Synthesis and characterization of La（OH）_3 nanopowders from hydrolysis of lanthanum carbide

The lanthanum carbide alloy was induction melted in vacuum induction melting furnace from lanthanum and graphite with the mass ratio of 89:11. Lanthanum hydroxide (La(OH)3) nanopowders were prepared by a simple hydrolysis of lanthanum carbide at room temperature under normal atmospheric pressure without any surfactant. X-ray diffraction (XRD) showed that the nanoparticles were with a hex-agonal structure. The effect factors such as reaction time,reaction temperature and the mass ratio of lanthanum carbide p...     

Synthesis and characterization of manganese doped CeO2 nanopowders from hydrolysis and oxidation of Ce37Mn18C45

The Mn-doped CeO 2 nanopowders with high catalysis activity were successfully fabricated through a simple hydrolyzed-oxidized approach.Firstly,the alloy Ce 37 Mn 18 C 45 was prepared in vacuum induction melting furnace.Subsequently,Mn-doped CeO 2 nanopowders with 142 m 2 /g of specific surface area were obtained through a simple hydrolyzed-oxidized procedure of the alloy.Those nanopowders were heat treated at different temperatures.The obtained materials were characterized by X-ray diffraction(XRD),transmission electron microscopy(TEM),high-resolution transmission electron microscopy(HRTEM) and energy dispersive spectroscopy(EDS).And the catalytic activity on vinyl chloride(VC) emission combustion was investigated.The results showed that those nanopowders after hydrolyzed-oxidized from Ce 37 Mn 18 C 45 mainly consisted of CeO 2 and Mn 3 O 4.Manganese element increased the thermal stability of CeO 2 nanopowders.The Mn-doped CeO 2 nanopowders had three morphologies.Small particles were Mn-doped CeO 2,square particles were Mn 3 O 4 and the rods were Mn 3 O 4 and Mn 2 O 3.The Mn-doped CeO 2 nanopowders had good vinyl chloride(VC) emission catalytic performance.     

硼对奥氏体耐热钢 TP347H 热加工性、组织和力学性能的影响

试验钢以超临界锅炉用奥氏体耐热钢TP347H(%:0.07C、17.98Cr、10.78Ni、0.70Nb、0.0267N)为炉料,用25 kg真空感应炉在氩气保护下熔炼,并加入0～0.16%B.结果表明,当加B量≥0.02%时,试验钢奥氏体晶粒明显粗化,1 200～950 ℃锻造时锻坯开裂.当加B量约0.01%时,奥氏体耐热钢TP347H具有最佳的综合性能:钢的室温抗拉强度为615 MPa;750℃,120 MPa钢的持久寿命为230 h,伸长率为42%.     

快淬Nd11Fe72Co8V1.5B7.5合金的研究

快淬速度 18m·s-1的Nd11Fe72 Co8V1.5B7.5薄片经 6 5 0℃× 4min晶化处理后 ,晶粒尺寸约 10 0nm ,该快淬薄片经 6 0 0℃× 4min晶化处理后制成的粘结磁体的磁性能 :Br=0 .6 6T ,JHC =780kA·m-1,(BH) max=6 9kJ·m-3 。     

纳米晶Nd10.1Fe76.2Co4.5Zr3B6.2 永磁材料制备工艺和磁性能的研究

采用熔体快淬及热处理工艺制备Nd10.1Fe76.2Co4.5Zr3B6.2永磁材料,研究了制备工艺参数和热处理工艺对材料结构和磁性能的影响.结果表明,粘结磁体的磁性能与熔体快淬和热处理工艺密切相关,快淬速度为20m/s的薄带经690℃×4min退火处理可得到最佳磁性能Br=0.714T、JHc=698kA/m、(BH)max=82.0kJ/m3.     

Nanocrystalline Nd2Fe14B／α—Fe permanent magnet

Nd8.5Fe75Co5Cu1Zr3Nb1B6.5bonded magnet was prepared by melt-spinning(vs=18m/s)and subsequent heat treatment(670℃，4min).Excellent magnetic properties of the bonded magnet were achieved:Br=0.68T,iHc=620.3kA/m,(BH)max=74kJ/m^3.The addition of Cu and Zr elements shows to be advantageous in improving an intrinsic coercivity and squareness of hysteresis loop,as well as energy product.In has a remarkable remanence enhancement and the isotropic saturation remanence ratio Mr/Ms is 0.83.     

纳米晶复合Nd9.5Fe81-xCoxZr3B6.5永磁材料磁性能的研究

采用熔体快淬及晶化退火工艺制备了Nd9.5Fe81-xCoxZr3B6.5(x=0、2、5、8、10)纳米晶合金条带,研究了Co的添加对快淬合金磁性能和居里温度的影响.结果表明,适量Co元素的添加能够有效降低各相晶粒的尺寸,增强了软、硬磁相晶粒的交换耦合作用,从而提高了合金的磁性能.Co含量为5%(原子分数)的合金,经670℃/4min的晶化处理后所得到的最佳磁性能为`Br=0.90T,jHc=588kA/m,(BH)max=117kJ/m3.     

Cr对纳米晶复合Nd2Fe14 B/α-Fe永磁材料磁性能的影响

采用快淬和晶化退火法制备了成分为Nd8.5Fe75-xCo5Cu1Nb1Zr3CrxB6.5(x=0.5,1,2)的纳米晶复合永磁合金.研究了Cr的添加对合金晶粒尺寸及磁性能的影响,结果表明适量Cr的添加能有效抑制磁性相晶粒长大,提高了合金的矫顽力.Cr含量为1%(at%),快淬速度为15.0m/s的合金经690℃/4min的晶化处理,由晶化磁粉粘结所得到的磁体最佳磁性能为:Br=0.62T,jHc=806.4kA/m,(BH)max=69.0kJ/m3.     

表面状态对Fe3（Al,Cr,Zr,B）金属间化合物环境脆性的影响

研究了不同热处理工艺及不同表面状态对Ｆｅ３（Ａｌ，Ｃｒ，Ｚｒ，Ｂ）金属间化合物环境脆性的影响。结果表明在不同气氛中的拉伸塑性依次为Ｏ２＞Ａｒ＞Ａｉｒ＞Ａｒ＋Ｈ２Ｏ。带氧化皮或在试样表面涂上油脂可以有效消除其环境脆性。轧态条状组织在空气中的拉伸塑性明显高于再结晶组织。     

碳化镧锰水解氧化法制备La0.978Mn0.946O3氧化物

碳化镧锰合金在室温常压下进行水解氧化反应,洗涤并在50～80℃烘干得到La(OH)3和Mn3O4纳米粉。探讨了反应温度、反应时间、悬浮液浓度和碳化镧锰颗粒大小对晶粒尺寸的影响。优化工艺条件为:反应温度35℃,反应时间18 h,悬浮液浓度0.1 g/ml,碳化镧锰颗粒小于0.15 mm,得到比表面积为122.6 m2/g的La(OH)3和Mn3O4纳米粉。将该纳米粉分别在400、600、800℃和1 000℃煅烧2 h,最终得到晶化程度较好的La0.978Mn0.946O3氧化物。