Fatty acids,sterols, and tocopherols composition in seed oil extracts from four moroccan ecotypes of Ceratonia siliqua L.

Morphological characterization was investigated by agro-morphological criteria related to carob seed size in four different moroccan regions collected in 2018 and 2019. There was no significant difference (p ≤ 0.05) on the seeds lengths and widths. However, a significant difference between seeds thickness and total seeds weight per pod (p ≤ 0.05) were observed between these four populations. The fatty acid, sterol, tocopherol, hydrocarbon, and the unoxygenated composition of carob seed extracts (Ceratonia siliqua L.) were studied. The mean fat yield of the seeds obtained is 1.53%–2.17%, 2.14%–2.15%, 1.61%–1.62%, 1.71%–1.75% for, respectively, the P1 (Meknes), P2 (Fez), P3 (Khemisset), and P4 (Marrakech) in 2018 and 2019. The seed oil was extracted with hexane and the analysis of the fatty fraction was performed by gas chromatography–mass spectrometry (GC–MS). Results show that the major fatty acids for 2018 and 2019 are linoleic acid (61.48%–61.52%, 52.12%–52.14%, 57.76%–58.15%, 61.33%–61.52%), palmitic acid (15.78%–15.81%, 16.44%–16.45%, 19.11%–18.37%, 20.24%–20.32%), oleic acid (11.03%–11.04%, 8.72%–8.82%, 8.51%–8.61%, 8.41%–8.53%), stearic acid (4.35%–3.14%, 5.40%–5.43%, 3.12%–3.13%, 0.96%–1.56%), and cerotic acid (0.62%–0.53%, 4.51%–4.52%, 4.03%–4.06%, 3.84%–3.87%). The unsaturated fatty acids (69.39% in 2018 and 69.68% in 2019) are the most dominant in the four seed extracts compared to the saturated fatty acids. In addition, the oil carob seeds analysis revealed the presence of γ-tocopherol, α-tocopherol and four sterols that included campesterol, stigmasterol, and β-sitosterol. Moreover, the determination of hydrocarbon and un-oxygenated compounds confirmed the existence of major compounds such as heptadecane, 2-methyltriacontane, 1-iodo hexadecane and 1-iodo octadecane. The hierarchical analysis based on the morphological and chromatographic characterization of the seeds allowed the identification of three groups. Consequently, the first group consisted of populations from Marrakesh (P4) and Khemisset (P3), the second group consisted of the P1 from Meknes, and the P2 from Fez constituted the third group.     

Crystal Structure and Physicochemical Properties of Two Supramolecular Compounds: (C4H8NH2)4[Mo8O26] and (NH4)Na2[AsIIIMo6O21(O2CCH2NH3)3]·8H2O

Two inorganic–organic hybrid supramolecular compounds based on polyoxometalates formulated as (C₄H₈NH₂)₄[Mo₈O₂₆] (1) and (NH₄)Na₂[As^IIIMo₆O₂₁(O₂CCH₂NH₃)₃]·8H₂O (2) have been synthesized by conventional solution method and characterized by infrared, UV–Vis and single-crystal X-ray diffraction analyses. Thermal analysis was performed to study their thermal stability. The atomic arrangement in compound (1) can be described as inorganic layers built by [Mo₈O₂₆]^4?, pyrrolidinium cations are embedded into layers. The fascinating structural feature of compound (2) is that the glycine molecules are bounded to two edge-sharing Mo centers via their carboxylate functionality leading to functionalized heteropolymolybdate [As^IIIMo₆O₂₁(O₂CCH₂NH₃)₃]^3?, extensive net hydrogen bonds between cations and anions contribute to the crystal packing. The electrochemical behavior of compound (2) has been studied.     

Extended Bayesian generalization model for understanding user’s intention in semantics based images retrieval

Multimedia Tools and Applications - Learning concepts from examples presented in user’s query and infer the other items that belong to this query is still a significant challenge for images...     

