Investigations on the Effect of Tungsten Carbide and Graphite Reinforcements during Spark Erosion Machining of Aluminium Alloy (AA 5052) Hybrid Composite

Silicon - Reinforcements introduced to metal matrix composites are known for their inherent properties like corrosion resistance, wear resistance and machinability. This study deals with the...     

Design of Compact D-shaped Frequency Reconfigurable Slot Antenna for Ku/K Band Applications

Wireless Personal Communications - In this paper, a new compact design of frequency reconfigurable slot antenna is presented. The proposed radiating patch consists of two symmetrical D shape slots...     

A study on buckling of thin conical frusta under axial loads

Experiments were performed wherein conical frusta of aluminium of thicknesses between 0.7 and 1.62 mm and semi-apical angles range of 16–29° were axially compressed in a universal testing machine. The load–deformation curves and deformed shapes of specimens were recorded. These deformed in axisymmetric concertina mode and non-symmetric diamond modes.A three dimensional numerical simulation was carried out for all samples tested under quasi-static loading using ANSYS^®. Various stages of collapse of the shell, including non-symmetrical lobe formation were simulated for the first time, and material, geometric and contact non-linearities were incorporated. The plastic region of the material curve was assumed to be piecewise linear. Tensile tests were performed on standard samples to obtain stress–strain curves. Results thus obtained compared well with the experiments.Based on the formation of rolling and stationary plastic hinges an analysis was also carried out to study the behaviour of shells under axial compression and results were compared with experimental and numerical results.     

Effect of SiC on Mechanical and Microstructural Characteristics of Al Based Functionally Graded Material

Silicon - In this study, an attempt was made to enhance the mechanical and microstructural properties of aluminium (Al) based FGM with the influence of silicon carbide (SiC) elements. The five...     

Corrosion of carbon steel feeders during dilute chemical decontamination of primary heat transport system of PHWRs

Carbon steel feeders in the primary heat transport system of pressurized heavy water reactors (PHWRs) show significant wall thinning due to flow accelerated corrosion (FAC). This is of great concern, as the wear rate in certain locations exceeds the corrosion allowance by design. This necessitates periodic measurement of wall thickness and in some cases even mid course enmasse replacement of feeders. While analyzing the data on wall thicknesses and in arriving at the wall thinning rate during operation of the reactor, sufficient care has to be taken to account for the wall thinning occurring during full system chemical decontamination campaign which is carried out occasionally to reduce dose rates during reactor shut down. Chemical decontamination of primary heat transport system is carried out using a mixture of organic acids at a total concentration of about 0.1 g/L and at 85 °C. The results of experiments carried out under simulated conditions for estimating the wall thinning occurring in carbon steel feeder elbow during dilute chemical decontamination are described in this work. The corrosion rates are quantified.     

Conductive electrospun PANi-PEO/TiO2 fibrous membrane for photo catalysis

The integration of electrospinning and electrospraying to prepare the fibrous catalytic filter membrane is demonstrated. The non-conductive polyethylene oxide (PEO) is blended with (±)-camphor-10-sulfonic acid (CSA) doped conductive polyaniline (PANi) for electrospinning. The conductive CSA/PANi-PEO composite fibers are produced upon electrospinning, which are used as the conductive collector for electrospraying process by which titanium dioxide (TiO₂) nanoparticles (NPs) are sprayed and allowed to adsorb on the fibers. The degree of adsorption and dispersion of nano TiO₂ catalysts on the surface of the CSA/PANi-PEO fibers exhibit a stronger dependence on weight percentage (wt%) of PANi in PEO solution and the strength of electrical conductivity of the fibers used during electrospraying. CSA/PANi-PEO fibers as collector reduce the wastage of TiO₂ NPs during electrospraying to lesser than 5%. Among the three different composition of PANi studied, PEO with 12 wt% PANi yields very uniform diameter and beads-free fibrous structure with higher electrical conductivity. 12 wt% CSA/PANi-PEO fibrous membrane is found to support for greater dispersion of TiO₂ NPs. The photocatalytic activity of the as-prepared TiO₂-PANi-PEO catalytic membrane is tested against the toxicant simulant 2-chloroethyl phenyl sulfide (CEPS) under the ultraviolet light irradiation. It is observed that the TiO₂ nanoparticles catalysts embedded PANi-PEO fibrous membrane decontaminated the toxicant CEPS significantly, which is due to uniform dispersion of the catalysts produced by the methodology.     

Machining of NiTi-shape memory alloys-A review

The emerging trends in the development of advanced smart materials with better unique properties under different environments for a particular application fascinate the researchers and industrialists. Nickel-Titanium based shape memory alloys are exotic materials due to their unique properties such as SME, SE, high damping characteristics, high corrosion and wear resistance and biocompatibility. This article presents an overview of machining processes that can be used to machine the NiTi and its surface induced characteristics such as microhardness, surface roughness, topography, induced layer, residual stress, fatigue and phase transformation. The surface integrity characteristics are discussed for machining of NiTi-SMAs under the category of traditional, non-traditional and micro-machining with the effect of input parameters such as cutting speed, feed, depth of cut, type of lubricant and type of coating material on cutting tool. The conventional machining of NiTi alloys are quite complicated due to high toughness, severe strain hardening, fatigue hardening and distinctive property of NiTi-SMAs such as pseudoelastic and shape memory effect. From this study, non-traditional process is significantly used to machine the NiTi-SMAs due to its better results on surface integrity characteristics. Consequently, future trends are also identified for machining the NiTi-SMAs and to improve the surface integrity characteristics.     

NIR Photoresponsive Crosslinked Upconverting Nanocarriers Toward Selective Intracellular Drug Release

An NIR‐responsive mesoporous silica coated upconverting nanoparticle (UCNP) conjugate is developed for controllable drug delivery and fluorescence imaging in living cells. In this work, antitumor drug doxorubicin (Dox) molecules are encapsulated within cross‐linked photocaged mesoporous silica coated UCNPs. Upon 980 nm light irradiation, Dox could be selectively released through the photocleavage of theo‐nitrobenzyl (NB) caged linker by the converted UV emission from UCNPs. This NIR light‐responsive nanoparticle conjugate demonstrates high efficiency for the controlled release of the drug in cancer cells. Upon functionalization of the nanocarrier with folic acid (FA), this photocaged FA‐conjugated silica‐UCNP nanocarrier will also allow targeted intracellular drug delivery and selective fluorescence imaging towards the cell lines with high level expression of folate receptor (FR).     

Effect of nitrate ions on the corrosion of stellite in permanganate media

The dissolution behaviour of stellite #3 in two oxidizing agents of equivalent acidity namely, permanganic acid (HMnO₄) and a mixture of nitric acid and potassium permanganate (NP) was evaluated. The presence of nitrate in the permanganate formulation was found to reduce its efficiency for oxidizing stellite. Electrochemical polarization and impedance studies were carried out at 90 °C in NP and HMnO₄. The redox potential of both the oxidizing agents favoured transpassive dissolution of chromium from the alloy. In NP, only the chromium depleted inter-phase boundary was attacked while most of the chromium rich carbide phases were intact. In contrast, in HMnO₄, uniform corrosion of the surface was observed. The impedance response was found to change with duration of exposure. The nitrate ions in permanganate were found to promote the repassivation of the surface. HMnO₄ was found to be a better formulation for dissolving cobalt from the alloy as compared to NP.