The three Rs of river ecosystem resilience: Resources,recruitment, and refugia

Resilience in river ecosystems requires that organisms must persist in the face of highly dynamic hydrological and geomorphological variations. Disturbance events such as floods and droughts are postulated to shape life history traits that support resilience, but river management and conservation would benefit from greater understanding of the emergent effects in communities of river organisms. We unify current knowledge of taxonomic‐, phylogenetic‐, and trait‐based aspects of river communities that might aid the identification and quantification of resilience mechanisms. Temporal variations in river productivity, physical connectivity, and environmental heterogeneity resulting from floods and droughts are highlighted as key characteristics that promote resilience in these dynamic ecosystems. Three community‐wide mechanisms that underlie resilience are (a) partitioning (competition/facilitation) of dynamically varying resources, (b) dispersal, recolonization, and recruitment promoted by connectivity, and (c) functional redundancy in communities promoted by resource heterogeneity and refugia. Along with taxonomic and phylogenetic identity, biological traits related to feeding specialization, dispersal ability, and habitat specialization mediate organism responses to disturbance. Measures of these factors might also enable assessment of the relative contributions of different mechanisms to community resilience. Interactions between abiotic drivers and biotic aspects of resource use, dispersal, and persistence have clear implications for river conservation and management. To support these management needs, we propose a set of taxonomic, phylogenetic, and life‐history trait metrics that might be used to measure resilience mechanisms. By identifying such indicators, our proposed framework can enable targeted management strategies to adapt river ecosystems to global change.     

Long-term sensor measurements of lung deposited surface area of particulate matter emitted from local vehicular and residential wood combustion sources

Abstract

Lung deposited surface area (LDSA) is a relatively new metric that has been argued to be more accurate at predicting health effects from aerosol exposure. For typical atmospheric aerosol, the LDSA concentration depends mainly on the concentration of ultrafine particles (e.g. vehicular exhaust emissions and residential wood combustion) and therefore optical methods cannot be used to measure and quantify it. The objective of this study was to investigate and describe typical characteristics of LDSA under different urban environments and evaluate how a diffusion charging-based Pegasor AQ Urban sensor (Pegasor Ltd., Finland) can be used as an alternative to optical sensors when assessing local combustion emissions and respective LDSA concentrations. Long-term (12?months) sensor measurements of LDSA were carried out at three distinctly different measurement sites (four sensor nodes) in the Helsinki metropolitan area, Finland. The sites were affected mainly by vehicular exhaust emission (street canyon and urban background stations) and by residential wood combustion (two detached housing area stations). The results showed that the accuracy of the AQ Urban was good (R² = 0.90) for the measurement of LDSA when compared to differential mobility particle sizer. The mean concentrations of LDSA were more than twice as high at the street canyon (mean 22 µm² cm^?3) site when compared to the urban background site (mean 9.4 µm² cm^?3). In the detached housing area, the mean concentrations were 12 µm² cm^?3, and wood combustion typically caused high LDSA peaks in the evenings. High correlations and similar diurnal cycles were observed for the LDSA and black carbon at street canyon and urban background stations. The utilization of a small-scale sensor network (four nodes) showed that the cross-station variability in hourly LDSA concentrations was significant in every site, even within the same detached housing area (distance between the two sites ～670?m).     

The stiffness of laser stake welded T-joints in web-core sandwich structures

The purpose of this paper is to describe experiments carried out on laser stake welded T-joints of web-core steel sandwich structures. A special test setup was developed to measure the shear-induced rotation at the T-joint. The ratio of the shear force to rotation angle gave the joint stiffness. This stiffness was measured for specimens with two different face-plate thicknesses. The influence of weld thickness, root gap and occurrence of contact were further investigated with finite element simulations. Finally, the shear stiffness of the sandwich structure transverse to the web plate direction was determined using the experimentally obtained average joint stiffness value. The validation of the shear stiffness was carried out by considering a beam in four-point bending. The agreement between calculated deflection and stress and experimental results was found to be good.     

Microstructure,Phase Occurrence,and Corrosion Behavior of As-Solidified and As-Annealed Al-Pd Alloys

In the present work, we studied the microstructure, phase constitution, and corrosion performance of Al₈₈Pd₁₂, Al₇₇Pd₂₃, Al₇₂Pd₂₈, and Al₆₇Pd₃₃ alloys (metal concentrations are given in at.%). The alloys were prepared by repeated arc melting of Al and Pd granules in argon atmosphere. The as-solidified samples were further annealed at 700 °C for 500 h. The microstructure and phase constitution of the as-solidified and as-annealed alloys were studied by scanning electron microscopy, energy-dispersive x-ray spectroscopy, and x-ray diffraction. The alloys were found to consist of (Al), ε _n (~ Al₃Pd), and δ (Al₃Pd₂) in various fractions. The corrosion testing of the alloys was performed in aqueous NaCl (0.6 M) using a standard 3-electrode cell monitored by potentiostat. The corrosion current densities and corrosion potentials were determined by Tafel extrapolation. The corrosion potentials of the alloys were found between ? 763 and ? 841 mV versus Ag/AgCl. An active alloy dissolution has been observed, and it has been found that (Al) was excavated, whereas Al in ε _n was de-alloyed. The effects of bulk chemical composition, phase occurrence and microstructure on the corrosion behavior are evaluated. The local nobilities of ε _n and δ are discussed. Finally, the conclusions about the alloy’s corrosion resistance in saline solutions are provided.     

