Synergistic Effects of Polybenzimidazole and Aramide on Enhancing Flame-Retardancy and Solubility

Aromatic and functional polymers with processibility derived from biobased starting materials are prerequisite considering sustainable society. Poly(2,5-benzimidazole)s are rigid-rod polymers to show ultrahigh thermal stability such as flame retardance, while usually suffer from poor solubility. Here, poly(benzimidazole-co-amide)s are synthesized from two biobased monomers, 3,4-diaminobenzoic acid and a semirigid comonomer, 4-aminohydrocinnamic acid. The copolymers with an amide composition of 80 mol% and higher are soluble in widely used polar solvents to fabricate the films keeping high flame retardance, which is comparable with popular high-performance polymers such as aromatic polyimides, polyetheretherketone, polyphenylene sulfide, etc.     

Linear circuits: a measurement‐based approach

This paper proposes a new measurement‐based approach that can solve synthesis problems in unknown linear circuits. The method makes use of a small number of measurements to determine the functional dependency of any circuit signal or variable on any set of design variables. Once the functional dependency is obtained, the design requirements can be applied to find the design parameter values. The results are described for linear direct current and alternating current circuits. Copyright © 2013 John Wiley & Sons, Ltd.     

A simulation as a service cloud middleware

Many seemingly simple questions that individual users face in their daily lives may actually require substantial number of computing resources to identify the right answers. For example, a user may want to determine the right thermostat settings for different rooms of a house based on a tolerance range such that the energy consumption and costs can be maximally reduced while still offering comfortable temperatures in the house. Such answers can be determined through simulations. However, some simulation models as in this example are stochastic, which require the execution of a large number of simulation tasks and aggregation of results to ascertain if the outcomes lie within specified confidence intervals. Some other simulation models, such as the study of traffic conditions using simulations may need multiple instances to be executed for a number of different parameters. Cloud computing has opened up new avenues for individuals and organizations with limited resources to obtain answers to problems that hitherto required expensive and computationally-intensive resources. This paper presents SIMaaS, which is a cloud-based Simulation-as-a-Service to address these challenges. We demonstrate how lightweight solutions using Linux containers (e.g., Docker) are better suited to support such services instead of heavyweight hypervisor-based solutions, which are shown to incur substantial overhead in provisioning virtual machines on-demand. Empirical results validating our claims are presented in the context of two case studies.     

CVD synthesis of graphene nanoplates on MgO support

Synthesis of graphene directly on MgO has been carried out and the structural properties of the obtained material have been investigated. Few-layered graphene was produced by simple thermal decomposition of methane over MgO powder at 950 °C in a CVD reactor. The samples were purified by 10 N HNO₃ treatment, and studied by TEM, Raman spectroscopy, EDAX and SEM. TEM clearly indicated the formation of graphene. EDAX showed that the purified sample contained only carbon and no traces of MgO. The characteristic Raman features of graphene were also seen as D-band at 1316 cm^?1, G-band at 1602 cm^?1, and a small 2D-band at 2700 cm^?1 in the Raman spectra. The strong D-band suggests that the graphene possess large number of boundary defects. The small 2D-band indicates the formation of few-layered graphene.     

Unified BER and optimum threshold analysis of binary modulations in simple and cascaded Rayleigh fading channels with switched combining

Following a unified analytical framework, the bit error rate (BER) of several coherent and non‐coherent binary modulation schemes is derived for a switched diversity system. The two variants of switched combining that have been investigated are switch and stay combining and switch and examine combining. For channel modelling, at first a simple slow flat fading channel is assumed, where the amplitude attenuation obeys the Rayleigh distribution. Later the BER calculations are repeated for cascaded Rayleigh fading channel case. Rayleigh fading is the most popular model for electromagnetic signal propagation in wireless media when both or either of the transmitter/receiver is fixed. On the other hand, when both the transmitter and the receiver are mobile, a cascaded (or double) Rayleigh fading model is better suited. The applicability of these two models, namely simple and cascaded Rayleigh model, has been indicated by several theoretical studies and their suitability is established by various field measurements. In our paper, simple closed‐form BER expressions as a function of switching threshold have been found and optimum switching thresholds have been computed for both these models as well as for both types of diversity combining described earlier. The results presented in this paper can be very useful for communication system designers to analyze link quality of switched diversity assisted systems in various wireless environments. Copyright © 2010 John Wiley & Sons, Ltd.     

