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排序方式: 共有2273条查询结果,搜索用时 343 毫秒
1.
Leonie Reinders Stephanie Pfeifer Sarah Kröner Heiko Stolpmann Achim Renfftlen L. Charlyn Greiler Bernd Clauß Michael R. Buchmeiser 《Journal of the European Ceramic Society》2021,41(6):3570-3580
Polycrystalline mullite fibers and novel zirconia-toughened mullite (ZTM) fibers with average diameters between 9.7 and 10.3 μm containing 3, 7 and 15 wt.-% tetragonal ZrO2 (ZTM3, ZTM7, ZTM15) in the final ceramic were prepared via dry spinning followed by continuous calcination and sintering in air. A shift in the formation of transient alumina phases and tetragonal ZrO2 to higher temperatures with increasing amounts of ZrO2 was observed. Concomitantly, the mullite formation temperature was lowered to 1229 °C for ZTM15 fibers. X-ray diffraction revealed formation of the desired tetragonal crystal structure of ZrO2 directly from the amorphous precursor. Room temperature Weibull strengths of 1320, 1390 and 1740 MPa and Weibull moduli of 9.5, 7.1 and 9.0 were determined for mullite, ZTM3 and ZTM15 fibers, respectively. Average Young’s moduli ranged from 190 to 220 GPa. SEM images revealed crack-free fiber surfaces and compact microstructures independent of the amount of ZrO2. 相似文献
2.
We consider large-scale dynamical systems in which both the initial state and some parameters are unknown. These unknown quantities must be estimated from partial state observations over a time window. A data assimilation framework is applied for this purpose. Specifically, we focus on large-scale linear systems with multiplicative parameter-state coupling as they arise in the discretization of parametric linear time-dependent partial differential equations. Another feature of our work is the presence of a quantity of interest different from the unknown parameters, which is to be estimated based on the available data. In this setting, we employ a simplicial decomposition algorithm for an optimal sensor placement and set forth formulae for the efficient evaluation of all required quantities. As a guiding example, we consider a thermo-mechanical PDE system with the temperature constituting the system state and the induced displacement at a certain reference point as the quantity of interest. 相似文献
3.
Marcel Loewert Julian Hoffmann Paolo Piermartini Manuel Selinsek Roland Dittmeyer Peter Pfeifer 《化学工程与技术》2019,42(10):2202-2214
Current projects focusing on the energy transition in traffic will rely on a high‐level technology mix for their commissioning. One of those technologies is the Fischer‐Tropsch synthesis (FTS) that converts synthesis gas into hydrocarbons of different chain lengths. A microstructured packed‐bed reactor for low‐temperature FTS is tested towards its versatility for biomass‐based syngas with a high inert gas dilution. Investigations include overall productivity, conversion, and product selectivity. A 60‐times larger pilot‐scale reactor is further tested. Evaporation cooling is introduced which allows to increase the available energy extraction from the system. From that scale on, an autothermal operation at elevated conversion levels is applicable. 相似文献
4.
Chenhui Ding Marion Breunig Jana Timm Roland Marschall Jürgen Senker Seema Agarwal 《Advanced functional materials》2021,31(49):2106507
Covalent organic frameworks (COFs) show advantageous characteristics, such as an ordered pore structure and a large surface area for gas storage and separation, energy storage, catalysis, and molecular separation. However, COFs usually exist as difficult-to-process powders, and preparing continuous, robust, flexible, foldable, and rollable COF membranes is still a challenge. Herein, such COF membranes with fiber morphology for the first time prepared via a newly introduced template-assisted framework process are reported. This method uses electrospun porous polymer membranes as a sacrificial large dimension template for making self-standing COF membranes. The porous COF fiber membranes, besides having high crystallinity, also show a large surface area (1153 m2 g−1), good mechanical stability, excellent thermal stability, and flexibility. This study opens up the possibility of preparation of large dimension COF membranes and their derivatives in a simple way and hence shows promise in technical applications in separation, catalysis, and energy in the future. 相似文献
5.
