Revealing Nanomechanical Domains and Their Transient Behavior in Mixed-Halide Perovskite Films

Halide perovskites are a versatile class of semiconductors employed for high performance emerging optoelectronic devices, including flexoelectric systems, yet the influence of their ionic nature on their mechanical behavior is still to be understood. Here, a combination of atomic-force, optical, and compositional X-ray microscopy techniques is employed to shed light on the mechanical properties of halide perovskite films at the nanoscale. Mechanical domains within and between morphological grains, enclosed by mechanical boundaries of higher Young's Modulus (YM) than the bulk parent material, are revealed. These mechanical boundaries are associated with the presence of bromide-rich clusters as visualized by nano-X-ray fluorescence mapping. Stiffer regions are specifically selectively modified upon light soaking the sample, resulting in an overall homogenization of the mechanical properties toward the bulk YM. This behavior is attributed to light-induced ion migration processes that homogenize the local chemical distribution, which is accompanied by photobrightening of the photoluminescence within the same region. This work highlights critical links between mechanical, chemical, and optoelectronic characteristics in this family of perovskites, and demonstrates the potential of combinational imaging studies to understand and design halide perovskite films for emerging applications such as photoflexoelectricity.     

Design and fabrication of thermoelectric waste heat reutilization system—possible industrial application

The current article discussed the detail design and development of an experimental test rig to derive usable energy by utilizing the waste heat energy through a heat exchanger made of Bi₂Te₃ material. The accuracy including the efficiency of the fabricated device is demonstrated further by verifying the associated parameter through a simulation model (commercial finite element package, ANSYS 15.0). To imitate the waste hot air from the industry is achieved via a heat gun and fed to the test rig for the generation of thermoelectric power. The simulation model accuracy has been demonstrated by juxtaposing the associated experimental data and computational readings. Subsequently, the feasibility and optimum range of design parameters are established by comparing the experimental and the simulation data (triggered temperature difference, voltage output, and heat flux) generated at the interface of the thermoelectric power generators. In addition, the coefficient of determination (R²) value has been evaluated statistically and verified with the current experimental results for the demonstration of the relevancy. The statistical study shows the existence of the correlation between the current experimental and the simulation model. Also, the experimental result indicates the possible implementation of the newly developed system for the recovery from the waste heat either the automobile exhaust or any other kind of dissipated heat from the industries.     

Effect of pH on the detailed chemical nature and metal-carbonate species in as synthesized zirconia alumina composites

Zirconia was deposition precipitated on γ-alumina in pH range 7-10 from zirconium oxy-nitrate and soda ash. Zirconium formed its hydroxycarbonate as deduced from ICP-EOS, CHN, and TGA-MS. Higher pH favored formation of carbonate species of zirconium over its hydroxide. TGA-MS indicated formation of three different types of carbonate species. FTIR results corroborated this. Monodentate metal carbonate was observed irrespective of pH of preparation. In addition, bridged bidentate species formed at pH ≤ 8 which changed to chelating bidentate at pH > 8. XRD indicated that all the samples formed tetragonal-zirconia upon calcination irrespective of pH of preparation. Higher pH resulted in smaller crystallites of t-ZrO₂. Changes in chemical moiety with pH reflected on acidity and the deactivation rate for 2-methyl-3-butyn-2-ol which decreased by two orders of magnitude in samples prepared at higher pH. Surface area and pore volume benefited from deposition precipitation. SEM-EDAX showed reasonable distribution of zirconia over γ-Al₂O₃.     

Studies on ballistic parameters of di-butyl phthalate-coated triple base propellant used in large caliber artillery gun ammunition

Triple base propellant (TBP) containing mainly nitrocellulose, nitroglycerine, and nitroguanidine has been manufactured and coated with plasticizer in the present work. The aim was to study ballistics of di-butyl phthalate (DBP)-coated TBP. DBP solution in ethanol containing nitrocellulose dope was used for coating onto the propellant grains. DBP-deterred propellant showed inhibition to burning, resulting in lowering the values of ballistic parameters namely peak pressure (P_max), dP_max, pressure index (α), and burning rate coefficient (β) during closed vessel firing. Increase in percentage of DBP in coating solution led to further decrease in ballistic parameters. Dynamic evaluation of the surface-moderated propellant showed comparatively lower muzzle velocity and chamber pressure for deterred propellant batches without leaving any unburnt particles in gun chamber at subzero temperatures with the lowest possible charge mass. The DBP-coated propellant can be useful in 155-mm artillery gun to achieve higher loading density as it has lower flame temperature and chamber pressure as compared to uncoated propellant which will result in increasing barrel life due to reduction in the barrel erosion.     

