Recent Advances in Conjugated Polymers for Visible-Light-Driven Water Splitting

With the ambition of solving the challenges of the shortage of fossil fuels and their associated environmental pollution, visible-light-driven splitting of water into hydrogen and oxygen using semiconductor photocatalysts has emerged as a promising technology to provide environmentally friendly energy vectors. Among the current library of developed photocatalysts, organic conjugated polymers present unique advantages of sufficient light-absorption efficiency, excellent stability, tunable electronic properties, and economic applicability. As a class of rising photocatalysts, organic conjugated polymers offer high flexibility in tuning the framework of the backbone and porosity to fulfill the requirements for photocatalytic applications. In the past decade, significant progress has been made in visible-light-driven water splitting employing organic conjugated polymers. The recent development of the structural design principles of organic conjugated polymers (including linear, crosslinked, and supramolecular self-assembled polymers) toward efficient photocatalytic hydrogen evolution, oxygen evolution, and overall water splitting is described, thus providing a comprehensive reference for the field. Finally, current challenges and perspectives are also discussed.     

Spreading and Curing Behaviors of a Thermosetting Droplet-Silicone on a Heated Surface

Thermosetting materials are widely used as encapsulation in the electrical packaging to protect the core electronic components from external force, moisture, dust, and other factors. However, the spreading and curing behaviors of such kind of fluid on a heated surface have been rarely explored. In this study, we experimentally and numerically investigated the spreading and curing behaviors of the silicone(OE6550 A/B, which is widely used in the light-emitting diode packaging) droplet with diameter of ～2.2 mm on a heated surface with temperature ranging from 25 ℃ to 250 ℃. For the experiments, we established a setup with high-speed camera and heating unit to capture the fast spreading process of the silicone droplet on the heated surface. For the numerical simulation, we built a viscosity model of the silicone by using the Kiuna's model and combined the viscosity model with the Volume of Fluid(VOF) model by the User Defined Function(UDF) method. The results show that the surface temperature significantly affected the spreading behaviors of the silicone droplet since it determines the temperature and viscosity distribution inside the droplet. For surface temperature varied from 25 ℃ to 250 ℃, the final contact radius changed from ～2.95 mm to ～1.78 mm and the total spreading time changed from ～511 s to ～0.15 s. By further analyzing the viscosity evolution of the droplet, we found that the decreasing of the total spreading time was caused by the decrease of the viscosity under high surface temperature at initial spreading stage, while the reduction of the final contact radius was caused by the curing of the precursor film. This study supplies a strategy to tuning the spreading and curing behavior of silicone by imposing high surface temperature, which is of great importance to the electronic packaging.     

Effect of comb-type copolymer on crystallization of paraffin from waxy oils and methyl ethyl ketone (MEK) -toluene dewaxing

In this research, maleic anhydride-α-octadecene copolymer and its derivative with phenylethylamine was synthesized and its effect on the crystallization of paraffins was investigated. This derivative, when added into second cut of vacuum gas oil and forth cut of vacuum gas oil, increases the size and improves aggregation of paraffin crystals observed by polarizing light microscopy, increases onset temperature and enthalpy of paraffin crystallization determined by differential scanning calorimetry, improves the dewaxing efficiency with dosage of 100?ppm explored by MEK-toluene dewaxing.     

合成丁苯嵌段共聚物的影响因素

采用负离子溶液聚合方法制备了丁苯嵌段共聚物，研究了引发剂、活化剂、偶合剂、终止剂对聚合产物性能的影响。     

微计算机控制的造波系统

本文所述系统可在水池中产生单一频率规则波、周期不规则波及"随机波",用于海洋、造 船工程的模型试验,采用频域迭代法和成型滤波器法来产生模拟海浪.尽管这一控制系统是 专为产生模拟海浪而设计的,但其控制方案也可直接用于其他测试技术领域,以产生"随机" 信号.     

内燃机车曲轴中频淬火过程的数值模拟

借助 ANSYS大型有限元分析软件 ,实现了 16 V2 4 0曲轴淬火过程的计算机模拟 ,模拟结果可直观地显示出任一时刻曲轴表面及内部的温度分布、冷却曲线以及淬火结束后的残余应力分布 ,并能预测淬硬层深度。同时对比了轴颈内圆角处进行淬火和不进行淬火两种工艺的效果 ,为现场提供了用虚拟现实方法详尽分析和研究淬火工艺的工具。     

Solving the bi-objective personnel assignment problem using particle swarm optimization

A particle swarm optimization (PSO) algorithm combined with the random-key (RK) encoding scheme (named as PSORK) for solving a bi-objective personnel assignment problem (BOPAP) is presented. The main contribution of this work is to improve the f₁_f₂ heuristic algorithm which was proposed by Huang et al. [3]. The objective of the f₁_f₂ heuristic algorithm is to get a satisfaction level (SL) value which is satisfied to the bi-objective values f₁, and f₂ for the personnel assignment problem. In this paper, PSORK algorithm searches the solution of BOPAP space thoroughly. The experimental results show that the solution quality of BOPAP based on the proposed method is far better than that of the f₁_f₂ heuristic algorithm.     

基于提高弱电网新能源并网水平的逆变器功率-电压控制策略

传统功率-电流控制的并网逆变器存在谐波振荡等交互稳定性问题,限制了新能源的并网水平,尤其在弱交流电网中更为突出.为克服上述缺点,提出了一种新型功率-电压控制策略.首先在旋转dq坐标系下建立了逆变器输出阻抗的动态模型,包括主电路参数,锁相环(PLL)动态参数和调节器参数;然后基于波特图分析传统功率-电流控制策略下和本文所提功率-电压控制策略下逆变器输出阻抗的频率特性,证明了本文所提功率-电压控制策略稳定性,可以减小PLL带宽和输出功率的影响,从而提高弱电网中逆变器的额定功率注入功率,最后仿真和实验结果验证了所提出控制策略的有效性.     

基于 MEEMD-FN-LSTM 的冷热电联供系统负荷预测∗

针对当前冷热电联供(Combined Cooling,Heating and Power,CCHP)系统优化调度研究缺少冷热电负荷预测的问题,提出了基于改进集成经验模态分解(Modified Ensemble Empirical Mode Decomposition,MEEMD)、模糊熵(Fuzzy Entropy,FN)和长短期记忆神经网络(Long Short Term Memory,LSTM)的CCHP系统负荷预测方法.使用M EEM D算法将原始数据分解为若干IM F分量,计算IM F分量的模糊熵并将模糊熵相近的分量相加,使用LSTM对相加后新的分量进行预测,最后将分量预测结果重构得到最终预测值.通过仿真并对比分析其他方法的负荷预测精度,证明所提预测方法具有良好的预测效果.