6.
Quoc Ahn Tran Bastien Chevalier Miguel Angel Benz-Navarrete Pierre Breul Roland Gourvès 《Soils and Foundations》2019,59(6):2348-2355
This paper presents a calculation method for obtaining the continuous variation in stress between the tip and the soil during dynamic penetration tests, particularly in the case of using the Panda 3® penetration testing device. The originality of the method is that the tip stress can be computed continuously throughout the driving process. For each impact of the hammer on the penetrometer, data are recorded by sensors located at the top of the apparatus. Then, the stress at the tip and the displacement of the apparatus are calculated with a method based on the propagation of waves in the device. A three-dimensional numerical model of the penetration test, based on the Panda 3® specifications and using the discrete element method (DEM), is proposed in this paper. The purpose of the simulations is to validate the calculation method by comparing the curves of the tip stress versus the penetration distance obtained in two different ways, the first being the distance directly observed at the tip and the second being the distance calculated from the data recorded at the top of the penetrometer, as with the experimental device. The entire apparatus is represented, including the hammer, the rod, and the tip, and is driven into the model soil. The calculation method is applied, and the results are compared to the actual response of the soil to the driving of the penetrometer directly at the tip, which can be obtained with the numerical model. The responses are found to be very similar, confirming the theoretical framework and its underlying assumptions. This method is applied to dynamic penetration tests and provides the opportunity to obtain mechanical parameters other than the tip resistance from the tests. 相似文献
7.
Dr. Hui Qiu Richard Caldwell Dr. Lesley Liu-Bujalski Dr. Andreas Goutopoulos Reinaldo Jones Justin Potnick Dr. Brian Sherer Dr. Andrew Bender Dr. Roland Grenningloh Dr. Daigen Xu Dr. Anna Gardberg Dr. Igor Mochalkin Dr. Theresa Johnson Dr. Ariele Viacava Follis Jared Head Dr. Federica Morandi 《ChemMedChem》2019,14(2):217-223
Bruton's tyrosine kinase (Btk) is an attractive target for the treatment of a wide array of B-cell malignancies and autoimmune diseases. Small-molecule covalent irreversible Btk inhibitors targeting Cys481 have been developed for the treatment of such diseases. In clinical trials, probe molecules are required in occupancy studies to measure the level of engagement of the protein by these covalent irreversible inhibitors. The result of this pharmacodynamic (PD) activity provides guidance for appropriate dosage selection to optimize inhibition of the drug target and correlation of target inhibition with disease treatment efficacy. This information is crucial for successful evaluation of drug candidates in clinical trials. Based on the pyridine carboxamide scaffold of a novel solvent-accessible pocket (SAP) series of covalent irreversible Btk inhibitors, we successfully developed a potent and selective affinity-based biotinylated probe 12 (2-[(4-{4-[5-(1-{5-[(3aS,4S,6aR)-2-oxo-hexahydro-1H-thieno[3,4-d]imidazol-4-yl]pentanamido}-3,6,9,12-tetraoxapentadecan-15-amido)pentanoyl]piperazine-1-carbonyl}phenyl)amino]-6-[1-(prop-2-enoyl)piperidin-4-yl]pyridine-3-carboxamide). Compound 12 has been used in Btk occupancy assays for preclinical studies to determine the therapeutic efficacy of Btk inhibition in two mouse lupus models driven by TLR7 activation and type I interferon. 相似文献
8.
