Developing only Fe derived bifunctional overall water splitting electrocatalyst both for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) while performing at low onset overpotential and with high catalytic stability is a rare instance. We present here the first demonstration of unique iron-oxide nanobeads (FeOx-NBs) based electrocatalyst executing both OER and HER with high activity. Thin-film electrocatalytic FeOx-NBs assembly is surface grown via simple spray coating (SC). The unique SC/FeOx-NBs propels OER initiating water oxidation just at 1.49 VRHE (η = 260 mV) that is the lowest observable onset potential for OER on simple Fe-oxide based catalytic films reported so far. Catalyst also reveals decently high HER activity and competent overall water splitting performance in the FeOx-NBs two-electrode system as well. Catalyst also presents stable kinetics, with promising high electrochemically active surface area (ECSA) of 1765 cm2, notable Tafel slopes of just 54 mV dec1? (OER) and 85 mV dec1? (HER), high exchange current density of 1.10 mA cm2? (OER), 0.58 mA cm2? (HER) and TOF of 74.29s1?@1.58VRHE, 262s1?@1.62VRHE (OER) and 82.5s1?@-0.45VRHE, 681s1?@-0.56VRHE (HER). 相似文献
This work is based on formulating and optimizing controlled release (CR) valsartan (160 mg) tablets using different viscosity grades of the cellulosic polymer. The objective was to develop an effective once-daily drug delivery system of this cardiovascular agent. Central composite design was used for designing the formulations. Polymers used were Methocel® K4M, K15M and K100M. Compatibility of excipients with active was studied through FT-IR. Micromeritic properties were determined and formulations exhibiting appropriate flow characteristics were compressed. Swelling behavior and in vitro buoyancy effect were studied and response surface curves were constructed to optimize the formulation. Multi-point dissolution profiles of valsartan CR tablets at pH 1.2, 4.5 and 6.8 were obtained. Model-dependent and model-independent methods were performed including f2, stability test as per ICH guidelines and ANOVA. FT-IR studies revealed the compatibility of valsartan with all excipients. Formulation K4T9 (containing 25% K4M polymer) was selected to be the best optimized trial, based on physical properties and controlled release profile (23% at 4 h, 82% at 16 h and 100% at 24 h). Results of buoyancy and swelling behavior indicated that HPMC-K4M polymer exhibited excellent floating lag time and swelling indexes. In vitro drug release kinetics showed that formulation K4T9 displayed Korsmeyer–Peppas drug release pattern with r value > 0.99. The manufacturing process of K4T9 was also found to be reproducible with a shelf life period of 41 and 36 months at room temperature and accelerated conditions, respectively. Valsartan CR matrix-based formulation was successfully prepared with Methocel K4M retardant. 相似文献
Water Resources Management - Drought is recurrently occurring in many parts of the globe. In contrast to other natural hazards, drought has complex climatic characteristics. Several environmental... 相似文献
In this paper, a reliable stochastic numerical analysis for typhoid fever incorporating with protection against infection has been considered. We have compared the solutions of stochastic and deterministic typhoid fever model. It has been shown that the stochastic typhoid fever model is more realistic as compared to the deterministic typhoid fever model. The effect of threshold number T* hold in stochastic typhoid fever model. The proposed framework of the stochastic non-standard finite difference scheme (SNSFD) preserves all dynamical properties like positivity, bounded-ness and dynamical consistency defined by Mickens, R. E. The stochastic numerical simulation of the model showed that increase in protection leads to low disease prevalence in a population. 相似文献
As per the most recent literature, Orthogonal Frequency Division Multiplexing (OFDM), a multi access technique, is considered most suitable for the 3G, 4G and 5G techniques in high speed wireless communication. What made OFDM most popular is its ability to deliver high bandwidth efficiency and superior data rate. Besides it, high value of peak to average power ratio (PAPR) and Inter Carrier Interference (ICI) are the challenges to tackle down via appropriate mitigation scheme. As a research contribution in the present work, an improved self-cancellation (SC) technique is designed and simulated through Simulink to mitigate the effect of ICI. This novel proposed technique (Improved SC) is designed over discrete wavelet transform (DWT) based OFDM and compared with conventional SC scheme over different channel conditions i.e. AWGN and Rayleigh fading environments. It is found that proposed DWT-OFDM with Improved SC scheme outperforms conventional SC technique significantly, under both AWGN and Rayleigh channel conditions. Further, in order to justify the novelty in the research contribution, a Split-DWT based Simulink model for Improved SC scheme is investigated to analyse the BER performance. This Split-DWT based Simulink model presented here foretells the future research potential in wavelet hybridization of OFDM to side-line ICI effects more efficiently.
The wheel of industrialization that spun throughout the last century resulted in urbanization coupled with modifications in lifestyles and dietary habits. However, the communities living in developing economies are facing many problems related to their diet and health. Amongst, the prevalence of nutritional problems especially protein–energy malnutrition (PEM) and micronutrients deficiencies are the rising issues. Moreover, the immunity or susceptibility to infect-parasitic diseases is also directly linked with the nutritional status of the host. Likewise, disease-related malnutrition that includes an inflammatory component is commonly observed in clinical practice thus affecting the quality of life. The PEM is treatable but early detection is a key for its appropriate management. However, controlling the menace of PEM requires an aggressive partnership between the physician and the dietitian. This review mainly attempts to describe the pathophysiology, prevalence and consequences of PEM and aims to highlight the importance of this clinical syndrome and the recent growth in our understanding of the processes behind its development. Some management strategies/remedies to overcome PEM are also the limelight of the article. In the nutshell, early recognition, prompt management, and robust follow up are critical for best outcomes in preventing and treating PEM. 相似文献
The aim of the study was to examine the effects of augmented reality technology on stories in terms of narrative skill, story length and creativity and also to examine correlations between these variables. Posttest-only design with a nonequivalent group model was used. In this study, the sample consisted of 100 fifth-grade elementary students, comprising 46 boys and 54 girls. Purposive and convenience sampling methods were applied. For purposive sampling, the group’s ages, education levels, and experiences in storytelling activities were gathered, and for convenience sampling, easy access to schools was considered. As data collection tools, a suitable narrative scale was used which was found in the literature and creative story form was developed by the researcher. According to the findings, mean scores for all variables for the experimental group were higher than those for the control group. Also, a statistically significant mean difference was found between the experimental and control groups with regard to narrative skill, length of stories, and creativity in stories. In fact, a positive correlation was found between all variables. It is important to recognize when a technology is found to contribute positively to narrative skill and creativity in telling stories, and to ensure this technology is used. Determining correlation between these variables may provide a contribution to studies about evaluating the effect of the new technologies. 相似文献