全文获取类型
收费全文 | 415篇 |
免费 | 34篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 5篇 |
化学工业 | 124篇 |
金属工艺 | 4篇 |
机械仪表 | 12篇 |
建筑科学 | 18篇 |
能源动力 | 12篇 |
轻工业 | 122篇 |
水利工程 | 10篇 |
石油天然气 | 3篇 |
无线电 | 13篇 |
一般工业技术 | 66篇 |
冶金工业 | 26篇 |
原子能技术 | 2篇 |
自动化技术 | 33篇 |
出版年
2024年 | 1篇 |
2023年 | 5篇 |
2022年 | 3篇 |
2021年 | 27篇 |
2020年 | 20篇 |
2019年 | 11篇 |
2018年 | 15篇 |
2017年 | 20篇 |
2016年 | 14篇 |
2015年 | 14篇 |
2014年 | 26篇 |
2013年 | 28篇 |
2012年 | 41篇 |
2011年 | 33篇 |
2010年 | 21篇 |
2009年 | 26篇 |
2008年 | 21篇 |
2007年 | 22篇 |
2006年 | 14篇 |
2005年 | 8篇 |
2004年 | 6篇 |
2003年 | 10篇 |
2002年 | 11篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1997年 | 5篇 |
1996年 | 6篇 |
1995年 | 6篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1991年 | 5篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1985年 | 3篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有450条查询结果,搜索用时 15 毫秒
1.
Premnath Kumar Arun Prasad Murthy Leticia S. Bezerra Bibiana K. Martini Gilberto Maia Jagannathan Madhavan 《International Journal of Hydrogen Energy》2021,46(1):622-632
Hydrogen production through water splitting is an efficient and green technology for fulfilling future energy demands. Carbon nanotubes (CNT) supported Ni2P has been synthesized through a simpler hydrothermal method. Ni2P/CNT has been employed as efficient electrocatalysts for hydrogen and oxygen evolution reactions in acidic and alkaline media respectively. The electrocatalyst has exhibited low overpotential of 137 and 360 mV for hydrogen and oxygen evolution reactions respectively at 10 mA cm?2. Lower Tafel slopes, improved electrochemical active surface area, enhanced stability have also been observed. Advantages of carbon support in terms of activity and stability have been described by comparing with unsupported electrocatalyst. 相似文献
2.
Marcelo Fernandes Cipreste Michele Rocha de Rezende Marlon Luiz Hneda Anderson Maia Peres Alexandre Alberto Chaves Cotta Verônica de Carvalho Teixeira Waldemar Augusto de Almeida Macedo Edésia Martins Barros de Sousa 《Ceramics International》2018,44(15):17800-17811
Hydroxyapatite (HA) nanoparticles (NPs) doped with different radioisotopes for use as theranostic systems play an important role in scientific research nowadays due to their ability to simultaneously act in the treatment and diagnosis of various types of cancers. In this work, we describe the synthesis and characterization of a hydroxyapatite/tenorite nanocomposite functionalized with folic acid, representing a nanotheranostic material with potential for application as an agent in positron emission tomography imaging systems and to act specifically in the treatment and diagnosis of osteosarcoma. 64Cu and 32P were produced by nuclear activation in the TRIGA reactor at CDTN. The obtained samples were characterized by XRD with Rietveld refinement, XAFS, SEM, BET, TGA, FTIR, CHN, ICP-AES, XPS and gamma spectroscopy. We investigated how CuO grows in HA NPs, the stability of the interactions between CuO and HA constituents and the interactions between folic acid and the surface of the HA NPs. The results indicate the formation of a second phase (tenorite) besides hydroxyapatite, and that the interactions between the two phases are stable, resulting in a nanocomposite. Furthermore, the activation of 64Cu and 32P inside the HA matrix, through the exposition to a neutron flux, produces a theranostic material of interest for biological tests. 相似文献
3.
This paper addresses reliable and efficient calculation of the mode of a multivariate sample, which is a classical fusion function. In particular, we focus on the inputs given on the unit simplex, when aggregating elements of Atanassov intuitionistic fuzzy sets, interval-valued fuzzy sets and their extensions, as well as compositional data. We outline the use of a specially designed 2-additive fuzzy measures and the Choquet integral for the purposes of reducing computational complexity in higher dimensions. We present computational analysis and benchmark four different methods of density-based mode estimation. 相似文献
4.
A series of 16-layer polypropylene/flame retardant (PP/FR) film/foam composite structures were produced by microlayer coextrusion. A highly branched PP was used in the foam layers to increase strain hardening and cell stability, while the PP used in the film layers was a high shear viscosity grade to confine bubble growth. In addition to improved tensile properties, the PP/FR composite film/foams exhibited five times the compression modulus of PP/FR composite foams at each FR loading level. The thermal stabilities of the composites were investigated, exhibiting three step decompositions. The FR particles were effective in decreasing flammability by forming intumescent char. The PP/FR-film/foam-20 showed self-extinguishing behavior in a modified vertical burn test, while the PP/FR-foam-20 sample continued to burn. Cone calorimetry demonstrated that PP/FR film/foams had lower heat release than PP/FR foams due to the unique alternating film/foam structure of PP/FR film/foams. Scanning electron microscopy imaging of the residual chars from fire testing that the PP/FR composite film/foams showed a more continuous protective char surface when compared with PP/FR composite foams at each FR concentration. The combined data indicate that the formation of a surface film on top of a foam ensures a robust intumescent fire protective barrier for partly foamed materials and shows a new way toward lightweight materials with improved fire safety performance. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48552. 相似文献
5.
