Measurements and Calculations of the Halfwidth of Two Rotational Transitions of Water Vapor Perturbed by N2, O2, and Air

In this paper we report the results of both an experimental and theoretical study of the halfwidths of two transitions of water vapor. Measurements on the lines of the H216O and H218O isotopomers located at 325.1 and 203.4 GHz, respectively, were carried out in the temperature range 300-393 K, with N2 and O2 as perturbing gases. The foreign-broadening coefficients and their temperature-dependence parameters were determined assuming a Voigt profile and the usual temperature dependence for the halfwidth. The retrieved values are compared to values calculated using the complex semiclassical formalism of Robert and Bonamy. The assumed intermolecular potential is a combination of electrostatic and atom-atom components. This last contribution is defined as the sum of pairwise Lennard-Jones 6-12 interactions between the atoms of H2O and the atoms of the perturbing molecules expanded to eighth order. Also calculated are the pressure-induced shifts of the spectral lines for temperatures from 200 to 400 K. Calculated and experimental results are in good agreement, within +/-3.2%, except for the N2-broadening temperature coefficients, for which there are discrepancies as high as 23%. Air-broadening parameters are determined following the classical relation: gamma (air) = 0.79gamma (N2) + 0.21gamma (O2). Copyright 1999 Academic Press.     

Establishing an objective basis for image compositing in satellite oceanography

This study strives to establish an objective basis for image compositing in satellite oceanography. Image compositing is a powerful technique for cloud filtering that often emphasizes cloud clearing at the expense of obtaining synoptic coverage. Although incomplete cloud removal in image compositing is readily apparent, the loss of synopticity, often, is not. Consequently, the primary goal of image compositing should be to obtain the greatest amount of cloud-free coverage or clarity in a period short enough that synopticity, to a significant degree, is preserved.To illustrate the process of image compositing and the problems associated with it, we selected a region off the coast of California and constructed two 16-day image composites, one, during the spring, and the second, during the summer of 2006, using Advanced Very High Resolution Radiometer (AVHRR) InfraRed (IR) satellite imagery. Based on the results of cloud clearing for these two 16-day sequences, rapid cloud clearing occurred up to day 4 or 5, followed by much slower cloud clearing out to day 16, suggesting an explicit basis for the growth in cloud clearing. By day 16, the cloud clearing had, in most cases, exceeded 95%. Based on these results, a shorter compositing period could have been employed without a significant loss in clarity.A method for establishing an objective basis for selecting the period for image compositing is illustrated using observed data. The loss in synopticity, which, in principle, could be estimated from pattern correlations between the images in the composite, was estimated from a separate time series of SST since the loss of synopticity, in our approach, is only a function of time. The autocorrelation function of the detrended residuals provided the decorrelation time scale and the basis for the decay process, which, together, define the loss of synopticity. The results show that (1) the loss of synopticity and the gain in clarity are inversely related, (2) an objective basis for selecting a compositing period corresponds to the day number where the decay and growth curves for synopticity and clarity intersect, and (3), in this case, the point of intersection occurred 3.2 days into the compositing period. By applying simple mathematics it was shown that the intersection time for the loss in synopticity and the growth in clarity is directly proportional to the initial conditions required to specify the clarity at the beginning of the compositing period, and inversely proportional to the sum of the rates of growth for clarity and the loss in synopticity. Finally, we consider these results to be preliminary in nature, and, as a result, hope that future work will bring forth significant improvements in the approach outlined in this study.     

Pregnancy loss and autoantibodies against phospholipid-binding proteins

We investigated the utility of two approaches for exploiting pleiotropy to search for genes influencing related traits. To do this we first assessed the genetic correlations among a set of five closely related quantitative traits (Q1, Q2, Q3, Q4, Q5). We then used the genetic correlations among these five traits both to remove the common genetic effects of the four remaining traits, thereby identifying the unique genetic contribution to each trait, and to extract a synthetic phenotype which exploits the shared genetic information (pleiotropy) among these five traits. After obtaining these conditional traits, we then searched for evidence of quantitative trait loci (QTLs) (using variance component linkage) influencing the unique residual genetic component for each trait as well as those influencing the expression of the synthetic traits. From this work, we conclude that the removal of the common genetic effects of other traits in a group may be of greater utility when the majority of the pleiotropy initially detected between traits is attributable to the shared additive effects of polygenes, rather than to those of major loci. By contrast, decomposition of the genetic covariance matrix to its principal components is a greater utility when the majority of pleiotropy is attributable to major loci.     

Arsenic in drinking water and incidence of urinary cancers

To investigate the effects of a new nonNMDA antagonist on the trisynaptic pathways in the hippocampus, the author examined kainate(KA)-induced generalized seizures in rats. A novel nonNMDA antagonist, YM90K, showed the blockade of the Schaffer collaterals in 2-deoxyglucose study (2-DG) and that the CA1-2 pyramidal cells of the hippocampus were preserved seven days after the KA injections. On the other hand, the control and MK-801 (NMDA-antagonist) treated rats did not depress the Schaffer collaterals and showed persistent hypermetabolism of glucose in the CA1 pyramidal cell layer, where neurons were not preserved seven days later. 2-DG was useful to reveal the effects of nonNMDA antagonist on the KA-induced generalized seizures. This suggests that YM90K is a potent nonNMDA antagonist and that it has a neuroprotective effect in rats.