State-of-the-art technology: Recent investigations on laser-mediated synthesis of nanocomposites for environmental remediation

In both developing and industrialized/developed countries, various hazardous/toxic environmental pollutants are entering water bodies from organic and inorganic compounds (heavy metals and specifically dyes). The global population is growing whereas the accessibility of clean, potable and safe drinking water is decreasing, leading to world deterioration in human health and limitation of agricultural and/or economic development. Treatment of water/wastewater (mainly industrial water) via catalytic reduction/degradation of environmental pollutants is extremely critical and is a major concern/issue for public health. Light and/or laser ablation induced photocatalytic processes have attracted much attention during recent years for water treatment due to their good (photo)catalytic efficiencies in the reduction/degradation of organic/inorganic pollutants. Pulsed laser ablation (PLA) is a rather novel catalyst fabrication approach for the generation of nanostructures with special morphologies (nanoparticles (NPs), nanocrystals, nanocomposites, nanowires, etc.) and different compositions (metals, alloys, oxides, core-shell, etc.). Laser ablation in liquid (LAL) is generally considered a quickly growing approach for the synthesis and modification of nanomaterials for practical applications in diverse fields. LAL-synthesized nanomaterials have been identified as attractive nanocatalysts or valuable photocatalysts in (photo)catalytic reduction/degradation reactions. In this review, the laser ablation/irradiation strategies based on LAL are systematically described and the applications of LAL synthesized metal/metal oxide nanocatalysts with highly controlled nanostructures in the degradation/reduction of organic/inorganic water pollutants are highlighted along with their degradation/reduction mechanisms.     

Magnetic soy protein isolate–bovine serum albumin nanoparticles preparation as a carrier for inulinase immobilisation

Magnetic nanoparticles (NPs) were functionalised with soy protein isolate (SPI) and bovine serum albumin (BSA) for inulinase immobilisation. The results revealed the nanomagnetite size of about 50 nm with a polydispersity index (PDI) of 0.242. The average size of the SPI NPs prepared by using acetone was 80–90 nm (PDI, 0.277), and SPI–BSA NPs was 80–90 nm (PDI, 0.233), and their zeta potential was around −34 mV. The mean diameter of fabricated Fe₃ O₄ @SPI–BSA NPs was <120 nm (PDI, 0.187). Inulinase was covalently immobilised successfully through glutaraldehyde on Fe₃ O₄ @SPI–BSA NPs with 80% enzyme loading. Fourier transform infrared spectra, field emission scanning electron microscopy, and transmission electron microscopy images provided sufficient proof for enzyme immobilisation on the NPs. The immobilised inulinase showed maximal activity at 45°C, which was 5°C higher than the optimum temperature of the free enzyme. Also, the optimum pH of the immobilised enzyme was shifted from 6 to 5.5. Thermal stability of the enzyme was considerably increased to about 43% at 75°C, and K _m value was reduced to 25.4% after immobilisation. The half‐life of the enzyme increased about 5.13‐fold at 75°C as compared with the free form. Immobilised inulinase retained over 80% of its activity after ten cycles.Inspec keywords: magnetic particles, nanoparticles, proteins, molecular biophysics, nanofabrication, enzymes, Fourier transform spectra, infrared spectra, scanning electron microscopy, field emission ion microscopy, transmission electron microscopy, pH, biochemistry, nanobiotechnology, biomagnetism, electrokinetic effects, iron compoundsOther keywords: magnetic nanoparticles, soy protein isolate, bovine serum albumin, inulinase immobilisation, nanomagnetite, polydispersity index, SPI‐BSA NP, zeta potential, inulinase, glutaraldehyde, enzyme loading, Fourier transform infrared spectra, field emission scanning electron microscopy, transmission electron microscopy images, enzyme immobilisation, pH, size 80 nm to 90 nm, temperature 45 degC, temperature 75 degC, Fe₃ O₄      

Speech and music separation approaches - a survey

Multimedia Tools and Applications - With the growth of acoustic data in the development of multimedia tools, mobile phones and the Internet of Multimedia Things (IoMT), recent studies exploit...     

Creep analysis of an earth embankment on soft soil deposit with and without PVD improvement

In this paper, an anisotropic creep constitutive model, namely Creep-SCLAY1S is employed to study the installation effects of prefabricated vertical drains (PVDs) on the behavior of a full scale test embankment, namely Haarajoki embankment in Finland. The embankment was constructed on a natural soft soil with PVD installed to improve the drainage under one half of it. The Creep constitutive model used in this study, incorporates the effects of fabric anisotropy, structure and time within a critical state based framework. For comparison, the isotropic modified Cam clay (MCC) model and the rate-independent anisotropic S-CLAY1S model are also used for the analyses. The numerical predictions are compared with field measurements and the results indicate that the creep model provides an improved approximation of field settlements, and excess pore pressure build-up and dissipations. In addition, the application of two commonly used permeability matching techniques for two dimensional (2D) plane-strain analysis of the PVD problem is studied and the results are discussed highlighting their limitations and advantages.     

