Applying reticular synthesis to the design of Cu-based MOFs with mechanically interlocked linkers

The concept of“robust dynamics”describes the incorporation of mechanically interlocked molecules(MIMs)into metal-organic framework(MOF)materials such that large amplitude motions(e.g.,rotation or translation of a macrocycle)can occur inside the free volume pore of the MOF.To aid in the preparation of such materials,reticular synthesis was used herein to design rigid molecular building blocks with predetermined ordered structures starting from the well-known MOF NOTT-101.New linkers were synthesized that have a T-shape,based on a triphenylene tetra-carboxylate strut,and their incorporation into Cu(II)-based MOFs was investigated.The single-crystal structures of three new MOFs,UWCM-12(fof),β-UWCM-13(loz),UWCM-14(lil),with naked T-shaped linkers were determined;β-UWCM-13 is the first reported example of the loz topology.A fourth MOF,UWDM-14(lil)is analogous to UWCM-14(lil)but contains a[2]rotaxane linker.Variable-temperature,²H solid-state NMR was used to probe the dynamics of a 24-membered macrocycle threaded onto the MOF skeleton.     

Efficiency of sediment transport by flood and its control in the Lower Yellow River

1IntroductionIntheriversystemwithsediment-ladenflow,WaterUseforSedimentTransport(WUST)isaveryimportantcomponentofecologicalwaterdemands,whichmaintainfundamentalfunctionofallecosystemcomponentsataspecificlevelofcondition[1].EnoughWUSTisthepremisetokeepthestableriver-bedandhealthyriverecosystem;alsoitisthebaseflowofriverfortheexploitationofwaterresources.Comparingwithotherrespectsrelatedwithwaterdemandsofriverecosystemsuchastheminimumflowforfishesorripariantrees,researchesontheWUSTarequite…     

Particle simulation of the failure process of brittle rock under triaxial compression

In order to investigate the failure process of brittle rock under triaxial compression through both experimental and numerical approaches, the particle simulation method was used in numerical simulations and the simulated results were compared with those of the experiment. The numerical simulation results, such as fracture propagation, microcrack distribution, stress-strain response, and damage patterns, were discussed in detail. The simulated results under various confining pressures (0-60 MPa) are in good...     

Comprehensive assessment on dynamic roof instability under fractured rock mass conditions in the excavation disturbed zone

The damage process of fractured rock mass showed that the fracture in rocks induced roof collapse in Yangchangwan Coal Mine,China.The rock mass was particularly weak and fractured.There occurred 6 large-scale dynamical roof falls in the excavation disturbed zone (EDZ) with the collapsing volume of 216 m3.First,the field detailed geological environment,regional seismic dy-namics,and dynamic instability of roadways were generally investigated.Second,the field multiple-index monitoring measurements for detecting the deep delamination of the roof,convergence deformation,bolt-cable load,acoustic emission (AE) characteristic pa-rameters,total AE events,AE energy-releasing rate,rock mass fracture,and damage were arranged.Finally,according to the time-space-strength relations,a quantitative assessment of the influence of rock-mass damage on the dynamic roof instability was accomplished.     

Ultralight X-type lattice sandwich structure (I): Concept,fabrication and experimental characterization

A new type of ultra-lightweight metallic lattice structure (named as the X-type structure) is reported. This periodic structure was formed by two groups of staggered struts in the traditional pyramid structure, and fabricated by folding expanded metal sheet along rows of offset nodes and then brazing the folded structure (as the core) with top and bottom facesheets to form sandwich panels. The out-of-plane compressive and shear properties of the X-type lattice sandwich structure were investigated experimentally and compared to those of the sandwich having a pyramidal truss core. It is found that the formation of the 2-dimensional staggered nodes can effectively make the X-type structure more resistant to inelastic and plastic buckling under both compression and shear loading than the pyramidal lattice truss. Obtained results show that the compressive and shear peak strengths of the X-type lattice structure are about 30% higher than those of the pyramidal lattice truss having the same relative density. Supported by the National Basic Research Program of China (“973” Project) (Grant No. 2006CB601202), the National Natural Science Foundation of China (Grant Nos. 10632060,10825210), the National “111” Project of China (Grant No. B06024) and the National High-Tech Research and Development Program of China (“863” Project) (Grant No. 2006AA03Z519)     

Incoherent scatter spectra due to HF heating in the low ionosphere region

The electron velocity distribution function and the incoherent scatter spectra during ionospheric heating in low ionosphere region are presented with consideration of the elastic collision between electrons and neural particles and the excitation of rotation energy level. The effects of pump frequency and electric fields on the spectra are discussed. With the increase of electric field, the non-Maxwellian feature is enhanced, and with the increase of heating frequency, the non-Maxwellian feature is weakened. The non-Maxwellian factor will bring a large error in ionosphere parameters, which must be considered in the inversion. Supported by the National Natural Science Foundation of China (Grant No. 40310223), the National Key Laboratory of Electromagnetic Environment (LEME), and National Key Technologies R&D Program of China (Grant No. 2006BAB18B06)     

Research on indoor experimentation of range SAL imaging system

By means of advantages of both SAR and lidar, the combination of the techniques of (inverse) synthetic aperture and lidar makes it possible to obtain high resolution 2-D image. In this paper, an indoor experimental system of inverse synthetic aperture lidar imaging is given and a processing approach is presented. The given system is in the mode of lidar system with separated receiver and transmitter, which can effectively eliminate the jamming from the lens or/and the intersection between two optic fibers. ...     

Gearbox fault diagnosis of rolling mills using multiwavelet sliding window neighboring coefficient denoising and optimal blind deconvolution

Fault diagnosis of rolling mills, especially the main drive gearbox, is of great importance to the high quality products and long-term safe operation. However, the useful fault information is usually submerged in heavy background noise under the severe condition. Thereby, a novel method based on multiwavelet sliding window neighboring coefficient denoising and optimal blind deconvolution is proposed for gearbox fault diagnosis in rolling mills. The emerging multiwavelets can seize the important signal proce...     

一种高效的电子政务系统的设计与应用

计算机网络技术的出现,全球信息化改变着人们的生活方式,世界各国高度重视发展电子政务,它是一个国家及城市竞争力水平的标志之一.在这样严峻的社会形势下,建立一个高效的电子政务系统是十分必要的.首先,分析了建立电子政务系统的必要性、特点、功能;然后,提出了电子政务系统的体系模型,设计出了功能结构图和网络结构图,详细地描述了方案思路;最后,把此模型应用到商洛市旅游行业中,经过调查数据研究分析,政务系统的出现给旅游业带来巨大的变化,整个城市的经济、影响力大幅度上升.     

优等品硫磺

对于在储运过程中遇到的某些现实情况,广泛采用的"优等品"硫磺标准并非总是适用的.提出对加拿大硫磺开发研究所1977年公布的《成型固体硫磺优等品质量标准》中的一些指标进行修订.建议在加入SLS之前硫磺的水分质量分数为0.8%～1.8%,硫化氢质量分数小于0.003%.