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排序方式: 共有3047条查询结果,搜索用时 78 毫秒
1.
Nusrat Shaheen Muhammad Aadil Sonia Zulfiqar Humera Sabeeh Philips O. Agboola Muhammad Farooq Warsi Mohamed F. Aly Aboud Imran Shakir 《Ceramics International》2021,47(4):5273-5285
Here, we have fabricated the spinel binary-metal oxide (FeCo2O4) via a solvent-free and cost-effective approach. The nanocomposites of the as-fabricated binary-metal spinel oxide have been prepared with three different conductive-matrices, namely r-GO, CNTs, and PANI, via ultra-sonication approach. The spinel phase and surface functionalities of the fabricated FeCo2O4 sample have been confirmed via XRD and FT-IR analyses, respectively. The morphological-structure and elemental composition of the fabricated samples have been probed via FESEM and EDX results. The role of added conductive-matrices in the improvement of the electrical conductivities of the fabricated nanocomposites has been investigated via I–V experiments. The electrochemical experiments, conducted in half-cell configuration, showed that FeCo2O4/PANI nanocomposite exhibited the highest specific capacitance (658.9 Fg-1) than that of the remaining two nanocomposites. Furthermore, FeCo2O4/PANI nanocomposite exhibited excellent cyclic stability as it lost just 8.3% of its initial specific capacitance even after 3000 cyclic tests. The superior capacitive-activity of the FeCo2O4/PANI nanocomposite is accredited to its high conductivity, large surface area, and synergy effects between the pseudocapacitance derived from the PANI and FeCo2O4 nanostructure. The electrochemical and electrical measurements suggested that FeCo2O4/PANI nanostructure is an emerging contender for energy storage applications. 相似文献
2.
Babak Jaleh Mahmoud Nasrollahzadeh Bahareh Feizi Mohazzab Mahtab Eslamipanah Mohaddeseh Sajjadi Hossein Ghafuri 《Ceramics International》2021,47(8):10389-10425
In both developing and industrialized/developed countries, various hazardous/toxic environmental pollutants are entering water bodies from organic and inorganic compounds (heavy metals and specifically dyes). The global population is growing whereas the accessibility of clean, potable and safe drinking water is decreasing, leading to world deterioration in human health and limitation of agricultural and/or economic development. Treatment of water/wastewater (mainly industrial water) via catalytic reduction/degradation of environmental pollutants is extremely critical and is a major concern/issue for public health. Light and/or laser ablation induced photocatalytic processes have attracted much attention during recent years for water treatment due to their good (photo)catalytic efficiencies in the reduction/degradation of organic/inorganic pollutants. Pulsed laser ablation (PLA) is a rather novel catalyst fabrication approach for the generation of nanostructures with special morphologies (nanoparticles (NPs), nanocrystals, nanocomposites, nanowires, etc.) and different compositions (metals, alloys, oxides, core-shell, etc.). Laser ablation in liquid (LAL) is generally considered a quickly growing approach for the synthesis and modification of nanomaterials for practical applications in diverse fields. LAL-synthesized nanomaterials have been identified as attractive nanocatalysts or valuable photocatalysts in (photo)catalytic reduction/degradation reactions. In this review, the laser ablation/irradiation strategies based on LAL are systematically described and the applications of LAL synthesized metal/metal oxide nanocatalysts with highly controlled nanostructures in the degradation/reduction of organic/inorganic water pollutants are highlighted along with their degradation/reduction mechanisms. 相似文献
3.
Mohammad Bani Ismail Peramaiyan Rajendran Hamad Mohammed AbuZahra Vishnu Priya Veeraraghavan 《International journal of molecular sciences》2021,22(8)
Doxorubicin increases endothelial permeability, hence increasing cardiomyocytes’ exposure to doxorubicin (DOX) and exposing myocytes to more immediate damage. Reactive oxygen species are major effector molecules of doxorubicin’s activity. Mangiferin (MGN) is a xanthone derivative that consists of C-glucosylxanthone with additional antioxidant properties. This particular study assessed the effects of MGN on DOX-induced cytotoxicity in human umbilical vein endothelial cells’ (HUVECs’) signaling networks. Mechanistically, MGN dramatically elevated Nrf2 expression at both the messenger RNA and protein levels through the upregulation of the PI3K/AKT pathway, leading to an increase in Nrf2-downstream genes. Cell apoptosis was assessed with a caspase-3 activity assay, transferase-mediated dUTP-fluorescein nick end labeling (TUNEL) staining was performed to assess DNA fragmentation, and protein expression was determined by Western blot analysis. DOX markedly increased the generation of reactive oxygen species, PARP, caspase-3, and TUNEL-positive cell numbers, but reduced the expression of Bcl-2 and antioxidants’ intracellular concentrations. These were effectively antagonized with MGN (20 μM), which led to HUVECs being protected against DOX-induced apoptosis, partly through the PI3K/AKT-mediated NRF2/HO-1 signaling pathway, which could theoretically protect the vessels from severe DOX toxicity. 相似文献
4.
Najiba Hasan Hamad 《亚洲传热研究》2022,51(5):3794-3814
Classical Fourier's theory is well-known in continuum physics and thermal sciences. However, the primary drawback of this law is that it contradicts the principle of causality. To explore the thermal relaxation time characteristic, Cattaneo–Christov's theory is adopted thermally. In this regard, the features of magnetohydrodynamic (MHD) mixed convective flows of Casson fluids over an impermeable irregular sheet are revealed numerically. In addition, the resulting system of partial differential equations is altered via practical transformations into nonlinear ordinary differential equations. An advanced numerical algorithm is developed in this respect to get higher approximations for temperature and velocity fields, as well as their corresponding wall gradients. For validating our numerical code, the current outcomes are compared with the available literature results. Moreover, it is revealed that the velocity field is more prominent in the suction flow situation as compared with the injection flow case. It is also found that the Casson fluid is hastened in the case of lower yield stress. Larger values of thermal relaxation parameters create a lessening trend in the temperature distribution and its related boundary layer breadth. 相似文献
5.
