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排序方式: 共有275条查询结果,搜索用时 15 毫秒
1.
Colloid transport through porous media can be influenced by the presence of biofilms. Sterile and non-sterile sand columns were investigated using Laponite RD as model colloid and a highly mucoid strain of Pseudomonas aeruginosa as model biofilm former. Laponite RD was marked specifically by fluorescent complexes with rhodamine 6G. Breakthrough curves (BTCs) were used as parameters for determination of colloid transport characteristics. In the sterile columns, the colloid was mobile (collision efficiencies from 0.05 to 0.08) both after the presence of Na(+) and Ca(2+) ions followed by deionised water influent. In the biofilm-grown column, the same treatment did not result in colloid retention in the case of Na(+) exposure, but in altered or enhanced colloid transport. In the case of Ca(2+) ions exposure, colloid retention increased with biofilm age. After 3 weeks, almost complete retention was observed. Similar observations were made in columns packed with material from slow sand filtration units. These data reveal the complex interactions between biofilms, cations and colloid transport. Changes in the electrolyte composition of water percolating the subsurface can frequently occur and will result in different colloid transport characteristics with regard to the dominating species of ions and the relative abundance of microbial biofilms. This has to be considered when modelling colloid transport through the subsurface. 相似文献
2.
Using 15N‐Ammonium to Characterise and Map Potassium Binding Sites in Proteins by NMR Spectroscopy 下载免费PDF全文
Dr. Nicolas D. Werbeck Dr. John Kirkpatrick Dr. Jochen Reinstein Dr. D. Flemming Hansen 《Chembiochem : a European journal of chemical biology》2014,15(4):543-548
A variety of enzymes are activated by the binding of potassium ions. The potassium binding sites of these enzymes are very specific, but ammonium ions can often replace potassium ions in vitro because of their similar ionic radii. In these cases, ammonium can be used as a proxy for potassium to characterise potassium binding sites in enzymes: the 1H,15N spin‐pair of enzyme‐bound 15NH4+ can be probed by 15N‐edited heteronuclear NMR experiments. Here, we demonstrate the use of NMR spectroscopy to characterise binding of ammonium ions to two different enzymes: human histone deacetylase 8 (HDAC8), which is activated allosterically by potassium, and the bacterial Hsp70 homologue DnaK, for which potassium is an integral part of the active site. Ammonium activates both enzymes in a similar way to potassium, thus supporting this non‐invasive approach. Furthermore, we present an approach to map the observed binding site onto the structure of HDAC8. Our method for mapping the binding site is general and does not require chemical shift assignment of the enzyme resonances. 相似文献
3.
Angela Gerlach Enrico Preuss Paul Uwe Thamsen Flemming Lykholt-Ustrup 《Journal of Mechanical Science and Technology》2017,31(4):1711-1719
We did a numerical study of the internal flow field of a vortex pump. Five operating points were considered and validated through a measured characteristic curve. The internal flow pattern of a vortex pump was analyzed and compared to the Hamel-Oseen vortex model. The calculated flow field was assessed with respect to the circumferential velocity, the vorticity and the axial velocity. Whereas the trajectories of the circumferential velocity were largely in line with the Hamel-Oseen vortex model, the opposite was true for vorticity. Only the vorticity at strong part load was in line with the predictions of the Hamel-Oseen vortex model. We therefore compared the circumferential velocity and vorticity for strong part load operation to the analytical predictions of the Hamel-Oseen vortex model. The simulated values were below the analytical values. The study therefore suggests that a vortex similar to the Hamel-Oseen vortex is only present at the strong part load operation. 相似文献
4.
This paper contains a tentative suggestion of how to take into account the value of changes in price volatility in real world cost-benefit analyses. Price volatility is an important aspect of security of supply which first of all concerns physical availability, but assuming that consumers are risk averse, security of supply can also be viewed as a matter of avoiding oscillations in consumption originating from volatile prices of for instance oil. When the government makes transport-related choices on behalf of the consumers, the effect on oscillations in general consumption should be included in the policy assessment taking into account the most significant correlations between prices of alternative fuels and between fuel prices and consumption in general. In the present paper, a method of valuing changes in price volatility based on portfolio theory is applied to some very simple transport-related examples. They indicate that including the value of changes in price volatility often makes very little difference to the results of cost-benefit analyses, but more work has to be done on quantifying, among other things, consumers’ risk aversion and the background standard deviation in total consumption before firm conclusions can be drawn. 相似文献
5.