Anaerobic methane oxidation and aerobic methane production in an east African great lake (Lake Kivu) 总被引:1,自引:0,他引:1
Fleur A.E. Roland Cédric Morana François Darchambeau Sean A. Crowe Bo Thamdrup Jean-Pierre Descy Alberto V. Borges 《Journal of Great Lakes research》2018,44(6):1183-1193
We investigated CH4 oxidation in the water column of Lake Kivu, a deep meromictic tropical lake with CH4-rich anoxic deep waters. Depth profiles of dissolved gases (CH4 and N2O) and a diversity of potential electron acceptors for anaerobic CH4 oxidation (NO3?, SO42?, Fe and Mn oxides) were determined during six field campaigns between June 2011 and August 2014. Denitrification measurements based on stable isotope labelling experiments were performed twice. In addition, we quantified aerobic and anaerobic CH4 oxidation, NO3? and SO42? consumption rates, with and without the presence of an inhibitor of SO42?-reducing bacteria activity. Aerobic CH4 production was also measured in parallel incubations with the addition of an inhibitor of aerobic CH4 oxidation. The maximum aerobic and anaerobic CH4 oxidation rates were estimated to be 27?±?2 and 16?±?8?μmol/L/d, respectively. We observed a difference in the relative importance of aerobic and anaerobic CH4 oxidation during the rainy and the dry season, with a greater role for aerobic oxidation during the dry season. Lower anaerobic CH4 oxidation rates were measured in presence of molybdate in half of the measurements, suggesting the occurrence of linkage between SO42? reduction and anaerobic CH4 oxidation. NO3? consumption and dissolved Mn production rates were never high enough to sustain the measured anaerobic CH4 oxidation, reinforcing the idea of a coupling between SO42? reduction and CH4 oxidation in the anoxic waters of Lake Kivu. Finally, significant rates (up to 0.37?μmol/L/d) of pelagic CH4 production were also measured in oxygenated waters. 相似文献
9.
Nathália Maria P. Rocha e Silva Fabíola Carolina G. Almeida Fernanda Cristina P. Rocha e Silva Juliana M. Luna Leonie A. Sarubbo 《Journal of surfactants and detergents》2020,23(6):1111-1123
The use of toxic petroleum-based heavy oils is common in industrial processes. The cleaning of machines, equipment, and other surface covered in these oils is achieved with expensive products that are often also toxic and harmful to both the health of workers and the environment. The present paper proposes the development of a sustainable biodetergent made from plant-based materials. Tests were performed to determine the properties of the biodetergent in terms of its surfactant and emulsifying capacities, stability, toxicity, and the removal of heavy oil from glass plates and metallic surfaces. The formulation was composed of a natural solvent (cottonseed oil), a plant-based surfactant agent (saponin), and two natural stabilizers (carboxymethylcellulose and glycerine). The formulation was stable, nontoxic, and highly efficient, removing 100% of the heavy oil from glass and metallic surfaces. This solution developed in this study could be used in diverse industries with the need to clean machines and parts encrusted with oil and grease as well as the cleaning of floors covered with petroleum-based residues. A preliminary analysis of the economic feasibility of using the detergent was carried out at a Brazilian power plant. Besides the reduction in environmental impact due to the use of a nontoxic, biodegradable product as well as the reduction in health risks to workers associated with toxic cleaning products, this new product can have a considerable impact on the market as an environmentally friendly solution. 相似文献
10.
Roland E. Allen 《Journal of Modern Optics》2020,67(1):35-40
ABSTRACTRelatively simple but apparently novel ways are proposed for viewing three related subjects: black hole entropy, the black hole information paradox, and time travel paradoxes. (1) Gibbons and Hawking have completely explained the origin of the entropy of all black holes, including physical black holes – nonextremal and in 3-dimensional space – if one can identify their Euclidean path integral with a true thermodynamic partition function (ultimately based on microstates). An example is provided of a theory containing this feature. (2) There is unitary quantum evolution with no loss of information if the detection of Hawking radiation is regarded as a measurement process within the Everett interpretation of quantum mechanics. (3) The paradoxes of time travel evaporate when exposed to the light of quantum physics (again within the Everett interpretation), with quantum fields properly described by a path integral over a topologically nontrivial but smooth manifold. 相似文献