Effects of fermentation conditions and homogenization pressure on the rheological properties of Kefir

In this study, the effects of fermentation conditions (temperature and time) as well as homogenization pressure on the rheology and EPS production in Kefir made from bovine whole milk were investigated. Results showed that the rheological characteristics and EPS production are affected significantly (p < 0.05) by the fermentation temperature but not by the incubation time. Furthermore, the homogenization pressure was found to influence significantly (p < 0.05) the rheology but not the production of EPS in Kefir.     

Effect of some operating variables on the microstructure and physical properties of a novel Kefir formulation

In this work, the rheological and textural properties, water-holding capacity (WHC), syneresis, and microstructure of a novel formulation of Kefir were studied by varying the incubation time and temperature, as well as the ratio of peanut-milk and skimmed-milk. Generally, all the experimental responses resulted to be significantly affected (p < 0.05) by all dependent variables examined. Kefir WHC was not significantly influenced (p > 0.05) by the fermentation temperature.     

Transport properties study of supplementary cementitious materials: case of tuff,limestone filler and granodiorite

The aim of this research is to determine the effects of replacing cement with tuffs on the transport properties and service life of cement-based materials. Specimens were prepared replacing 5% and 15% by weight of cement with both white and brown tuffs. Additional specimens were prepared replacing cement with 5% and 15% limestone filler and granodiorite to compare the effects of these types of materials. For these four types of specimen as well as a control mortar with no cement replacement transport properties (gas permeability and chloride ingress) were measured as well as porosity and pore diameter. The transport properties were compared the changes in these porosity and pore diameter. Based on the results, white tuff significantly improves the transport properties of the mortars due to its pozzolanic reaction and that white tuff may be an economically and functionally viable replacement for cement where concrete durability is important. Pore diameter and porosity did not correlate well with transport properties.     

Electrical and Seismic Tomography Used to Image the Structure of a Tailings Pond at the Abandoned Kettara Mine, Morocco

The Kettara site (Morocco) is an abandoned pyrrhotite ore mine in a semi-arid environment. The site contains more than 3 million tons of mine waste that were deposited on the surface without concern for environmental consequences. Tailings were stockpiled in a pond, in a dyke, and in piles over an area of approximately 16?ha and have generated acid mine drainage (AMD) for more than 29?years. Geophysical methods have been used at the Kettara mine site to determine the nature of the geological substrate of the tailings pond, the internal structure of the mine wastes, and to investigate the pollution zones associated with sulphide waste dumps. Electrical resistivity tomography (ERT) and seismic refraction data were acquired, processed, and interpreted; the results from ERT and seismic refraction were complementary. A topographical survey of the tailings disposal area was also undertaken to estimate the volume of wastes and quantify the AMD process. Two-dimensional inverse models were used to investigate the geophysical data and indicated alteration zones at depth. It was determined that the material could be classified into three categories: tailings, with low resistivity (5?C15??? m) and low velocity (500?C1,800?m/s); altered, black shales, with intermediate resistivity (20?C60??? m) and velocity (2,000?C3,500?m/s), and; materials with high resistivity and velocity (>60????m and >4,000?m/s, respectively), including unaltered shales associated with quartzite seams. The low-resistivity zone generates AMD, which migrates downward through fractures and micro-fractures. The substrate is composed of broken and altered shale, which facilitates AMD infiltration.     

Adaptive type-2 fuzzy sliding mode controller for SISO nonlinear systems subject to actuator faults

In this paper, an adaptive type-2 fuzzy sliding mode control to tolerate actuator faults of unknown nonlinear systems with external disturbances is presented. Based on a redundant actuation structure, a novel type-2 adaptive fuzzy fault tolerant control scheme is proposed using sliding mode control. Two adaptive type-2 fuzzy logic systems are used to approximate the unknown functions, whose adaptation laws are deduced from the stability analysis. The proposed approach allows to ensure good tracking performance despite the presence of actuator failures and external disturbances, as illustrated through a simulation example.