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The effects of grain size, space velocity, temperature and reactant concentration on the kinetics of NOx reduction with propane over Co-β-zeolite catalyst were investigated. The external mass transfer phenomenon was examined by varying the space velocity. The results show that the transfer can be negligible when the space velocity is greater than 60000 h-1 in low temperature range. However, the transfer exists at high temperatures even when the space velocity reaches a high level.Variation of the catalyst grain size from 0.05 to 0.125 mm does not change the conversion rate of NOx. The concentrations of components, NOx, C3H8 and O2, were also investigated to have a better understanding of mechanism. Based on the experimental data, the selectivity formula was proposed. The results shows that lower temperature is helpful to get higher selectivity as the activation energy of hydrocarbon oxidation, Ea,2, is greater than that of NOx reduction, Ea,1, (Ea,2>Ea,1). High NOx concentration and low C3H8 concentration are beneficial to high selectivity. However in order to maintain high activity simultaneously, the temperature and C3H8 concentration should be high enough to promote NOx reduction. 10%(ψ) H2O and 75×10-6(ψ) SO2 were introduced into the reaction system, and Co-β-zeolite shows strong resistance to water and SO2. 相似文献
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研究的重点是风化煤中主要成分黄腐植酸钙溶解平衡,从难溶盐的酸溶解和配位溶解以及升高温度时对其溶解的影响3方面入手进行探讨研究,找到最佳溶解条件,以提高从风化煤中黄腐植酸溶出分离的目的。 相似文献
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为了研究综放工作面覆岩破断特征的微震效应,对中煤平朔集团有限公司井工三矿39107工作面进行了微震监测,得出的结论是:工作面倾向的微震事件分布和矿压分布规律均表现为以工作面中部为轴线的对称分布形态,工作面顶板岩层以工作面中部垮断破坏最为剧烈,向两端逐渐趋于缓和;采空区边缘外的微震事件呈线性分布,倾向方向的岩层裂缝角为65°;在工作面前方50m以外微震事件总体表现较为平和,煤岩体微震事件处于萌芽期,在工作面50m范围内微震时间的数量和能量也随之增加,微震事件处于孕育期,当进入20m范围内时,微震事件分布总体表现为密集剧烈的特征,微震事件处于多发期;在工作面前方20 m范围内,微震事件能量最大但数量较小,工作面后方20m范围内微震事件数量最多但能量较小;微震事件的能量随着周期来压的产生也发生周期性变化:来压之前基本顶已经出现超前的关键断裂,微震事件能量的高峰期比初次来压和周期来压在时间上具有超前性,利用该特性,可有效地对初次来压和周期来压进行预测预报. 相似文献
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随着科学技术的发展,先进的技术也在煤矿中得到了应用。自动化技术作为先进技术的代表,给煤矿生产效率带了巨大提升。本文介绍了煤矿井下工作面自动控制系统,首先分析了其组成结构,然后重点分析了主要功能和优势,最后简要介绍了其在生产中的应用情况,有助于加深采矿工程技术人员对煤矿自动化的认识。 相似文献
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作为电力系统中输送电能的核心设备之一,变压器的重要性不可忽视。一旦变压器发生故障将势必对电力系统运行造成重大影响,威胁到季统的稳定性,甚至还会导致严重的经济损失。变压器差动保护在近端区外发生故障时由于非周期短路电流的存在会直接使故障点侧电流互感器达到饱和状态,造成一次电流与二次电流之间的连接出现紊乱,这一误差势必将扩大回路不平衡电流的数值。CT的饱和状态使得制动电流难以达到期望值,这是造成误动作的直接原因。本文重点分析了10kV线路故障引起主变差动保护动作的故障处理。 相似文献