Classification of feeding fats by FT‐IR spectroscopy

In this paper, a technique useful for the classification of different food oil co‐ and by‐products of potential use for feed preparation is shown. The proposal is based upon a Fourier transform infrared evaluation of different classes of compounds, and its elaboration was carried out starting from the knowledge of the chemical composition of each feedstock category. Using this technique, a sure classification of fatty acid calcium soaps, fully hydrogenated fatty acids, lecithins, acid oils from chemical refining, acid oils from physical refining and fish oils can be easily done. The remaining categories of animal fats, fried oils and oils recovered from exhausted bleaching earth can be differentiated by using one or two additional chemical tests. The scope of this paper is to provide a quick, easy and non‐expensive tool for a correct classification of feedstock, in order to allow the choice of correct and applicable analytical tests for the evaluation of the quality and of the composition of each sample.     

Hyperhomocysteinemia: Focus on Endothelial Damage as a Cause of Erectile Dysfunction

Erectile Dysfunction (ED) is defined as the inability to maintain and/or achieve a satisfactory erection. This condition can be influenced by the presence of atherosclerosis, a systemic pathology of the vessels that also affects the cavernous arteries and which can cause an alteration of blood flow at penile level. Among the cardiovascular risk factors affecting the genesis of atherosclerosis, hyperhomocysteinemia (HHcys) plays a central role, which is associated with oxidative stress and endothelial dysfunction. This review focuses on the biological processes that lead to homocysteine-induced endothelial damage and discusses the consequences of HHcys on male sexual function     

Integrators’ Air Transport Networks in Europe

Integrators are shipping carriers that control complete air and road delivery networks and offer a wide range of package delivery services. Despite the increasing relevance of small package delivery services in the European air transport market, very little has been written on integrated carriers’ air transport networks on the Old Continent. In this paper we examine the network configurations of DHL, FedEx, TNT, and UPS in terms of hubs, spokes, and market shares. Our results show that integrators operate hub-and-spoke networks. Network indices and centrality measures confirm that their network structures are more similar to those of full-service passenger carriers rather than those of low-cost carriers. However, the nature of their hub-and-spoke systems is different because freight tons, as compared to passengers, are more easily flown along multiple-stop and circular routes. As a consequence, FedEx, TNT, and UPS operate non-pure star networks with a dominant central hub and a set of intermediate airports acting as stops between the central hub and (usually) one “external airport”. DHL operates a multi-hub architecture, with a main dominant hub in Leipzig and a set of “secondary hubs” that provide several connections to other network nodes. Furthermore, we provide evidence of the most important intra-Europe and long-haul routes for each integrator, showing that DHL seems to have a more developed Europe-Asia connection, and is the only integrator to connect Europe to Sub-Saharan Africa. Finally, we show the high degree of complementarity existing between FedEx and TNT networks and that such complementarity is confirmed also by an analysis of their market shares in the different European sub-markets. Despite the significant level of market concentration, our analysis shows that the recent merger between FedEx and TNT is not expected to significantly modify market equilibrium in Europe.

     

Quantitative analysis of convective dose in hemofiltration and hemodiafiltration: "predilution" vs. "postdilution" reinfusion

In hemofiltration (HF) and hemodiafiltration (HDF), removal of medium and high-molecular-weight solutes is greatly enhanced by convective mechanisms as compared with simple diffusion; increasing convective flows may allow greater removal rates of these solutes. Use of "predilution" (pre-H[D]F) may allow higher ultrafiltration rates than the "postdilution" mode (post-H[D]F); yet, the dilution of plasma water may have unpredictable effects on "endogenous" water convection. We have applied a mathematical analysis to evaluate and compare endogenous water convective flow rates in pre-H(D)F vs. post-H(D)F. Endogenous plasma water recovered in ultrafiltrate was calculated according to patient (hematocrit, total protein level) and session parameters (blood flow, ultrafiltration rate, programmed weight loss), in absolute terms and as a fraction of endogenous plasma water delivery to the filter. Maximally efficient post-H(D)F was modelled according to a preset postfilter hematocrit or filtration fraction. Nomograms were constructed expressing endogenous water convective fluxes in relation to parameters of interest (ultrafiltration rate, blood flow, hematocrit) with both post-H(D)F and pre-H(D)F, and "efficiency" of pre-H(D)F vs. post-H(D)F (as the ratio of endogenous water convective flow rate with the 2 techniques) as a function of the ultrafiltration/reinfusion rate. In post-H(D)F, the model predicts maximal ultrafiltration rates within the limits of a preset hemoconcentration at the filter outlet; additionally, the model allows to calculate ultrafiltration/reinfusion quantities to be set in pre-H(D)F to equal and overcome maximal convective efficiency of post-H(D)F. This "equivalence" ultrafiltration rate may greatly vary according to patient's hematocrit and blood flow, so that the ultrafiltrate-reinfusate volume available in the system dictates, in any patient, which mode of reinfusion may attain higher "endogenous" convective flow rates. Pre-H(D)F may allow higher fractional and absolute "endogenous" convective flow rates as compared with post-H(D)F, provided that adequate amounts of reinfusate are available. For lower reinfusate volumes than "equivalence" values, post-H(D)F remains a better option.     