An automated software reliability prediction system for safety critical software

Software reliability is one of the most important software quality indicators. It is concerned with the probability that the software can execute without any unintended behavior in a given environment. In previous research we developed the Reliability Prediction System (RePS) methodology to predict the reliability of safety critical software such as those used in the nuclear industry. A RePS methodology relates the software engineering measures to software reliability using various models, and it was found that RePS’s using Extended Finite State Machine (EFSM) models and fault data collected through various software engineering measures possess the most satisfying prediction capability. In this research the EFSM-based RePS methodology is improved and implemented into a tool called Automated Reliability Prediction System (ARPS). The features of the ARPS tool are introduced with a simple case study. An experiment using human subjects was also conducted to evaluate the usability of the tool, and the results demonstrate that the ARPS tool can indeed help the analyst apply the EFSM-based RePS methodology with less number of errors and lower error criticality.     

Structural and Luminescence Studies on Barium Sodium Borosilicate Glasses Containing Uranium Oxides

Barium sodium borosilicate glasses containing different amounts of uranium oxides were prepared by conventional melt quench method and investigated for their structural aspects by ²⁹Si and ¹¹B MAS NMR technique combined with steady‐state luminescence and lifetime measurements. Based on MAS NMR studies, it is confirmed that uranium ions act as network modifier up to 15 wt% and beyond which a separate uranium containing phase is formed. From the luminescence studies, it is inferred that uranyl species is in a highly distorted environment. For more than 15 wt% uranium oxide incorporation, weaker U–O–U linkages are formed at the expense stronger U–O–Si/B linkages, as suggested by the excited state lifetime value of the uranyl species as well as red shift in emission peak maximum. For glass samples containing more than 25 wt% uranium oxides, crystalline barium uranium silicate gets phase separated from glass matrix as confirmed by XRD studies.     

Effect of Dopants and Sintering Method on the Properties of Ceria-Based Electrolytes for IT-SOFCs Applications

Doped and co-doped ceria ceramics are used as electrolyte materials in solid oxide fuel cells. In this work, ceria-based oxides, Ce_0.90Gd_0.06Y_0.02M_0.02O_2?δ (M?=?Ca, Fe, La, and Sr) were prepared by conventional as well as microwave processing from the precursors prepared by the mixed oxide method. The consolidated calcined powders in pellet form were sintered in microwave energy at 1400°C for 20 min and in an electric furnace of IR radiation at 1400°C for 6 h. The x-ray diffraction analysis confirmed that all the compositions were crystallized into a cubic fluorite structure. Surface morphology of the sintered products was studied using scanning electron microscopy and the microhardness was investigated using the Vickers hardness test. The comparative results analysis shows that the microwave-sintered samples have uniform grain growth, higher density and higher microhardness than the corresponding conventionally sintered products. The microwave-sintered sample of composition Ce_0.90Gd_0.06Y_0.02Sr_0.02O_2?δ was found to have the highest microhardness among the four compositions due to its high density and smallest grain size.     

Best management practices for corporate, academic and governmental transfer of sustainable technologies to developing countries

Innovations with respect to technologies that contribute to environmental sustainability have emerged within national government laboratories, international agencies and within academic research institutes. Since each of these entities is understandably more focused on ab initio research, conceptual development and proofs of concept, the production level manufacturing and broad dissemination of such technologies require development of best management practices (BMPs) for effective partnerships with and/or technology licensure to private sector industry. Alternatively, certain technologies that address specific environmental sustainability needs within the developing countries can be and have been transferred directly, either through bi-lateral transfers or through multi-lateral agencies, serving as intermediaries. The appropriateness of such transfers is contingent upon host country environmental, cultural and socio-political conditions, the type of technology involved, the “terms of transfer” and the relationships established between the technology conceivers and the end-users. The authors select examples of identified modes of sustainable technology transmission and derive experiential BMPs, which may be of some utility for future sustainable technology transfer. Moreover, in providing these BMPs, the historical record and contemporary caveats with respect to unregulated technology transfer, whether sustainable or otherwise, to developing countries and the array of corresponding proposed codes of conduct are examined, given the normative objective that such technologies should ultimately contribute to ecologically benign and societally beneficial objectives, such as environmental sustainability, equitable growth and poverty alleviation. These issues and the need to establish BMPs would be broadly relevant with the new focus on climate change-related technology funds and associated regional impact projects evolving across the globe and within the developing countries in particular.