SEP calculations for coherent M‐ary FSK in different fading channels with MRC diversity

In this paper, the authors derive symbol error probability (SEP) expressions for coherent M‐ary frequency shift keying (MFSK) modulation schemes in multipath fading channels. The multipath or small‐scale fading process is assumed to be slow and frequency non‐selective. In addition, the channel is also subjected to the usual degradation caused by the additive white Gaussian noise (AWGN). Different small‐scale fading statistics such as Rayleigh, Rician (Nakagami‐n), Hoyt (Nakagami‐q), and Nakagami‐m have been considered to portray diverse wireless environments. Further, to mitigate fading effects through space diversity, the receiver front‐end is assumed to be equipped with multiple antennas. Independent and identically distributed (IID) as well as uncorrelated signal replicas received through all these antennas are combined with a linear combiner before successive demodulation. As the detection is coherent in nature and thus involves phase estimation, optimum phase‐coherent combining algorithms, such as predetection maximal ratio combining (MRC), may be used without any added complexity to the receiver. In the current text, utilizing the alternate expressions for integer powers (1≤n≤4) of Gaussian Q function, SEP values of coherent MFSK are obtained through moment generating function (MGF) approach for all the fading models (with or without MRC diversity) described above. The derived end expressions are composed of finite range integrals, which can be numerically computed with ease, dispenses with the need of individual expressions for different M, and gives exact values up to M=5. When the constellation size becomes bigger (M≥6), the same SEP expressions provide a quite realistic approximation, much tighter than the bounds found in previous literatures. Error probabilities are graphically displayed for each fading model with different values of constellation size M, diversity order L, and for corresponding fading parameters (K, q, or m). To validate the proposed approximation method extensive Monte‐Carlo simulations were also performed, which show a close match with the analytical results deduced in the paper. Both these theoretical and simulation results offer valuable insight to assess the efficacy of relatively less studied coherent MFSK in the context of the optimum modulation choice in wireless communication. Copyright © 2010 John Wiley & Sons, Ltd.     

Simulation of forced convection in non-Newtonian fluid through sandstones

Numerical simulation is carried out to study forced convection in non-Newtonian fluids flowing through sandstones. Simulation is carried out using lattice Boltzmann method (LBM) for both shear-thinning and shear-thickening, by varying the power law index from 0.5 to 1.5 in Carreau–Yasuda model. Parameters involved in LBM and Carreau model are identified to achieve numerical convergence. Permeability and porosity are varied in the range of 10^?10–10^?6 and 0.1–0.7, respectively, to match actual geometrical properties of sandstone. Numerical technology is validated by establishing Darcy's law by plotting the graph between velocity and pressure gradient. Consequently, investigation is carried out to study the influence of material properties of porous media on flow properties such as velocity profiles, temperature profiles, and Nusselt number.     

DEVOLATILIZATION STUDIES ON A BITUMINOUS COAL UNDER VARIOUS GAS ENVIRONMENTS

ABSTRACT

Devolatilization of a bituminous coal was studied in the temperature range 3 50°C to 550°C and at two pressures: 30 psig and 375 psig. Three separate particle sizes were investigated: (?2, +l),(?4, +3) and (?9, +6) mm. The runs, lasting up to 30 minutes, were carried out under two different types of flowing gas environments: a synthetic gas mixture of composition similar to that entering the devolatilization zone from the gasification zone below in a fixed bed gasifier, and containing 3% steam by volume; and, a helium-steam mixture, also containing 3% steam by volume.

The gas evolution rates from devolatilization show a peak at 5–10 minutes from the start of a run and then gradually taper off to zero as the run progresses. The concentration of methane in the off-gas stream is observed to be higher in the helium runs. There, however, is no significant effect of gas environment on the molecular weights of the tar, which show a maximum in the range 300–500. The tar yields, however, are higher for the helium runs; in all cases, the tar yields peak at 4 °C. The gas yield, however, is higher for the reactive gas environment. The total volatiles yield appears independent of particle size; however, it seems to increase with pressure, over the temperature range studied.