Lars Pleth Nielsen Morten Schønning Steffen V. Christensen Søren V. Hoffmann Zheshen Li Philip Hofmann Flemming Besenbacher Bjerne S. Clausen 《Catalysis Letters》2001,73(2-4):85-90
The sulfiding of Mo/Al2O3 in H2S/Ar versus in H2S/H2 has been studied by temperature-programmed sulfiding (TPS), X-ray photon electron spectroscopy (XPS), extended X-ray absorption fine structure (EXAFS), and temperature-programmed desorption of NO (NO-TPD). All the applied techniques agree on the sulfur content in the sulfided catalysts and the findings are in accord with a model for the H2S production reaction. The nucleation and growth of well-ordered MoS2 clusters are probed by XPS during sulfiding with and without the presence of hydrogen. The resulting dispersion of the MoS2 phase is evaluated on the basis of XPS, EXAFS, and NO-TPD, and is found to be highest when the sulfiding occurs in the presence of hydrogen. 相似文献
6.
7.
Dan Xia Qingzhong Xue Jie Xie Huijuan Chen Cheng Lv Flemming Besenbacher Mingdong Dong 《Small (Weinheim an der Bergstrasse, Germany)》2010,6(18):2010-2019
A simple way of synthesizing carbon nanotube (CNT)/graphene (GN) nanoscroll core/shell nanostructures is demonstrated using molecular dynamics (MD) simulations. The simulations show that GN sheets can fully self‐scroll onto CNTs when the CNT radius is larger than a threshold of about 10 Å, forming a stable core/shell structure. Increasing the length of the GN sheet results in multilayered carbon nanoscroll (CNS) shells that exhibit a tubular structure similar to that of multiwall CNTs. The distances between the CNT and the GN wall or adjacent GN walls are about 3.4 Å. It is found that the van der Waals force plays an important role in the formation of the CNT/GN nanoscroll core/shell‐composite nanostructures. However, the chirality of the CNT and the GN sheet does not affect the self‐scrolling process, which thus provides a simple way of controlling the chirality and physical properties of the resulting core/shell structure. It is expected that this preparation method of CNT/GN nanoscroll core/shell composites will lead to further development of a broad new class of carbon/carbon core/shell composites with enhanced properties and even introduce new functionalities to composite materials. 相似文献
8.
The calculus of communicating systems, CCS, was introduced by Robin Milner as a calculus for modelling concurrent systems. Subsequently several techniques have been developed for analysing such models in order to get further insight into their dynamic behaviour.In this paper we present a static analysis for approximating the control structure embedded within the models. We formulate the analysis as an instance of a monotone framework and thus draw on techniques that often are associated with the efficient implementation of classical imperative programming languages.We show how to construct a finite automaton that faithfully captures the control structure of a CCS model. Each state in the automaton records a multiset of the enabled actions and appropriate transfer functions are developed for transforming one state into another. A classical worklist algorithm governs the overall construction of the automaton and its termination is ensured using techniques from abstract interpretation. 相似文献
9.
Kinetics of tyre char oxidation under combustion conditions 总被引:1,自引:0,他引:1
Morten Boberg Larsen Morten Linde Hansen Lars Skaarup-Jensen Flemming Frandsen 《Fuel》2007,86(15):2343-2350
Combustion of tyre char particles with diameters between 102 and 212 μm was performed in an experimental laboratory reactor, at temperatures between 750 and 850 °C, in an oxidative atmosphere with up to 10 vol.% O2 at 1 bar. The observed char combustion time varied from about 9 s at 750 °C to about 4 s at 850 °C. Under these conditions the experimental data indicated increasing mass transfer resistance with temperature. A diffusion reaction model was employed to study the effects of simultaneous mass transfer and kinetics in the experiments. An intrinsic reaction rate for tyre char combustion was estimated and comparison with literature data revealed good agreement. 相似文献
10.
Weihe P Kato K Calafat AM Nielsen F Wanigatunga AA Needham LL Grandjean P 《Environmental science & technology》2008,42(16):6291-6295
To learn the extent of human exposure to polyfluoroalkyl compounds (PFCs) in a remote fishing population, we measured, in Faroese children and pregnant women, the serum concentrations of nine PFCs, including perfluorooctane sulfonate (PFOS), perfluorooctanoate (PFOA), and perfluorononanoate (PFNA), by using online solid-phase extraction coupled to isotope dilution high-performance liquid chromatography-tandem mass spectrometry. The serum samples analyzed had been collected between 1993 and 2005 from 103 children 7 years of age, 79 of these children at 14 years of age, and from 12 pregnant women and their children 5 years later. PFOS was detected in all samples analyzed, and both PFOA and PFNA were detected in all but one of the samples. The concentrations found are comparable tothose reported elsewhere. Correlations between paired concentrations were poor. However, PFOS and PFNA concentrations correlated well with the frequency of pilotwhale dinners and with concentrations of mercury and polychlorinated biphenyls. One whale meal every two weeks increased the PFOS concentration in 14-year-olds by about 25% and PFNA by 50%. The high frequency of detection of most PFCs suggests widespread exposure in the Faroe Islands already by the early 1990s, with whale meat being an important source. 相似文献