Zein-based anti-browning cling wraps for fresh-cut apple slices

The usage of cling wraps is emerging as an easy and cost-effective approach to protect fresh-cut fruits and vegetables from dust, whilst improving visual appeal on retail counters. This study focused on developing an alternate, protein-based packaging material as a food grade cling wrap for food packaging applications. Zein-based cling wraps were produced, and their physical and mechanical characteristics were evaluated and compared with conventionally used chitosan biopolymer films and commercial synthetic polymer films. Antioxidant potential of the prepared films was studied, and the effectiveness of the developed films as anti-browning cling wraps was evaluated using studies conducted on fresh-cut apple slices at ambient conditions. Anti-browning effects were in par with polymeric counterparts; however, zein cling wraps could better prevent weight loss in apple slices. Zein-based films can be adopted as biodegradable food grade cling wraps as an alternative to chitosan and synthetic polymeric materials.     

Optimization of CdO nanoparticles by Zr<Superscript>4+</Superscript> doping for better photocatalytic activity

Chemically controlled co-precipitation method has been adopted for the fabrication of pure and different wt% Zr doped CdO photocatalysts. Conventionally, the crystallite size and crystalline phase of CdO are in the midst of the parameters involved in the control of the photocatalytic activity. Aiming utterly at the size effect that modifies other attributes which are important to assess the photocatalytic activity of nanometric CdO, it was explored to synthesize CdO nanoparticles with controlled size, highly comparable morphology and analogous phase. The crystal structure and the crystallite size were estimated from the X-ray diffraction patterns and were confirmed through transmission electron microscope. The degree of crystallinity varied on Zr doping and the calculated crystallite sizes were in the range of 16–81 nm. The dopant ion Zr⁴⁺ have been detected through X-ray photoelectron spectroscopy (XPS) analysis signifying the dopant to substitute for cadmium (Cd²⁺) in the lattice of CdO. Particle size dependent optical band gaps calculated in the range 2.02–2.57 eV informed the viability of the materials to initiate photocatalytic reaction in the visible light region. Lesser recombination rate of the generated electrons and holes under light irradiation produced low intense photoluminescence peaks that displayed the appropriateness as photocatalysts. Zr⁴⁺ doping resulted in the enhancement of photocatalytic activity, evaluated by monitoring the degradation of methylene blue solution. 0.5 wt% Zr doped CdO nanoarticles calcined at 400 °C exhibited the highest photocatalytic activity with better percentage of color abatement (80.95%). The pseudo-first-order reaction rate became faster on Zr doping such that the rate constant is ~?0.4–0.5 h^?1 for Zr doped CdO while that for pure CdO is ~?0.3 h^?1.     

Metasurface based pattern reconfigurable antenna for 2.45 GHz ISM band applications

In this article, a Z‐shaped antenna is designed for 2.45 GHz ISM band applications. The proposed antenna is surrounded by metasurface‐based unit cells. The unit cells are designed to reflect for the proposed frequency. Each of this unit cells are activated with the help of a diode. Unit cell is considered active by switching on the diode of respective unit cell. According to the activation of unit cell the pattern of the antenna will be reconfigured. The 2.45 GHz ISM band pattern reconfigurable microstrip antenna is presented. The radiation pattern of the antenna can be steered toward a desired direction by activating appropriate metasurface unit cell, minimizing the interference and optimizing medium usage. The proposed antenna performance is presented with the help of reflection coefficient and the pattern steerable capability by activating metasurface unit cells. The proposed antenna is having azimuth‐pattern reconfigurable capability around 360°.     

Bidirectional energy storage photovoltaic grid-connected inverter application system

A novel topology of the bidirectional energy storage photovoltaic grid-connected inverter was proposed to reduce the negative impact of the photovoltaic grid-connected system on the grid caused by environmental instability. Using the proposed Inverter as a UPS power supply in case of a grid failure, storage electrical energy and regulating the energy delivered to the grid for reducing the pressure on the grid. A new artificial fish-swarm algorithm and variable step voltage perturbation method were presented to track the maximum power point of the solar panels. Analysis was done to reduce the output ripple of the inverter and sinusoidal pulse width modulation (SPWM) was selected to control the inverter. Model simulation was performed using PSpice software to obtain the volt-ampere characteristic curve of the solar panel output. The solar array simulator was used to verify the effect of maximum power point tracking at different light intensities. The study concludes that the maximum power point tracking (MPPT) efficiency of the bidirectional energy storage photovoltaic grid-connected inverter designed was as high as 99.9%. The distortion rate of the grid-connected current waveform was within 2% and the DC current component was less than 0.5%. The output voltage and power were in full compliance with the grid connection standard.     

Statistical method‐based calibration and validation of a solid oxide fuel cell model

A 2‐stage model validation strategy for the previously developed solid oxide fuel cell model using the data from custom‐designed experiments is presented. The strategy is based on the identification of model structural and parametric errors. In the preliminary validation, the causes that can result in the voltage error during changing temperature and fuel flow rate conditions are analysed. It is identified that the convection heat transfer process contributes significantly towards the cell performance in a temperature controlled test environment. Rectification of this error results in the reduction of the maximum voltage error from 14% to 0.5%. Graphical methods for data visualisation are utilised to examine goodness of fit of the model. Input sensitivity analysis reveals that the air flow rate has negligible influence on the output quantities of current density, fuel utilisation, and cell temperature owing to temperature‐controlled conditions of the test. Parameter sensitivity analysis through the elementary effects method reveals that most of the electrochemical parameters in general and the activation energies in particular have dominant effects on the considered system outputs. Model validation is carried out through a classical statistical method of hypothesis testing by using the parameter uncertainty information obtained through nonlinear least squares fitting. The efficacy of the model validation strategy is demonstrated through the model acceptance with 8% maximum error in cell current.     

Corrosion Inhibition of Mild Steel in Aqueous HCl using Bitter Leaf and Fenugreek Seed Oils

Protection of Metals and Physical Chemistry of Surfaces - Bitter leaf and Fenugreek seed oils were extracted from their parent seed plants for use as corrosion inhibitors for mild steel in HCl....