Biocatalytic electrode improvement strategies in microbial fuel cell systems

Microbial fuel cells (MFCs) produce electricity as a result of the microbial metabolism of organic substrates, hence they represent a sustainable approach for energy production and waste treatment. If the technology is to be implemented in industry, low cost and sustainable bioelectrodes must be developed to increase power output, increase waste treatment capacity, and improve service intervals. Although the current application of abiotic electrode catalysts, such as platinum and electrode binders such as Nafion leads to greater MFC performance, their use is cost prohibitive. Novel bioelectrodes which use cost effective and sustainable materials are being developed. These electrodes are developed with the intention to reduce start-up time, reduce costs, extend life-span and improve core MFC performance metrics (i.e. power density, current density, chemical oxygen demand (COD) reduction and Coulombic efficiency (CE)). Comparison of different MFC systems is not an easy task. This is due to variations in MFC design, construction, operation, and different inocula (in the case of mixed-culture MFCs). This high intra-system variability should be considered when assessing MFC data, operation and performance. This review article examines the major issues surrounding bioanode and biocathode improvement in different MFC systems, with the ultimate goal of streamlining and standardising improvement processes. © 2018 Society of Chemical Industry     

The Limits of Decentralisation in Urban Zambia

Against a background of the expansion of decentralisation across sub-Saharan Africa and widespread debates concerning the benefits associated with decentralisation, this article analyses the example of Zambia. The paper highlights the “limits” or constraints affecting the success of decentralisation. From detailed research in Ndola, attention is drawn to several issues surrounding the council’s inadequate human resource base as well as critical funding constraints which impact upon public service delivery.

By Words and Deeds: Racial Steering by Real Estate Agents in the U.S. in 2000

Although prohibited by the federal Fair Housing Act of 1968, studies in the 1980s found that racial steering by real estate agents in the U.S. was still occurring. That legislation was strengthened in 1988, but throughout the 1990s, no study examined whether these tougher strictures helped eliminate steering. In 2000, HUD and the Urban Institute conducted the national Housing Discrimination Study in 20 U.S. metropolitan areas to replicate and extend that earlier work. In this article, we report the results of this latest study, which examined three types of steering and three steering mechanisms, all at three geographic scales. The results indicate that steering of all types is occurring when Black and White homebuyers are involved. In at least 12 to 15% of the cases, agents provided gratuitous commentary that gave more information to White homebuyers and encouraged them to choose homes in areas with more White and fewer poor households. Steering is less prevalent when Hispanic and White buyers are involved. We also found no evidence that steering declined over the last decade, despite the toughening of the federal legislation in 1988. We conclude by discussing the implications for interracial wealth differentials and new fair housing enforcement initiatives.     

Analysis of through-thickness heterogeneities of microstructure and texture in nickel after accumulative roll bonding

The through-thickness heterogeneities of the microstructure and texture have been investigated in pure nickel processed by six cycles of accumulative roll bonding (ARB) with lubrication applied during each rolling pass. Strong rolling textures are found in the intermediate and center layers of the deformed sample, whereas increased fractions of the shear texture are observed near the surface. Significant differences at different depths are also revealed in the fractions of areas containing either predominantly low angle misorientations or predominantly high angle misorientations. It is found that the fractions of such areas are much more sensitive to the deformation history than the average parameters based on the measurements of the boundary spacing and fractions of high angle boundaries. For the material studied in this work, the area fraction of the low misorientation regions appears to correlate with the summed fraction of the rolling texture components. The observed microstructural and textural variations are discussed and compared with literature data, taking into account the influence of large-draught rolling and lubrication on the distribution of strain imposed during the ARB process.     

A review on carbon nanotube/polymer composites for organic solar cells

Carbon nanotubes (CNTs) have unique properties, such as their electrical conductivity, that enable them to be combined with conducting polymers to form composites for use in organic solar cells (OSCs). It is envisaged that the improved composite has a higher efficiency of green energy and will reduce the cost of these cells. The use of such alternative energy sources also drastically reduces overuse of fossil fuels and consequently limits environmental degradation. This review compares research and performance between conventional silicon solar cells and OSCs. It also discusses OSC photoexcitation and charge carrier generation with the incorporation of CNTs, physicochemical properties of the composites and other factors that affect the efficiencies of OSCs. In addition, properties of CNTs that favour their dispersion in polymer matrices as acceptors and charge carriers to the electrodes are covered. The effects of CNTs containing dopants, such as nitrogen and boron, on charge transfer are discussed. Also, the fabrication techniques of OSCs that include CNT/polymer composite processing and the methods of film deposition on the substrate are described. Finally, the case studies of OSCs containing polymers with single‐walled CNTs, double‐walled CNTs or multi‐walled CNTs are evaluated. Copyright © 2014 John Wiley & Sons, Ltd.     

Optimizing the multiple constrained resources product mix problem using genetic algorithms

The theory of constraints (TOC) is s a management philosophy for maximizing throughput. Since its introduction, many have criticized it as being inefficient when multiple constrained resources exist. The application of the five steps contained in TOC have been criticized by some researchers on the grounds that the application of five steps of TOC to the product mix decision leads to implicit or unrealizable solutions when multiple resource constraints in a plant exist. This paper views TOC as a management philosophy and a genetic algorithm-based TOC procedure is presented for solving combinatorial problems encountered in practice which cannot be solved using linear-integer programming or similar techniques. For smaller size problems, the results of the proposed procedure are compared with results of optimal methods published in the literature. The results are encouraging and therefore support the use of the proposed approach in an industrial setting.     

High strength Al–Al2O3p composites: Optimization of extrusion parameters

Composite aluminium alloys reinforced with Al₂O_3p particles have been produced by squeeze casting followed by hot extrusion and a precipitation hardening treatment. Good mechanical properties can be achieved, and in this paper we describe an optimization of the key processing parameters. The parameters investigated are the extrusion temperature, the extrusion rate and the extrusion ratio. The materials chosen are AA 2024 and AA 6061, each reinforced with 30 vol.% Al₂O₃ particles of diameter typically in the range from 0.15 to 0.3 μm. The extruded composites have been evaluated based on an investigation of their mechanical properties and microstructure, as well as on the surface quality of the extruded samples. The evaluation shows that material with good strength, though with limited ductility, can be reliably obtained using a production route of squeeze casting, followed by hot extrusion and a precipitation hardening treatment. For the extrusion step optimized processing parameters have been determined as: (i) extrusion temperature = 500 °C–560 °C; (ii) extrusion rate = 5 mm/s; (iii) extrusion ratio = 10:1.     

Vibration Reduces Metal to Metal Contact and Causes an Apparent Reduction in Friction

Experiments were conducted to determine the effect of vibration on friction. A rider, consisting of three fixed 1/3-inch diameter balls, slid along a flat steel plate under a dead weight load of 1 kg and a speed of 0.02 cm/second. The plate was vibrated by a speaker at frequencies of 20, 100, 500, and 1000 cycles per second. Acceleration, coefficient of friction, and electrical resistance of a contact were measured. For both lubricated (white oil plus oleic acid) and unlubricated conditions, apparent kinetic friction decreased rapidly after the acceleration of vibration approached and exceeded the acceleration due to gravity. Electrical resistance increased periodically with vibration. The data indicated that the vibration periodically reduced metal-to-metal contact due to reduced load. Thus, an apparent reduction of the coefficient of friction was observed. Microscopic observation of the unlubricated wear tracks on the plate showed absence of galling, brown film formation, and marked plastic deformation during sliding with vibration. The possibility of fretting-type oxide film was considered.