Size Measurement of Polystyrene Latex Particles Larger than 1 Micrometer using a Long Differential Mobility Analyzer

We describe a newly constructed annular-type differential mobility analyzer (DMA) with an effective electrode length of 60 cm, which is longer than that of our original DMA (40 cm length). This long DMA was developed to extend the classification size of particles measuring up to 1.5 μm. As an application of this DMA, the mean diameters and standard deviations were determined for six samples of monodisperse polystyrene latex (PSL) particles ranging from 0.94 to 1.27 μm in nominal diameter. These PSL particles suspended in double-distilled water were aerosolized by a glass nebulizer and then introduced into the DMA. The mean diameters and standard deviations of these PSL particles were calculated by Ehara's method and compared with the nominal diameters and uncertainties. There was good correlation between the nominal diameters of these samples—particularly for recently certified samples—and the measured diameters. Classification of aerosol particles more than 1 micrometer in diameter using this DMA will be useful for many purposes.     

Analysis of small-world networks with high broadcast speed

Given a network where each element has a small number of connected elements, the randomization of connections with small probabilities results in networks with a high broadcast speed. Such networks belong to the class of so-called small-world networks. Analyses indicate that broadcast to all elements of the network is fundamentally different from the average transmission speed. Networks with 10% randomness give the fastest broadcast speeds with no dependence on the position of the initial transmission source. This work was presented in part at the Sixth International Symposium on Artificial Life and Robotics, Tokyo, January 15–17, 2001     

Shape selectivity as a function of pore size in epoxidation of alkenes with supported titanium catalysts

Reactant shape selectivity of supported titanium catalysts for epoxidation of cyclohexene and 2-hexene has an excellent correlation with the pore diameter of the catalysts. With titanosilicate the preference to cis isomer epoxidation is small compared to TiO₂-SiO₂ probably because of the restriction of its diffusion imposed by the zeolite micropore structure.     

Aerosol-to-liquid collection: A method for making aqueous suspension of hydrophobic nanomaterial without adding dispersant

This article introduces an aerosol-based technique to make aqueous suspension of hydrophobic nanomaterial without adding dispersant. The method is intended for making a test-sample for evaluating the toxicities of nanomaterial by intra-tracheal administration. The method can wet the surface of hydrophobic nanomaterial within a few seconds. After the wetting process five to ten minutes of sonication assisted with manual stirring can fully disperse the hydrophobic nanomaterials in water. Two types of TiO₂ nanomaterial were used in this study; Tayca JMT-150IB whose surfaces are coated with negatively charged hydrophobic functional group, and P25 whose surfaces are naturally hydrophilic. Nanomaterials are aerosolized by a dry-method and become micrometer-sized agglomerates. Then supersaturated water vapor is condensed onto these airborne agglomerates by using a growth tube collector. The collected suspension (CS) of hydrophobic nanomaterial (JMT-150IB) is prepared in two steps; airborne agglomerates are collected onto a flat surface then transferred to liquid-water and subsequently sonicated for complete dispersion. This method works equally well for making the CS of hydrophilic nanomaterial. Size distribution measurements of the CS show that airborne agglomerates of TiO₂ dissociate into smaller units of agglomerates once they are captured into water, and the sizes of the agglomerates are in the nanometer to sub-micrometer range. Light scattering technique is used to show that a short sonication process can reproduce the particle number concentration of the CS after long storage.

Copyright © 2017 American Association for Aerosol Research     

An experimental study of energy dips for speech and music

Speech signals generally have many intervals with low energy “energy dips”. For music signals, energy dips are not always remarkable. We studied stochastic features of energy dips for speech and music signals. A certain difference was found between the signals in the length of energy dips. Also, the number of energy dips in a time window and their distribution were investigated. From this distribution, a threshold number of energy dips was estimated which provided a scheme for the discrimination of speech from music.     

Logichart — Intelligible Program Diagram for Prolog and its Processing System

An intelligible program diagram called Logichart has been developed for Prolog visualization. Its syntax rules and layout rules are formalized in terms of an attribute graph grammar. This grammar is underlain by a context–free graph grammar whose productions are defined to formalize the graph–syntax rules of Logichart diagrams. Semantic rules attached to the productions are defined in such a way that they can extract the layout information needed to display a Logichart diagram as attributes. Our Prolog visualization system, which has been implemented based on the attribute graph grammar, can draw a Logichart diagram for any correct Prolog program (completeness), and any Logichart diagram displayed by the system is always valid for the grammar (soundness). The system can also display the execution of a Prolog program in real time; that is, the Logichart diagram is dynamically updated as the program runs.     

Alternative Economics and Sustainable Future: Diverse Cultures/Beliefs/Values as Indispensable Factors

This article argues for a theoretical framework of alternative economics pertinent to Sustainable Development. The alternative economics requires an appropriate belief/value system based on a dynamic, sound and holistic society-specific culture (abbreviated as “Culture”). To represent the Culture-based belief/value system, a general framework for overarching Integral Harmony is introduced as an appropriate social value system for a paradigm shift toward sustainability. Such a social value system is now related to the value premises of the alternative economics. Then, the framework of alternative economics is explained in terms of basic theoretical construct that is simplified as a summary equation comprising value and real aspects. Finally, a typical working of the alternative economics is demonstrated diagrammatically as constant interactions of the value aspect and the real aspect (abbreviated as “Value-Real Interactions”).     

Photostability of Isovaline and its Precursor 5-Ethyl-5- methylhydantoin Exposed to Simulated Space Radiations

Aqueous solutions of isovaline and its precursor molecule, 5-ethyl-5-methylhydantoin, were irradiated with ultraviolet and γ-ray photons, to evaluate their structural stability against space radiation. The degree of photolysis was measured and irradiation products were identified using chiral, reversed-phase and ion-exchange high-performance liquid chromatography. The experimental results show that the degree of photolysis of 5-ethyl-5-methylhydantoin is more significant than that of isovaline under ultraviolet light irradiation, while the results under γ-ray irradiation are the opposite. As the products of isovaline photolysis, aspartic acid, serine, glutamic acid and alanine were dominantly detected.     

Design Considerations and Performance Evaluation of a Compact Aerosol Particle Mass Analyzer

A compact aerosol particle mass analyzer (APM) of which the size of the classifier was significantly reduced than that of the first commercial model (Kanomax Model 3600) was developed. Firstly, requirements for desired performance in classifying particle mass were set forth. Secondly, a theoretical framework for the design parameters of an APM that satisfies the requirements was formulated. Thirdly, the design parameters were determined that satisfies the requirements while reducing the instrument size. The requirements include the condition that the classification range covers from 0.001 to 1000 fg (approximately 12 to 1200 nm in size for spherical particles having the density of 1 g/cm³), and the condition that both the classification resolution and particle penetration in this mass range are higher than certain specified values. A prototype having the design parameters determined according to this theoretical framework was constructed, and its performance was evaluated experimentally. The external dimensions of the electrodes of the compact APM are approximately 140 mm in length and 60 mm in diameter. It was confirmed that the performance of the compact APM operated at the aerosol flow rate of 0.3 L/min was comparable to that of the Model 3600 APM operated at 1 L/min. Because of the reduced size and of the resultant improved portability, it is expected that the compact APM is readily applicable to field measurements.

Copyright 2013 American Association for Aerosol Research