Fe3O4-carbon spheres core–shell supported palladium nanoparticles: A robust and recyclable catalyst for suzuki coupling reaction

Suzuki-Miyaura (S-M) is regarded the most powerful way for synthesis biaryls, triaryls, or incorporating of substituted aryl moieties in organic preparation by the cross-coupling of aryl boronic acid with aryl halides using the Pd catalyst. This work reports the combining of the hydrothermal and microwave-assisted protocol to convert the glucose to magnetic carbon spheres (Fe₃O₄-CSPs) decorated with Pd nanoparticles (NPs) as the catalyst for Suzuki-Miyaura cross-coupling reactions. The physicochemical properties in the produced composite were examined using FESEM, HRTEM, nitrogen isotherms, Raman spectroscopy, FTIR, XPS, and XRD. The as-fabricated composite Pd/Fe₃O₄-CSPs is mostly spherical with a core–shell structure and possesses a great surface area of 253.2 m²·g^-1. Its catalytic performance demonstrates that the composite has excellent stability and high tolerance Suzuki-Miyaura cross-coupling reactions in 30 min at 80 ℃. Both activated and deactivated aryl halides provided excellent yield. The as-fabricated catalyst was recycled for up to four catalytic cycles without a substantial decline in performance. Moreover, this research offers a facile roadmap for synthesizing Pd/Fe₃O₄-CSPs composites and promoting the practical implementation of Pd/Fe₃O₄-CSPs catalysts for organic transformation processes.     

Microstructure and mechanical behavior of laser aided additive manufactured low carbon interstitial Fe49.5Mn30Co10Cr10C0.5 multicomponent alloy

Laser aided additive manufacturing(LAAM)was used to fabricate bulk Fe49.5Mn30Co10Cr10C0.5 interstitial multicomponent alloy using pre-alloyed powder.The room temperature yield strength(σy),ultimate tensile strength(σUTS)and elongation(εUST)were 645 MPa,917 MPa and 27.0％respectively.The as-built sample consisted of equiaxed and dendritic cellular structures formed by elemental segregation.These cellular structures together with oxide particle inclusions were deemed to strengthen the material.The other contributing components include dislocation strengthening,friction stress and grain bound-ary strengthening.The high εUTS was attributed to dislocation motion and activation of both twinning and transformation-induced plasticity(TWIP and TRIP).Tensile tests performed at-40℃and-130℃demonstrated superior tensile strength of 1041 MPa and 1267 MPa respectively.However,almost no twinning was observed in the fractured sample tested at-40℃and-130℃.Instead,higher fraction of strain-induced hexagonal close-packed(HCP)ε phase transformation of 21.2％were observed for fractured sample tested at-40℃,compared with 6.3％in fractured room temperature sample.     

增材制造设计(DfAM)下的金刚石晶格结构研究

基于机械零件的增材制造设计,用仿自然式方法设计了一种金刚石晶格结构,对晶胞相对密度和等效弹性模量建立了数学模型,并拟合得到二者关系式,一系列的仿真验证结果显示理论研究所得关系式具有一定的正确性;对金刚石晶格填充结构提出变密度假设,并用仿真和压缩试验的方法进行了验证,结果显示,填充单元密度以受力点为中心渐渐减小的变密度结构拥有更好的抗压性能,同时验证了本文得出的等效弹性模量数学模型具有一定的正确性和适用性.本研究结果可应用于承压机械零件的实体夹层填充,对机械零件进行应力匹配变密度设计,以达到机械结构轻量化的目标.     

Usability of Waste Steel Grits in Concrete Pavement

The usability of waste steel grits and limestone sand in the construction of concrete pavement was investigated.Four different types of pavement concretes were produced,including coarse limestone concrete not containing waste steel grit,coarse limestone concrete containing waste steel grit,limestone sand concrete not containing waste steel grit,and limestone sand concrete containing waste steel grit.In this study,water/binder ratio in concrete production was taken as 0.44.In the production of li...     

在腐植酸存在的条件下动态模拟铜在贻贝类体内的富积

正依据金属生物利用度模型,腐植酸对铜的络合作用有望降低水生生物对铜的生物利用度,就如生物配体模型(BLM)。这个模型在海洋无脊椎动物胚胎或是微藻类等不进食生物中得到了证实。但对于像紫贻贝等滤食性生物体,在腐植酸存在的条件下铜的富积较高,表明摄取的铜-腐植     

新时代开启一流矿山建设新征程——砥砺奋进的蒲白建新煤化公司

正坐落于黄土高原南部边缘黄陵境内的陕西建新煤化有限责任公司,是由陕西陕煤集团蒲白矿业有限公司出资51%、陕西黄河矿业(集团)有限责任公司出资49%组建的股份制企业。自2006年11月开工建设以来,伴随着时代前进的脚步,享受着改革开放的春风,经历了项目竣工验收、试生产、生产能力核定等多个环节,在11年的栉风沐雨中,建新煤化公司取得了辉煌的成就,呈现出崭新的气象,展露出无限的生机。截至2017年11月底,建新煤化公司已累计生产原煤2500万吨,累计产值达71亿元,累计实现利     

矿用直线振动筛结构故障分析

针对煤矿选煤厂直线振动筛工作过程中出现的结构故障问题,采用有限元仿真与现场测试结合的方法对振动筛出现故障的原因进行了分析研究。介绍了振动筛的主要结构及常见故障,并以某矿选煤厂发生大梁断裂的振动筛为例,对该振动筛进行三维建模和有限元模态分析,分析结果表明:随着模态阶次的增加,振型的变化逐渐由移动转为结构本身的扭曲变形。在该振动筛空载工作状态下,选用本质安全型便携式测振记录仪进行振动测试并处理测试信号,得到该振动筛的工作频率。结合模态分析结果和实际测试结果,判断出空载时频繁运行振动筛是造成其大梁断裂的主要原因。根据故障原因给出维护建议:应当尽量避免振动筛在空载或物料较少的状态下长时间运行;在振动筛投入使用前,应预先了解振动筛的工作状态及可能存在的薄弱环节,尽可能避免结构故障,保证振动筛可靠运行。