Prediction of traditionally utilised wheat dough technological quality parameters from Mixolab values: development and evaluation of regression models

The research was conducted with the aim to investigate the possibility of Farinograph, Extensograph and Amylograph values prediction with linear and/or multiple Mixolab regression models. In total, 163 flour samples were divided based on Machalanobis distances into three sets: prediction, validation and external sample set. Determination coefficients ranged from 0.145 to 0.640 for linear regression models and from 0.279 to 0.739 for multiple regression models. Internal and external validation of developed regression models was conducted. Testing of developed models resulted in a high share of samples for which predicted values were out of the ranges of method official reproducibility and a high share of samples for which predicted values were out of the quality level range obtained by analytical measurement. It was concluded that it is impossible to develop applicable regression models for prediction of Farinograph, Extensograph and Amylograph parameters on the basis of Mixolab values from standard protocol.     

A Partial Isothermal Section at 1000 °C of Al-Mn-Fe Phase Diagram in Vicinity of Taylor Phase and Decagonal Quasicrystal

Altogether 19 alloys of an Al-Mn-Fe system with compositions near to the Taylor phase and/or the decagonal quasicrystal were characterised by the x-ray diffraction and the energy-dispersive x-ray spectroscopy coupled with the scanning electron microscopy, after annealing at 1000 °C for 330 h. The obtained experimental results were used to propose a partial isothermal section at 1000 °C of the Al-Mn-Fe phase diagram. The ternary T-phase area of an untypical saddle shape was found to touch the Al-Mn binary one. The γ₂-phase was found to be stable between 2 and 30 at.% of Fe at 1000 °C and boundaries between γ₁- and γ₂-areas are expected to be located very close to the Al-Mn binary.     

Structure formation mechanisms in consolidating pigment coatings—Simulation and visualisation

Microstructure development in consolidating pigment coating layers was studied in terms of particle flocculation and clustering mechanisms utilising a 3D particle dynamics model. The model includes hydrodynamic forces, colloidal interactions as well as the Brownian motion. The influence of colloidal interactions and drying strategy on the coating layer thickness development and internal solid concentration gradients, was investigated. A low particle surface potential resulted in the formation of porous particle networks, which impeded the shrinkage of the coating layer. At higher surface potentials particles arranged into denser structures, whereby the solids concentration profile could be controlled by the drying. Low electrostatic double layer thicknesses allowed sharp concentration gradients to form as result of the applied drying strategy. At high double layer thicknesses, the structure formation was similar regardless of drying strategy. This work elucidates the combined effect of drying conditions and colloidal suspension properties on coating microstructure development. Furthermore, the results aid in the understanding of how coating suspension additives may influence the structure development of the coating layer.     

Photoswitchable Superabsorbency Based on Nanocellulose Aerogels

Chemical vapor deposition of a thin titanium dioxide (TiO₂) film on lightweight native nanocellulose aerogels offers a novel type of functional material that shows photoswitching between water‐superabsorbent and water‐repellent states. Cellulose nanofibrils (diameters in the range of 5–20 nm) with native crystalline internal structures are topical due to their attractive mechanical properties, and they have become relevant for applications due to the recent progress in the methods of their preparation. Highly porous, nanocellulose aerogels are here first formed by freeze‐drying from the corresponding aqueous gels. Well‐defined, nearly conformal TiO₂ coatings with thicknesses of about 7 nm are prepared by chemical vapor deposition on the aerogel skeleton. Weighing shows that such TiO₂‐coated aerogel specimens essentially do not absorb water upon immersion, which is also evidenced by a high contact angle for water of 140° on the surface. Upon UV illumination, they absorb water 16 times their own weight and show a vanishing contact angle on the surface, allowing them to be denoted as superabsorbents. Recovery of the original absorption and wetting properties occurs upon storage in the dark. That the cellulose nanofibrils spontaneously aggregate into porous sheets of different length scales during freeze‐drying is relevant: in the water‐repellent state they may stabilize air pockets, as evidenced by a high contact angle, in the superabsorbent state they facilitate rapid water‐spreading into the aerogel cavities by capillary effects. The TiO₂‐coated nanocellulose aerogels also show photo‐oxidative decomposition, i.e., photocatalytic activity, which, in combination with the porous structure, is interesting for applications such as water purification. It is expected that the present dynamic, externally controlled, organic/inorganic aerogels will open technically relevant approaches for various applications.