Optimize Routing Protocol Overheads in MANETs: Challenges and Solutions: A Review Paper

Wireless Personal Communications - Routing is one of the most challenging task in mobile ad hoc networks. Several works have been proposed to address this challenge. Majority numbers of researchers...     

Optimized Reliable Hybrid Routing Protocol Based Link Stability for Mobile Wireless Networks

Wireless Personal Communications - During the last two decades, there has been a tremendous growth in the use of MANETs, not only due to the development of the technology but also due to their high...     

Influence of processing on stability,microstructure and thermoelectric properties of Ca3Co4 − xO9 + δ

Due to high figure of merit, Ca₃Co_4 ? xO_9 + δ (CCO) has potential as p-type material for high-temperature thermoelectrics. Here, the influence of processing including solid state sintering, spark plasma sintering and post-calcination on stability, microstructure and thermoelectric properties is reported. By a new post-calcination approach, single-phase materials were obtained from precursors to final dense ceramics in one step. The highest zT of 0.11 was recorded at 800 °C for CCO with 98 and 72% relative densities. In situ high-temperature X-ray diffraction in air and oxygen revealed a higher stability of CCO in oxygen (～970 °C) than in air (～930 °C), with formation of Ca₃Co₂O₆ which also showed high stability in oxygen, even at 1125 °C. Since achievement of phase pure high density CCO by post-calcination method in air is challenging, the phase stability of CCO in oxygen is important for understanding and further improvement of the method.     

Influence of Methanol on Prion Reduction during High Temperature and High Pressure Oleochemical Processes

Prion‐reduction in standard biodiesel processes is caused by acidic and alkaline conditions. In the alternative RepCat biodiesel process, efficient prion‐reduction can be achieved by high‐temperature/pressure. However, a possible increase in thermostability of prions in the presence of methanol during these conditions has not previously been investigated, and is verified in this work. Samples are spiked with prions, treated with methanol, and incubated at 220 °C at 80 bar for 30 min. No traces of protease‐resistant prion protein (as proxy for prions) are detected in tallow or glycerine (as the final by‐product) after treatment. Serial dilutions of spiked prions show at least 6 log₁₀ prion reduction. More importantly, similar effects are detected using milder conditions of 200 °C at 70 bar for 15 min, representing the worst‐case conditions of the process. In conclusion, this study shows that methanol does not increase the thermostability of prions and the RepCat process can efficiently eliminate prions and is therefore safe for the usage of category 1 tallow. Practical Applications: The study further supports the applicability of RepCat process in reducing prion‐contamination in the presence of methanol. Furthermore, the conditions leads to a considerable reduction of prions in glycerine obtained as by‐product.     

Viscoelastic,thermal, and morphological analysis of HDPE/EVA/CaCO<Subscript>3</Subscript> ternary blends

High density polyethylene (HDPE), calcium carbonate (CaCO₃), and ethylene vinyl acetate (EVA) ternary reinforced blends were prepared by melt blend technique using a twin screw extruder. The thermal properties of these prepared ternary blends were investigated by differential scanning calorimetry. The effect of EVA loading on the melting temperature (T _m) and the crystallization temperature (T _C) was evaluated. It was found that the expected heterogeneous nucleating effect of CaCO₃ was hindered due to the presence of EVA. The melt viscosities of the ternary reinforced blends were affected by the % loading of CaCO₃, EVA, and vinyl acetate content. Viscoelastic analysis showed that there is a reduction of the storage modulus (G′) with increasing of EVA loading as compared to neat HDPE resin or to HDPE/CACO₃ blends only. The morphology of the composites was characterized by scanning electron microscopy (SEM). The dispersion and interfacial interaction between CaCO₃ with EVA and HDPE matrix were also investigated by SEM. We observed two main types of phase structures; encapsulation of the CaCO₃ by EVA and separate dispersion of the phases. Other properties of ternary HDPE/CaCO₃/EVA reinforced blends were investigated as well using thermal, rheological, and viscoelastic techniques.     

Thermomechanical properties of poly(vinyl alcohol) plasticized with varying ratios of sorbitol

The objective of this work is to study the thermal and mechanical properties of films based on blends of poly(vinyl alcohol) (PVA) with different weight percent of sorbitol. Solid-state PVA/sorbitol polymer membranes were prepared by a solution casting method. The characteristic properties of these polymer membranes were examined by thermo-gravimetric analysis (TGA), differential scanning calorimetry (DSC), nanoindentation methods and by Fourier Transform Infrared (FTIR) spectroscopy. It was found that the thermal properties (glass transition, T_g, melting point, T_m and decomposition temperature, T_d) for PVA blends showed a decrease proportional to the sorbitol concentrations. The hardness and elastic modulus obtained from nanoindentation test were also found to decrease with increase in plasticizer concentration. FTIR confirmed the reduction in hydrogen bonding between PVA chains in favour of formation new bonding between the plasticizer and the PVA chains.     

Maleated high oleic sunflower oil‐treated cellulose fiber‐based styrene butadiene rubber composites

Surface treatment of cellulose fibers was performed with maleated high oleic sunflower oil (MSOHO). The MSOHO‐treated cellulose fibers and unmodified cellulose fibers were dispersed in styrene butadiene rubber (SBR) using a two roll mill. Vapor grown carbon nanofibers (VGCNF) were also incorporated at only one parts per hundred rubber (phr) in unmodified cellulose fibers/SBR composites. The curing characteristics, mechanical properties, and water absorption of the resulting composites were determined. MSOHO‐treated fibers completed curing at much slower rate and also decreased the cure density of composites, compared to unmodified fibers. In contrast, the combination of VGCNF and unmodified cellulose fibers accelerated the SBR curing process, but reduced the cure density. MSOHO treatment improved the dispersion of the fibers in the SBR, which resulted in improved mechanical properties of composites. The composite incorporating 1 phr VGCNF and 15 phr unmodified cellulose fibers showed the greatest increase in tensile strength as compared with neat SBR. POLYM. COMPOS. 37:1113–1121, 2016. © 2014 Society of Plastics Engineers     

Computations of shear driven vortex flow in a cylindrical cavity using a modified k-ε turbulence model

In this paper, a new variant of the k-ε turbulence model (Saqr et al., CFD Letters, 1(2) pp. 87–94) is used to compute the shear driven vortex flow in an open cylindrical cavity. The results are compared with published LDA measurements for such flow configuration. The modified turbulence model demonstrated good agreement with experimental results, which further supports its validity in computing vortex dominated flows.     

Current scenario and potential of biodiesel production from waste cooking oil in Pakistan: An overview

Biodiesel utilization has been rapidly growing worldwide as the prime alternative to petrodiesel due to a global rise in diesel fuel demand along with hazardous emissions during its thermochemical conversion. Although, several debatable issues including feedstock availability and price, fuel and food competition, changes in land use and greenhouse gas emission have been raised by using edible as well as inedible feedstocks for the production of biodiesel. However, non-crop feedstocks could be a promising alternative. In this article, waste cooking oils have been recommended as a suitable option for biodiesel production bearing in mind the current national situation. The important factors such as the quantity of waste cooking oil produced, crude oil and vegetable oil import expenses, high-speed diesel imports, waste management issues and environmental hazards are considered. Moreover, process simulation and operating cost evaluation of an acid catalyzed biodiesel production unit are also conducted. The simulation results show that the production cost of waste cooking oil-based biodiesel is about 0.66USD·L^-1. We believe that the present overview would open new pathways and ideas for the development of biofuels from waste to energy approach in Pakistan.