Ablation behavior and mechanism of boron nitride - magnesium aluminum silicate ceramic composites in an oxyacetylene combustion flame

In the present study, ablation behavior and properties of BN-MAS (magnesium aluminum silicate) composites impinged with an oxyacetylene flame at temperatures up to 3100 °C were investigated. As ablation time ranged from 5 to 30 s, the mass and linear ablation rates increased from 0.0027 g/s and 0.001 mm/s to 0.0254 g/s and 0.087 mm/s, respectively. A SiO₂-rich protective oxide layer formed during the ablation process, which contributed to the oxidation resistance of the composites. Ablation products mainly consisted of magnesium-aluminum borosilicate glass, mullite, spinel and indialite. The thermal oxidation of h-BN during flame ablation and scouring of MAS by high-speed gas flow were the main ablation mechanisms.     

Landscaping Attributes and Property Buyers' Profiles: Their Joint Effect on House Prices

This paper investigates the effect of environmental features on house values while focusing on the interactions between landscaping attributes and home buyers' profile. The originality of this study rests on the assumption that, while neighbourhood characteristics translate into distinct sub-markets and primarily set the structure of house prices, individual home buyers' preferences, under specific market conditions, also affect values. The study benefits from two distinct, although related data sets on the single-family segment of Quebec City's housing market: while landscaping features were obtained via an extensive field survey of houses sold between 1993 and 2000, a detailed phone survey of related homeowners' family status, age and income profiles is being conducted since 2000. Findings suggest that household profile and structure do shape landscaping preferences and that utility patterns of homeowners may be best understood by looking at interactions between the two sets of variables. Considering that population aging is a major issue for economic and social planners, such a conclusion should be accounted for in housing policy design.     

Mapping of coastal-water turbidity using LANDSAT imagery

Secchi disk depth was recorded in the field all along the Swedish coastline and compared with LANDSAT data. Chromaticity analysis was applied in the evaluation to allow for Sun angle and atmospheric corrections. The data were used to study the relative nutrient and solids loading situations around the Swedish coast and as a basis for the applicability of laser bathymetry for water depth soundings     

Starch derivatives with high degree of functionalization. III. Influence of reaction conditions and starting materials on molecular structure of carboxymethyl starch

Carboxymethyl starch (CMS) was prepared in a completely heterogeneous procedure in a methanol/water slurry activated with aqueous sodium hydroxide (45%, w/v) using monochloroacetic acid as the etherifying agent. The influence of the reaction conditions and the type of starting starch (amylose content and preactivation) was evaluated in regard to the formation of the main repeating units (i.e., unfunctionalized and mono‐, di‐, tri‐, and tetra‐O‐carboxymethylated) and the pattern of functionalization within the anhydroglucose units (AGU). The reproducible synthesis gave products with a maximal degree of substitution of CM groups (DS_CM) of 0.66, which was reached in a one‐step synthesis. Repeated carboxymethylation led to products with a DS_CM of 0.88. As revealed by means of HPLC analysis after complete acidic depolymerization, in any sample the mono‐O‐carboxymethylated glucose (mono‐O‐CMglc) was preferably present while the di‐O‐CMglc was formed to a very low extent only. The tri‐O‐CMglc was found in some samples while tetra‐O‐CMglc was not detected. The mole fractions determined did not follow the simple Spurlin statistic as shown for CM cellulose synthesized under comparable conditions. Within the carboxymethylated AGUs a preferred functionalization at position 2 was analyzed by means of ¹H‐NMR spectroscopy after hydrolytic chain degradation. Consequently, the CMS samples synthesized contained mainly 2‐mono‐O‐CM‐AGU. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 2036–2044, 2001     

Retrotransposable elements R1 and R2 in the rDNA units of Drosophila mercatorum: abnormal abdomen revisited

R1 and R2 retrotransposable elements are stable components of the 28S rRNA genes of arthropods. While each retrotransposition event leads to incremental losses of rDNA unit expression, little is known about the selective consequences of these elements on the host genome. Previous reports suggested that in the abnormal abdomen (aa) phenotype of Drosophila mercatorum, high levels of rDNA insertions (R1) in conjunction with the under-replication locus (ur), enable the utilization of different ecological conditions via a population level shift to younger age. We have sequenced the R1 and R2 elements of D. mercatorum and show that the levels of R1- and R2-inserted rDNA units were inaccurately scored in the original studies of aa, leading to several misinterpretations. In particular, contrary to earlier reports, aa flies differentially underreplicate R1- and R2-inserted rDNA units, like other species of Drosophila. However, aa flies do not undergo the lower level of underreplication of their functional rDNA units (general underreplication) that is seen in wild-type strains. The lack of general underreplication is expected to confer a selective advantage and, thus, can be interpreted as an adaptation to overcome high levels of R1 and R2 insertions. These results allow us to reconcile some of the apparently contradictory effects of aa and the bobbed phenotype found in other species of Drosophila.     

The depolarization near-field scanning optical microscope: comparison of experiment and theory

The depolarization near-field scanning optical microscope allows for sub-wavelength optical resolution with uncoated optical fibre tips. We show by a simple thought experiment, by numerical solution of the Maxwell equations for a realistic geometry, and by direct experiments, that this novel apparatus images gradients of the dielectric function of a sample in the direction of the incident electric field vector. The near-field images obtained from experiment and theory agree well.     

Parallel Flow Asymmetries in Heat Exchangers

The effect of flow asymmetry was observed experimentally in vertical parallel channels of a continuous direct ohmic heater. While downward-oriented flow is evenly distributed at isothermal conditions, the flow rate in parallel channels differs in the case of heating due to buoyancy effects. Three different configurations of parallel flow (with and without internal heating in channels) are analyzed, giving critical values of Gr/Re or Ri = Gr/Re² and ensuring stable and even distribution of flow into parallel channels of vertically oriented heat exchangers or heaters. Experimental verification was based upon flow visualization (injection of a colored tracer and monitoring the tracer by a camera), measurement of temperature profiles, and stimulus response experiments using KCl as a tracer for conductivity methods (2 Pt conductivity probes) and Tc99 as a radioisotope tracer (collimated scintillation detectors).     

HPLC determination of polycyclic aromatic hydrocarbons (PAHs) in the littoral urban sewage area of cortiou (Marseille,France)

A selective method for determining polycyclic aromatic hydrocarbons (PAHs) in sediments using solid‐phase extraction and RP‐HPLC with fluorescence and UV detection is described. The complete analytical method is used to surface sediments from the creek of Cortiou (France). Sewage from the urban area of Marseille is delivered to the creek. PAH levels in sediments (µg/g) range between 2.251 µg/g (for the benzo(a)anthracene) and 相似文献