Application of anodized titanium for enhanced recruitment of endothelial progenitor cells

Objectives

To study the efficacy of an effective anodized titanium surface with enhanced attachment of endothelial progenitor cell (EPC).

Background

In-stent restenosis is a major obstacle for vascular patency after catheter-based intravascular interventions. Recently, stents that capture EPCs have been paid attention in order to make a functional endothelialized layer at the site of stent-induced endothelial denudation. Anodized titanium has been shown to enhance stem cell attachment. Anodization is a quick and inexpensive method, which can provide suitable stent surface.

Methods

Surface topography was examined by high-resolution scanning electron microscopy (SEM). Substrates were co-cultured with EPCs at second passage in 24-well culture plates. Evaluation of cell growth, proliferation, viability, surface cytotoxicity and cell adhesion was performed using 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) test and 4,6-diamidino-2-phenylindole dihydrochloride staining. For platelet attachment, platelets added to substrates were evaluated under SEM.

Results

The average MTT values for tissue culture polystyrene plate, unanodized and anodized titanium with nanostructure were equal to 0.49, 0.16 and 0.72, respectively (P < 0.05). The surface had no cytotoxic effects on cells. The average cell attachment results showed that 9,955 ± 461.18, 3,300 ± 197.98 and 11,359 ± 458.10 EPCs were attached per well of tissue culture polystyrene plate, unanodized and anodized titanium surfaces, respectively (P < 0.05).

Conclusions

Anodized titanium surfaces can be potentially applied for devices that need enhanced recruitment of EPCs. This unique property makes these anodized surfaces good and cheap candidates for designing cardiovascular medical devices as endovascular stents.     

Modelling stock selection using ordered weighted averaging operator

The main objective of stock selection is to select a set of assets in the stock market with high‐expected returns. There are many financial variables that affect the performance of stock firms. This paper proposes a novel linear programming model based on the ordered weighted averaging (OWA) operator for identifying superior stocks without requiring the re‐ordering process. The paper first converts a stock selection problem into a preference voting system by considering two different perspectives: an investor perspective in which the goal is to select stocks with the highest return, and a creditor perspective in which the goal is to maximize the repayment ability. The OWA operator is then used to formulate a linear programming model for identifying superior stocks. The usefulness of the proposed method in this paper is shown through an application in the Tehran stock market.     

Six common errors cause dangerous mistakes in interpretation of electron micrographs

The highly complex techniques of electron microscopy made it bound to the sensitive and critical micrograph analysis. The accurately interpreted micrographs are of paramount values in basic investigations. Interpretation skills and quality of the micrographs are the two fundamental keys in accomplishment of these goals but there are many mistakes and errors that can happen during the sample preparation, sectioning, EM operation, and photo publishing. The mentioned mistakes and errors effect directly in the final result which is a micrograph and can lead the analyzer who can be a pathologist to an interpretation followed by serious danger for patient. Artifacts caused by any given stimuli expected to be bothersome for investigators. Even best qualified equipments can be regarded as source of artifact generation. In this article, seven serious errors in electron micrographs which usually occur in transmission electron microscopy are addressed.     

A novel SOI MESFET to spread the potential contours towards the drain

ABSTRACT

This paper presents a new structure of Metal Semiconductor Field Effect Transistor (MESFET) for high power applications. One of the problems that we face in the design of the MESFET devices is that in most cases, the increase of breakdown voltage is accompanied by a decrease in the saturation drain current. Our aim to propose this structure is to improve these two parameters simultaneously. Using the insulator region under the sides of the gate (IR) and the hide field plate (HFP) in the buried oxide (BOX) are the fundamental solution for improving these parameters. We named the proposed structure as spread potential contours towards the drain MESFET (SPC-MESFET). By applying the proposed structure, the drain current and the breakdown voltage improve 20 and 27 percent compared to a conventional structure (C-MESFET), respectively. Therefore, the proposed device has a higher maximum power density than the C-MESFET structure. Also, this idea reduces the gate capacitance and thus the frequency characteristics such as cut off frequency (f_T), maximum oscillation frequency (f_max), and Maximum Available Gain (MAG) improve in comparison with the C-MESFET structure.     

Application of Optimistic and Pessimistic OWA and DEA Methods in Stock Selection

One of the main objectives of fund managers in financial service industry is to select superior stocks by analyzing financial ratios. This paper proposes a novel methodology for stock selection by integrating optimistic and pessimistic ordered weighted averaging (OWA) and data envelopment analysis (DEA) methods. The paper first reveals the drawback of using the standard DEA models for stocks evaluation and then proposes a new method by using the OWA operator. Unlike the classical DEA, the proposed method in this paper does not involve the specification of inputs and outputs. The paper incorporates optimistic and pessimistic scenarios and generates interval OWA scores for all stocks. This is followed by using appropriate interval DEA models for selecting superior stocks. The proposed method in this paper is applied to identify high financial performance stocks in the Tehran stock market.