Surface heat flow density at the phlegrean fields caldera (SOUTHERN ITALY)

The Phlegrean Fields area is a Holocene caldera located west of Naples, southern Italy. The recent post-caldera activity is characterized by several eruptive centers inside the collapsed area. In order to investigate the still active volcanic processes, surface heat flow measurements were carried out in 1995 in 30 sites of the Phlegrean Fields, and a heat flow map compiled. Filtering of the map reveals some well-defined anomalies superimposed on a general southward-increasing trend. Local anomalies are related to small magma bodies, whereas the observed general trend has been attributed to the effect of groundwater flow. This effect was calculated and removed. The undisturbed mean value of the surface heat flow density in the eastern sector is 149 mW\m², which is above the regional value of 85 mW\m² assigned to the eastern part of the Tyrrhenian Sea, and which is probably influenced by a very large, deep magmatic body.     

A surface roughness predictive model in deterministic polishing of ground glass moulds

The introduction of deterministic NC grinding and polishing operations, in the manufacturing of free-form glass components for precision optics, requires the characterization of surface topography evolution as a function of process parameters. In this work, a model based on Reye's wear hypothesis is proposed for the assessment of surface roughness prediction as a function of operating parameters, in the deterministic polishing process of glass moulds. According to Reye's hypothesis, the removed material per unit area is proportional to the work due to the friction force: the removed material per unit area can be computed by adequately integrating the areal material ratio function (Abbott–Firestone curve) of the surface and can be associated with the amplitude roughness parameter; the work due to the friction force per unit area is proportional to the integral of the product of pressure and velocity in the time interval and can be derived from the process parameters by means of the Hertz theory. The model assessment was performed on ground glass flat samples polished with different operating parameters, mapping the surface roughness using an atomic force microscope (AFM). The developed model shows a satisfactory estimate of surface roughness evolution during the polishing process and confirms the experimental results found in the literature for the Preston coefficient.     

Development and characterization of a modular acquisition system for a 4D PET block detector

Next generation PET scanners should fulfill very high requirements in terms of spatial, energy and timing resolution. Modern scanner performances are inherently limited by the use of standard photomultiplier tubes. The use of Silicon Photomultiplier (SiPM) matrices is proposed for the construction of a 4D PET module based on LSO continuous crystals, which is envisaged to replace the standard PET block detector. The expected spatial resolution of the module for the photon hit position is below 1 mm, and it will perform at the same time, the Depth Of Interaction (DOI) calculation and the Time Of Flight (TOF) measurement. The use of large area multi-pixel Silicon Photomultiplier (SiPM) detectors requires the development of a multichannel Digital Acquisition system (DAQ) as well as of a dedicated front-end in order not to degrade the intrinsic detector performances. We have developed a flexible and modular DAQ system for the read-out of two modules in time coincidence for Positron Emission Tomography (PET) applications. The DAQ system is based on a previously developed custom front-end ASIC chip (BASIC) which allows to read-out SiPM matrices preserving their spectroscopy and timing capabilities. Here we describe the acquisition system architecture and its characterization measurements.     

Nonlinear dynamic allocator for optimal input/output performance trade-off: Application to the JET tokamak shape controller

In this paper, we revisit the dynamic allocation scheme for input redundant plants proposed in Zaccarian (2009). within a set-point regulation setting and propose generalizations that apply to cases where the plant under consideration is not input redundant but the control specifications allow us to modify the set-point regulation within certain bounds. In this case, the input allocator is extended to the nonredundant case by allowing it to improve the input allocation selection at the price of some output regulation error. We also establish here desirable convergence properties of the allocator, which were only addressed for the linear case in Zaccarian (2009). In particular, we design the allocator dynamics as the gradient of a cost function and establish its convergence to the minimum of the cost function under some mild conditions. The allocation scheme is applied to the JET tokamak shape controller by illustrating its capabilities to enforce coil currents selections that tend to move away from the saturation limits within the allowable degrees of freedom.     

The Mixed Robust /FTS Control Problem Analysis and State Feedback Control

In this paper we deal with the mixed  /finite‐time stability control problem. More specifically, given an open loop uncertain linear system, we provide a necessary and sufficient condition for quadratic input‐output finite‐time stability with an  bound. Exploiting this result we also give a sufficient condition to solve the related synthesis problem via state‐feedback. The property of quadratic input‐output finite‐time stability with an  bound implies that the system under consideration satisfies an  performance bound between the disturbance input and the controlled output and, at the same time, is input‐output finite‐time stable for all admissible uncertainties. This condition requires the solution of a feasibility problem constrained by a pair of differential linear matrix inequalities (LMIs) coupled with a time‐varying LMI. The proposed technique is illustrated by means of both a numerical and a physical example.