Anabela Santos Ângelo Luís Susana Ferreira Ana P. Duarte 《International Journal of Food Science & Technology》2019,54(3):862-870
In this work, heather and its flowers were studied regarding their antioxidant and antimicrobial activities. Plants were subjected to ultrasound-assisted methanolic extraction followed by fractionation. A phytochemical characterisation of extracts content in total phenols and flavonoids, and their antioxidant activity was performed. The antimicrobial activity was evaluated through the determination of minimum inhibitory concentration and by bioautography. Following, studies on the antilisterial potential were carried out by: time-kill curves, inhibition of biofilm formation and tolerance of Listeria monocytogenes to adverse conditions. The results evidenced the antioxidant activity in both extracts, as well as, the antimicrobial activity against Gram-positive bacteria. Concerning the evaluation of the antilisterial potential, a bacteriostatic behaviour and inhibition of biofilms formation ability were observed. Listeria monocytogenes showed an increased susceptibility to adverse conditions when preincubated with extracts. Thus, heather and its flowers may be a source of new compounds with antilisterial activity potential. 相似文献
6.
Diogo Mendes David Sousa Ana C. Cerdeira Laura C.J. Pereira Ana Marques João Murta-Pina Anabela Pronto Isabel Ferreira 《Ceramics International》2021,47(1):381-387
High-performance YBCO 123 (YBa2Cu3O7-x) bulk superconductor samples were produced using the 3D printing paste-extrusion technique. The YBCO powder obtained after sintering a pre-mixture of Y2O3, BaCO3 and CuO powders at 950 °C was used in the formulation of pastes for extrusion in a 3D freeform printer. The 3D samples printed from pastes containing the pre-mixture powders were sintered, while those produced using the YBCO powder were not. X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and Raman analysis all confirmed the YBCO phase after sintering, both in the powder and in the samples made with the pre-mixture. Scanning electron microscopy (SEM) images revealed powder grains of heterogeneous size and geometry, as well as grain aggregation, in the sintered samples. Superconducting quantum interference device (SQUID) measurements taken within a fixed magnetic range revealed that the printed pieces have a typical magnetization temperature of 92 K, reaching ?1.43 emu/g and ?1.59 emu/g respectively a zero-field-cooled magnetization (ZFC) for sintered and non-sintered printed samples. 相似文献
7.
Erivan de Souza Oliveira Mighay Lovera Valessa Rios Pires Francisco Rogênio da Silva Mendes Nadya Virginia Lima Peixoto Maia João Pedro Viana Rodrigues Maria do Socorro Rocha Bastos Huai N. Cheng Atanu Biswas Renato de Azevedo Moreira Ana Cristina de Oliveira Monteiro Moreira 《Journal of Food Processing and Preservation》2022,46(3):e16408
8.
奥斯卡·尼迈耶——拉戈阿住宅与卡诺阿斯住宅 总被引:1,自引:0,他引:1
本文旨在分析巴西建筑师奥斯卡·尼迈耶在1942年与1953年所建造的两幢自宅,归纳在其空间构成、结构以及体验上的异同,重点在于分析这两幢住宅与各自所处的环境关系。文章结论系于尼迈耶如何将柯布西耶的设计理念与巴西的环境相结合。在第一幢住宅中,他严格地遵守柯布所设定的原则,而其后则在卡诺阿斯住宅的自由形体中作出种种发展与修改。在第二幢住宅中,建筑与自然紧密联系,并可以在可视性与可达性上通过空间句法分析证明。同时也可认为拉戈阿住宅功能被明确区分为室内与室外两个独立部分,而卡诺阿斯住宅则作为一个完整的整体体系。全部的研究基于柯布西耶理念背景以及巴西自由形式运动。 相似文献
9.
Leandro A. Villas Daniel L. Guidoni Guilherme Maia Richard W. Pazzi Jó Ueyama Antonio A. F. Loureiro 《Wireless Networks》2015,21(2):485-498
Localization and synchronization are fundamental services for many applications in wireless sensor networks (WSNs), since it is often required to know the sensor nodes’ position and global time to relate a given event detection to a specific location and time. However, the localization and synchronization tasks are often performed after the sensor nodes’ deployment on the sensor field. Since manual configuration of sensor nodes is usually an impractical activity, it is necessary to rely on specific algorithms to solve both localization and clock synchronization problems of sensor nodes. With this in mind, in this work we propose a joint solution for the problem of 3D localization and time synchronization in WSNs using an unmanned aerial vehicle (UAV). A UAV equipped with GPS flies over the sensor field broadcasting its geographical position. Therefore, sensor nodes are able to estimate their geographical position and global time without the need of equipping them with a GPS device. Through simulation experiments, we show that our proposed joint solution reduces time synchronization and localization errors as well as energy consumption when compared to solutions found in the literature. 相似文献
10.
Vivek Pandey Michael Seese João M. Maia David A. Schiraldi 《Polymer Engineering and Science》2020,60(10):2511-2516
Three chain extenders, pyromellitic dianhydride (PMDA), ethylene carbonate (EC), and a polymeric-epoxide, were investigated for improving recycled p(ethylene terephthalate) (r-PET) properties with melt extrusion. The amount of additives and processing temperatures were also varied to check for melt degradation. Small amplitude oscillatory shear experiments were performed to probe rheological changes with different chain extenders. Capillary rheometry with haul-off was also performed to measure extensional viscosity and melt strength. Higher loadings of the chain extenders were found to improve properties of r-PET. These chain extenders definitely increased melt viscosities when incorporated at the higher level of the ranges examined, matching that of virgin PET. EC addition resulted in high shear thinning of the polymer. Epoxy and PMDA added to r-PET produced products with the same extensional viscosity as v-PET. Haul-off experiments demonstrate superior performance by epoxy-modified r-PET compared to v-PET. 相似文献