Enhanced calcium–magnesium–aluminosilicate (CMAS) resistance of GdAlO3 (GAP) for composite thermal barrier coatings

The impact of calcium–magnesium–alumino-silicate (CMAS) degradation is a critical factor for development of new thermal and environmental barrier coatings. Several methods of preventing damage have been explored in the literature, with formation of an infiltration inhibiting reaction layer generally given the most attention. Gd₂Zr₂O₇ (GZO) exemplifies this reaction with the rapid precipitation of apatite when in contact with CMAS. The present study compares the CMAS behavior of GZO to an alternative thermal barrier coating (TBC) material, GdAlO₃ (GAP), which possesses high temperature phase stability through its melting point as well as a significantly higher toughness compared with GZO. The UCSB laboratory CMAS (35CaO–10MgO–7Al₂O₃–48SiO₂) was utilized to explore equilibrium behavior with 50:50 mol% TBC:CMAS ratios at 1200, 1300, and 1400°C for various times. In addition, 8 and 35 mg/cm² CMAS surface exposures were performed at 1425°C on dense pellets of each material to evaluate the infiltration and reaction in a more dynamic test. In the equilibrium tests, it was found that GAP appears to dissolve slower than GZO while producing an equivalent or higher amount of pore blocking apatite. In addition, GAP induces the intrinsic crystallization of the CMAS into a gehlenite phase, due in part to the participation of the Al₂O₃ from GAP. In surface exposures, GAP experienced a substantially thinner reaction zone compared with GZO after 10 h (87 ± 10 vs. 138 ± 4 μm) and a lack of strong sensitivity to CMAS loading when tested at 35 mg/cm² after 10 h (85 ± 13 versus 246 ± 10 μm). The smaller reaction zone, loading agnostic behavior, and intrinsic crystallization of the glass suggest this material warrants further evaluation as a potential CMAS barrier and inclusion into composite TBCs.     

Carbon losses from soil and its consequences for land-use management

This paper reviews our current knowledge and understanding of carbon processes in the terrestrial ecosystem with a view to reducing soil carbon losses by optimising land-use and land management. Processes that influence the fate of carbon (in both terms of quantity and quality) are important in determining soil fertility, quality and health as well as consequences for future environmental change scenarios. We need to understand the processes that determine soil carbon losses and the fate of the carbon once lost from the soil in order to provide sustainable solutions for mitigating these carbon losses as part of land management "best practice" and balancing national carbon budgets. Here we review the amount of carbon within the UK terrestrial pool, the processes involved and factors influencing carbon transport to and from soils, the fate of the carbon once it has been lost from the soil environment and land-use scenarios that affect carbon losses. We conclude with possible management options to reduce soil carbon loss and identify gaps in knowledge in order to better understand carbon processes in the terrestrial environment.     

Applicability of time-of-flight-based ground and multispectral aerial imaging for grapevine canopy vigour monitoring under direct root-zone deficit irrigation

ABSTRACT

This study investigates the applicability of ground-based 3D time-of-flight (ToF) imaging and small unmanned aerial system (UAS) integrated multispectral imaging as a rapid grapevine canopy vigour mapping tool for decision support during crop production management. Direct root-zone deficit irrigation was applied to grapevines with continuous and pulse irrigation techniques at 15%, 30%, and 60% rates as that of standard irrigation rate (100%) established by the grower in a commercial production. The control block was irrigated continuously at 100% standard irrigation rate. Field plots were imaged using ground platform integrated with 3D ToF imaging sensor and small UAS-integrated multispectral camera at 128 and 65 days before the harvest to estimate the canopy vigour variability associated with irrigation treatments. Customized as well as standard methods (convex hull and voxel grid) were utilized to extract canopy attributes (e.g. volume) from the 3D ToF imaging sensor data. The multispectral images were processed to extract normalized and green normalized difference vegetation index images. Resulting data were used to estimate canopy area ratio i.e. the ratio between the grapevine canopy area with respect to the total area in selected region of interest. A significant correlation (r = 0.34) between canopy volume estimated by customized algorithm and aerial canopy area ratio was observed. Custom canopy volume estimates were also highly correlated (r = 0.79) with voxel grid derived canopy volume data. Overall, 60% continuous direct root zone deficit irrigation appeared to produce canopy volume/vigour comparable with those under control treatment. Results also suggest that grower can utilize either or both (ground and aerial) grapevine canopy mapping techniques for effective management.     

Social identity,safety climate and self-reported accidents among construction workers

The construction industry has one of the highest frequencies of work-related accidents. We examined whether construction workers predominantly identify themselves in terms of their workgroup or in terms of the construction site. In addition, we examined the associations between social identity and safety climate, and how these constructs are associated with work-related accidents. The analyses were based on questionnaire responses from 478 construction workers from two large construction sites, and the methods involved structural equation modeling. Results showed that the workers identified themselves primarily with their workgroup, and to a lesser degree with the construction site. Social identity and safety climate were related both at the workgroup and construction site levels, meaning that social identity may be an antecedent for safety climate. The association between social identity and safety climate was stronger at the workgroup level than at the construction site level. Finally, safety climate at both levels was inversely associated with self-reported accidents, with the strongest association at the workgroup level. A focus on improving safety climate, particularly by integrating initiatives at both the workgroup and management level, may have the potential to improve safety performance and thus decrease the risk of accidents and injuries on construction sites.     

Translating Policy Into Brownfield Solar Development

Developing solar power generating resources on dormant, suspect property is an evolving activity, growing in popularity.     

The DOE advanced gas reactor fuel development and qualification program

The high outlet temperatures and high thermal-energy conversion efficiency of modular high-temperature gas-cooled reactors (HTGRs) enable an efficient and cost-effective integration of the reactor system with non-electricity-generation applications, such as process heat and/or hydrogen production, for the many petrochemical and other industrial processes that require temperatures between 300°C and 900°C. The U.S. Department of Energy (DOE) has selected the HTGR concept for the Next Generation Nuclear Plant (NGNP) Project as a transformative application of nuclear energy that will demonstrate emissions-free nuclear-assisted electricity, process heat, and hydrogen production, thereby reducing greenhouse-gas emissions and enhancing energy security. The objective of the DOE Advanced Gas Reactor (AGR) Fuel Development and Qualification program is to qualify tristructural isotropic (TRISO)-coated particle fuel for use in HTGRs. An overview of the program and recent progress is presented.