Upconversion properties of Y2O3：Er films prepared by sol-gel method

Y2O3:Er3+ films were prepared by a simple sol-gel process. The structural properties of Y2O3:Er3+ flints were characterized with X-ray diffraction, Fourier transform infrared spectroscopy and field emission scanning electron microscopy. The results indicated that the Y2O3:Er3+ f'rims might have high upconversion efficiency because of their low vibrational energy. Under 785 and 980 nm laser excitation, the samples showed green (2H11/2→4I15/2, 4S3/2→4I15/2) and red (4F9/2→4I15/2) upconversion emissions. The upconversion mechanisms were stud-led in detail through laser power dependence. Excited state absorption and energy transfer process were discussed as possible upconversion mechanisms. The cross relaxation process in Er3+ was also investigated.     

BCCP内水压承载能力原型试验

为了研究钢筋缠绕钢筒混凝土压力管（BCCP）在内水压作用下的承载破坏特征,设计了三个不同管径的BCCP内水压现场原型试验.在管径1 800 mm BCCP的钢筒、钢筋和混凝土保护层上布置环向应变片,逐级施加内水压至2.5 MPa,得到了各部位在内水压作用下的受力变化规律.主要结论如下:BCCP从生产时施加预应力到承受内水压至最终破坏的受力过程可分为5个阶段.1）管芯受预应力钢筋环向作用力阶段.缠筋后,钢筒与混凝土形成的管芯受到一个初始预压应力;2）保护层开裂前整管承受内水压弹性阶段.对应于试验中内水压小于1.5 MPa的阶段,管芯依然受压,而预应力钢筋和外混凝土保护层受拉;3）保护层开裂,管芯承受内水压弹性阶段.试验中当内水压达到1.6 MPa后,保护层开始达到抗拉强度开裂,混凝土管芯也从初始的受压慢慢转变为受拉,依然处于弹性状态;4）管芯开裂,钢筒和钢筋受拉弹性阶段.当内水压达到2.2 MPa后,管芯径向开裂,但是钢筒和钢筋的应力随内水压依然稳步增长;5）管道破坏阶段.钢筒和预应力钢筋达到最终屈服强度,整管丧失承载能力.研究成果可为BCCP在输调水工程中的推广使用以及相关标准的制定提供依据.     

FRP黏结长度对混凝土三点弯曲梁断裂参数的影响

为探讨纤维增强复合材料(FRP)加固带裂缝混凝土结构的最优性价比,采用损伤断裂试验,研究了FRP黏结长度对混凝土三点弯曲梁试件断裂参数的影响.通过在混凝土三点弯曲梁试件表面粘贴应变片,测试了FRP加固混凝土开裂破坏起裂荷载;利用夹式引伸计测得荷载-裂缝口张开位移曲线,根据改进的断裂韧度计算公式,计算出FRP黏结长度不同的混凝土三点弯曲梁试件的有效裂缝长度a_c,失稳韧度K■和起裂韧度K■.结果表明:对于相同初始裂缝深度的混凝土三点弯曲梁试件,FRP加固混凝土的峰值荷载随着FRP黏结长度的增加而增大,K■和K■均随着FRP黏结长度的增加先增大再减小,当FRP黏结长度为25mm时,FRP加固混凝土三点弯曲梁试件K■和K■的平均值均达到最大,阻裂效果最佳;采用声发射(AE)无损检测技术,对上述混凝土断裂过程中的声发射参量进行识别和采集,发现对于初始缝高比为0.4的FRP加固混凝土三点弯曲梁试件而言,其FRP最佳黏结长度为25mm.     

Photoluminescent properties of SreSiO4：Eu^3＋ and Sr2SiO4：Eu^2＋ phosphors prepared by solid-state reaction method

Eu²⁺ and (or) Eu³⁺ doped Sr₂SiO₄ phosphors particles were synthesized by a conventional solid-state reaction technique, and their structural and optical properties were investigated. The X-ray diffraction (XRD) results showed that the obtained phosphors were composed of orthorhombic α'-Sr₂SiO₄ and monoclinic β-Sr₂SiO₄ phase. When excited under 256 nm, Sr₂SiO₄:Eu³⁺ phosphors showed intense emission in the red region. Sr₂SiO₄:Eu³⁺ phosphors exhibited white emissions (x=0.30, y=0.40, T_C=6500 K) ranging from 425 to 650 nm when it was excited by near-ultraviolet (near-UV) light, indicating that Sr₂SiO₄:Eu²⁺ was a good light-conversion phosphor candidate for near-UV chip.