidation at the meat surface) was observed.     

The effect of the research setting on the emotional and sensory profiling under blind,expected, and informed conditions: A study on premium and private label yogurt products

Although sensory and emotional evaluation of food products mostly occurs in a controlled laboratory environment, it is often criticized as it may not reflect a realistic situation for consumers. Moreover, products are mainly blind evaluated by participants, whereas external factors such as brand are often considered as key drivers of food choice. This study aims to examine the role of research setting (central location test versus home-use test) and brand information on the overall acceptance, and sensory and emotional profiling of 5 strawberry-flavored yogurts. Thereby, private label and premium brands are compared under 3 conditions: blind, expected, and informed (brand information). A total of 99 adult subjects participated in 3 sessions over 3 consecutive weeks. Results showed that overall liking for 2 yogurt samples was higher in the laboratory environment under the informed evaluation condition, whereas no effect of research setting was found under the blind and expected conditions. Although emotional profiles of the products differed depending on the research setting, this was less the case for the sensory profiles. Furthermore, brand information clearly affected the sensory perception of certain attributes but had less influence on overall liking and emotional profiling. These results indicate that both scientists and food companies should consider the effect of the chosen methodology on ecological validity when conducting sensory research with consumers because the laboratory context could lead to a more positive evaluation compared with a home-use test.     

Improved process control of an industrial sludge centrifuge-dryer installation through binary logistic regression modeling of the fouling issues

Biological wastewater treatment generates huge amounts of waste sludge which need to be dewatered and eventually dried to minimize transportation and incineration costs. A characteristic feature of sludge in this context is that it turns into a sticky substance during its drying process inducing fouling problems in the drying installation. At the wastewater treatment plant of Monsanto in Antwerp, Belgium, one enclosed centrifuge-dryer system is used to dry the sludge. In the past, this installation had to be shut down regularly due to dryer fouling problems. To avoid these operational problems, a binary logistic regression analysis is presented in this research based on a 5-year database, resulting in an empirical model for the evaluation of the dryer fouling risk as a function of the sludge feed characteristics. The model inputs are the sludge volume index (SVI) and the dosing of clay additive and tertiary (flotation) sludge, the latter containing polyaluminumchloride (PACl), to the sludge feed of this particular system.By exploiting the knowledge captured by this model, the derived control strategy is based on the value of the SVI. Whenever the SVI is high the original high clay dosing to the feed needs to be maintained. At moderate SVI values, implying an intrinsically better sludge dewaterability, the strategy dictates a reduction in the clay dosing to the sludge feed to have a reduced sludge solids dryness after dewatering, thereby avoiding that the sludge exhibits its most sticky phase when passing the most fouling sensitive part of the dryer. When the SVI is lower than 50 mL/g the control strategy states that conditioning of the sludge with PACl is required to mask the stickiness instead of postponing it, avoiding that the stickiness of the sludge already hampers the dewatering stage of the process.     

先进低成本的铸件浇注和补缩系统设计方法

用实例介绍了一项用于铸造生产的三维模拟技术,通过对金属液充型和凝固过程的数值模拟进行铸造工艺设计,从而在计算机上实现可视铸造过程,能保证既快又省地设计一个优化的铸造工艺.与传统的模数法,经验和试错的工艺设计不同,本模型是用铸件的凝固时间计算补缩系统.从一个铸件凝固模拟开始,根据凝固时间和被补缩的体积,计算冒口和冒口颈的尺寸和数量,再进行铸件加冒口的模拟计算,做必要的修正,直到获得满意的结果,最后根据铸件的临界壁厚、体积、充型速度和浇注温度等参数计算浇注系统.当整个系统设计完成后,模拟计算整个充型和凝固过程以验证设计,做必要的修正,直到获得一个能生产无铸造缺陷铸件的铸造工艺,即保证一次成功生产出合格铸件,节约了时间和成本.     

Auswirkungen von Baggerungen und Verklappungen hochwasserbedingter Feinsedimentablagerungen am Fallbeispiel Winterhafen Linz/Donau

In the case study “Winterhafen Linz” the effects of dredging/excavating fine sediments previously deposited by flood events and their subsequent dumping into the Danube mainstream were investigated. While this maintenance work was in progress, the temporal and spatial extent of the sediment plume and the changes in bed topography were measured. By employing air-lift samplers and grab samplers in the dredging and dumping areas, the question as to whether, and if so to what extent, the benthic invertebrate community was disturbed by the maintenance work. It could be clearly demonstrated that the sediment dredging severely affected the benthic invertebrates (an 82 % decline in biomass), while the dumping of the material had no effects on the Danube biota. Numerical modeling was used to simulate discharges and dumping locations other than those actually encountered during the monitoring campaign, thus making it possible to extrapolate and draw conclusions beyond the concrete results. These findings in turn provided the basis for recommendations on how to optimize dredging and dumping procedures on the Danube in future.