Catalytic oxidation of CO on mesoporous codoped ceria catalysts:Insights into correlation of physicochemical property and catalytic activity

Codoping approach is an appealing strategy to further improve the catalytic activity of Ce-based catalysts. In the present study,Mn and/or Cu doped ceria solid solutions MnxCuyCe_(1-x-y)O_2,Cu_xCe_(1-x)O_2,Mn_xCe_(1-x)O_2 and pure CeO_2 were prepared by CTAB-assisted hydrothermal method for CO oxidation.XRD, SEM, EDS, BET, Raman, H2-TPR, XPS and in situ DRIFTS techniques were carried out to study the physicochemical properties and to correlate them to the activity. The doped samples maintain the cubic fluorite structure of CeO_2 with high crystallinity and small crystallite size, forming Ce-based solid solutions. The obtained catalysts have large mesoporous structure with average pore size of 10-14 nm. The doped transition metal enhances the oxygen vacancies and improves reducibility of the solids. The synergistic interaction of Mn and Cu codoping induces mo re oxygen vacancies, pro moting the increase of surface adsorbed oxygen and the transfer of bulk oxygen of catalyst, thereby enhancing the catalytic activity for CO oxidation. Besides, the decomposition rate of the carbonate species which is derived from in situ DRIFTS for each catalyst can provide a measure to evaluate its catalytic activity of CO oxidation.     

Microstructural characteristic,outward-inward growth behavior and formation mechanism of MAO ceramic coating on the surface of ADC12 Al alloy with micro-groove

The ceramic coatings on the surface of aluminum alloy substrates with micro-grooves have been successfully fabricated in the silicate solution via micro-arc oxidation (MAO) approach. Microstructure characterization showed that the larger main discharge channels were located in the center of micro-groove, the smaller secondary discharge channels were located on both sides of main discharge channel; and a few irregular micro-pores existed in the vicinity of all discharge channels, which were mainly cause by the rapid cooling and solidification of discharge channels hindering the removal of gases produced via reaction. Moreover, the growing direction of coating in the initial stage was mainly outward-growth and resulted in the formation of inverted triangle coating structure, which was due to the sharp-angled effect. But in the final growing stage, the inward-growth behavior played a key role owing to the spark transfer. According to above results and discussion, the formation of smooth, uniform and homogeneous ceramic coating on the surface of whole trapezoidal micro-groove substrate contained four stages: anodic oxidation growth, sharp corner rapid growth, coating homogenization and groove self-filling.     

放射性物品启运前辐射监测管理的探讨

我国放射性物品启运前的辐射监测管理对一类、二类和三类放射性物品有不同的要求,本文在梳理和分析我国现行放射性物品运输的法规和标准基础上,提出了放射性物品国内运输、抵达或途径中国的放射性物品运输启运前的辐射监测管理的程序并对辐射监测报告编制内容和报送程序等相关事项做出具体的归纳总结。     

爆炸冲击波载荷下预制孔铝板的动态响应

为研究爆炸冲击波对破片穿孔后板结构的毁伤效应,使用激波管为冲击波加载设备,对不同孔形的预制孔铝板进行冲击波加载.利用三维数字图像相关(3 D-DIC)技术,分析固支预制孔方形铝板在冲击波加载条件下的动态响应,得到预制孔铝板的动态响应和变形失效过程.结合3 D-DIC结果分析孔形对靶板刚度、破坏形式、承载能力的影响.结果表明:圆形孔靶板刚度最大,圆形孔靶板的极限承载能力最大,菱形孔靶板极限承载能力最差;孔形对撕裂破坏的影响主要体现在孔的角点在靶板分布上.该实验结果对固支板结构的抗爆设计具有一定参考价值.     

北京地铁暗挖区间隧道施工过程数值模拟

采用有限元方法对北京地铁5号线磁器口站～崇文门站区间隧道主体结构进行施工全过程数值模拟，以了解隧道施工过程中应力、位移变化情况，掌握施工过程中影响洞室稳定性的关键因素，以便指导施工。介绍了数值模拟计算结果。     

黄土地下隧道开挖对周围土体变形的影响分析

以西安地铁一线工程为背景,基于黄土力学参数,运用岩土工程数值分析软件FLAC3D,进行了黄土地层地下隧道开挖对周围土体变形影响的计算机模拟分析。根据黄土场地的实际条件,建立了隧道的计算模型,利用FLAC3D程序,模拟了黄土隧道开挖过程中前期支护条件、后期加固措施等因素对隧道内部地表、拱顶、侧墙以及地上建筑物沉降的影响程度和塑性区、位移的分布规律。可为黄土地区的地下工程建设提供一定的参考。     

粘性土的弹粘塑性本构方程及其应用

从常规试验成果出发，用弹粘塑性应力－应变－时间本构方程来描述粘性土的剪胀特性和时间效应。并采用Ｐｅｒｚｙｎａ的粘塑性方程，结合关联和不相关联流动法则，建立应力－应变－时间关系，对粘性土的有效应力路径特别是塑性区的剪胀特性和应力－应变关系的时间依存性进行了数值模拟计算，得出了与试验相近的结果。通过计算结果和试验结果的对比分析，探讨了该计算模型的合理性和可行性。     

水中机器人2D 仿真的策略优化

针对现行水中机器人2D仿真1vs1比赛中的顶球算法以及策略的不足,提出一种教学建模和区域划分的方法。介绍一种新的基于区域的自适应顶球策略,即在顶球的过程中,将比赛场地分成若干区域,并在算法中采用有限自动机,不同的策略可自适应地应用于不同的区域中。实验结果证实：优化后的顶球算法配合区域划分策略能够实现更快速有效地进球,同时也提出了现有平台的优化建议。     

城市地下综合管廊建设探讨

城市地下综合管廊对于城市建设具有重要意义,可以有效缓解城市道路积水、交通拥堵;解决反复开挖路面;防止管线破裂等事故发生。但就目前而言,我国城市地下综合管廊建设发展缓慢,笔者针对这一情况,从国内管廊发展概况、设计施工难点、难以推广原因及发展前景等方面进行了探讨。