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本实验模拟人体生理酸度(p H 7.4),应用荧光光谱法、紫外光谱法和圆二色光谱法,研究了食品着色剂柠檬黄与牛血清白蛋白(BSA)的结合性质。结果表明:柠檬黄对BSA内源荧光有较强的猝灭能力,荧光猝灭机制属于形成复合物的单一静态猝灭,计算得出的热力学参数熵变和焓变均为负值,表明氢键和范德华力是驱动柠檬黄-BSA复合物形成的主要作用力,25℃时结合常数已经达到3.04×105L·mol-1,表明柠檬黄与BSA有较强的亲合力。位点竞争实验表明:柠檬黄主要结合至BSA疏水空腔的亚域IIA,即site I位。荧光光谱、紫外光谱和圆二色光谱分析结果显示:柠檬黄与BSA结合引起BSA的表面疏水性增加,α-helix的含量减少,BSA二级结构发生了部分改变。 更多还原 相似文献
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以363 kV阀侧断路器为研究对象,建立三维简化模型,并综合考虑静载荷、风载荷及覆冰载荷等组合工况的条件下,对363 kV阀侧断路器整机进行静力学分析,得到整机零部件应力及变形分布情况,其中支柱复合套管根部最大应力为70.928 MPa,小于材料屈服强度。其次对363 k V阀侧断路器灭弧室关键件进行优化设计,并进行静电场和动态电场仿真分析,电场强度最大值降低了9.86%。然后设计真型抗震性能试验,获得了其自振频率及应变响应、加速度响应曲线,由测量点数据计算的支柱复合套管最小安全系数为1.97,且产品外观良好。因此,363 kV阀侧断路器通过了0.4g工况下的抗震力学性能试验,并通过了电气及机械性能试验检验,验证了整机结构设计的合理性,为支柱套管结构优化和导电结构的设计奠定基础。 相似文献
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Guaranteed cost control of networked control systems under limited communication capacity and variable sampling简 总被引:1,自引:0,他引:1
The problem of guaranteed cost control for the networked control systems (NCSs) with time-varying delays, time-varying sampling intervals and signals quantization was investigated, wherein the physical plant was continuous-time one, and the control input was discrete-time one. By using an input delay approach and a sector bound method, the network induced delays, quantization parameter and sampling intervals were presented in one framework in the case of the state and the control input by quantized in a logarithmic form. A novel Lyapunov function with discontinuity, which took full advantages of the NCS characteristic information, was exploited. In addition, it was shown that Lyapunov function decreased at the jump instants. Furthermore, the Leibniz-Newton formula and free-weighting matrix methods were used to obtain the guaranteed cost controller design conditions which were dependent on the NCS characteristic information. A numerical example was used to illustrate the effectiveness of the proposed methods. 相似文献
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本文提出利用MATLAB语言的SIMULINK软件包对液压系统进行动态仿真的方法.基于功率键合图理论建立了液压系统的仿真模型,并利用SIMULINK软件对液压系统的动态特性进行仿真.结果表明,SIMULINK方法是对液压系统的动态特性进行仿真的一条有效途径.用MATLAB实现其液压系统的动态仿真为液压系统设计提供系统工作的状态信息. 相似文献
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刘英英 《Canadian Metallurgical Quarterly》2011,(11)
农村城镇化建设是贯彻落实科学发展观的重要内容,也是全面建设小康社会的重要任务.本文介绍了城镇化的现状,分析了城镇化进程中的制约因素,最后提出了相应的对策. 相似文献
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