Rukia Fatima Muhammad Farooq Warsi Muhammad Ilyas Sarwar Imran Shakir Philips O. Agboola Mohamed F. Aly Aboud Sonia Zulfiqar 《Ceramics International》2021,47(6):7642-7652
A new AgO.CuO.WO3/rGO nanocomposite was designed for the investigation of the degradation ability of the hybrid material under visible light irradiation. The AgO, CuO, WO3 NPs, and AgO.CuO.WO3 hetero-metallic oxides were fabricated via the chemical co-precipitation method. The crystallite sizes and phase analyses were investigated by recording X-ray diffraction patterns. The crystallite sizes of three metal oxides in the AgO.CuO.WO3 hetero metal oxide were 16.7, 15.9, and 16.9 nm, respectively. The FESEM images at various magnifications were probed to study the morphology of synthesized materials. The micrographs of hetero-metallic oxides AgO.CuO.WO3 exposed that three metal oxides merged like small particles and gives a large bulbous appearance. EDX analyses confirmed the formation of required materials with high purity. FTIR data was in agreement with the literature which facilitated to ensure the purity of synthesized samples. The optical bandgap energy was calculated via the Tauc plot indicating that the blend of three metal oxides generated a new energy level in the electronic structure is suitable for photocatalysis in the presence of visible light. The bandgap energy of hetero metallic oxides was 1.25 eV which is less than individual metal oxides signifying the tuning of the bandgap. The incorporation of rGO in AgO.CuO.WO3 hetero-metallic oxides gives a new photocatalyst for optimum photodegradation of methylene blue in minimum time. The percentage degradation via AgO.CuO.WO3 was 87.20% in 70 min while the percentage degradation via AgO.CuO.WO3/rGO recorded by photocatalytic experiment was 95% in 40 min. The photocatalysis data revealed that AgO.CuO.WO3 hetero-metallic oxides-rGO nanocomposite ensured a strong potential to uptake organic dyes from water by promoting redox reactions during photocatalysis in the minimum time limit. 相似文献
6.
7.
Fatemeh Norouzi Jobie Mojtaba Ranjbar Akbar Hajizadeh Moghaddam Mahmoud Kiani 《Advanced Powder Technology》2021,32(6):2043-2052
For the first time in this study, Zinc oxide nanoparticles were biosynthesized by the eco-friendly and cost-effective procedure using Amygdalus scoparia stem bark extract then used as antibacterial, antifungal, anticancer, and anti-diabetic agents. The characterization techniques confirmed the biosynthesis, crystalline nature, structure, size, elemental composition of ZnO NPs and bioactive compounds that exist in A. scoparia extract accounting for Zn2+ ion reduction, capping and stabilization of ZnO NPs. The ZnO NPs displayed remarkable inhibitory activity against E. coli, E. aerigenes, S. aureus, P. oryzae, F. thapsinum, and F. semitectum compared to antibiotic standards. The ZnO NPs showed significant inhibitory effects on cancer cell lines, while it had no toxic effect on Vero normal cell line. The ZnO NPs (30 mg/kg)-treated diabetic rats showed significantly higher levels of insulin and lower AST, ALT and blood glucose compared with the STZ induced diabetic group and other treated groups (P < 0.05). The ZnO NPs- and extract-treated rats showed significantly higher levels of IR, GluT2, and GCK expression and lower TNFα expression compared with the STZ induced diabetic rats. Our findings showed that ZnO NPs represented an outstanding performance for biological applications. 相似文献
8.
Basaleh A. S. Amin M. S. Mahmoud M. H. H. 《Journal of Inorganic and Organometallic Polymers and Materials》2021,31(9):3829-3841
Journal of Inorganic and Organometallic Polymers and Materials - The present work offers beneficial method for Hg (II) elimination from aqueous solution. ZnIn2S4/g-C3N4 nanocomposites were... 相似文献
9.
Mahmoud MOUSTAFA Saad ALAMRI Hoida ZAKI Naglaa LOUTFY Tarek TAHA Ali SHATI Mohamed ALKAHTANI Sajda SIDDIQI 《Biocell》2019,43(2):81-88
The present research reports of quick and marked changes induced by plant extract of Euryops arabicus in the
gene expression of 49-kDa apyrases, cytoskeletal proteins, ATPases, ADPase and amount of amino acid of pea (Pisum
sativum L. var. Alaska). Pellets of cytoskeletals proteins (27000 xg) were probed with anti-apyrase antibody, biotinylated
anti-rat, actin and alpha and beta-tubulin for Western blotting. ATPase and ADPase activities were determined based
on the hydrolytic efficacy of adenine triphosphate and adenine diphosphate. By 72 hours, the abundance of apyrases,
cytoskeletal proteins and amount of amino acid in pellets of 27000 xg of germinated pea seeds in E. arabicus extracts
were sharply increased than those sown in distilled water. All the samples exhibited that the stems had more amount
from apyrases, cytoskeletal proteins, amino acids and ATPase and ADPase activities than primary leaves and primary
roots that were germinated either on E. arabicus water extract or in distilled water. Based on the enzyme’s capability to
hydrolyse nucleotide triphosphate and nucleotide diphosphate as well as the direct association between expression of
49-kDa apyrase and cytoskeletal proteins, E. arabicus water extract had an important effect on plant germinations. 相似文献