A bibliometric measure of translational science

Scientometrics - Science funders are increasingly requiring evidence of the broader impacts of even basic research. Initiatives such as NIH’s CTSA program are designed to shift the research...     

Pure CuBi2O4 Photoelectrodes with Increased Stability by Rapid Thermal Processing of Bi2O3/CuO Grown by Pulsed Laser Deposition

A new method for enhancing the charge separation and photo‐electrochemical stability of CuBi₂O₄ photoelectrodes by sequentially depositing Bi₂O₃ and CuO layers on fluorine‐doped tin oxide substrates with pulsed laser deposition (PLD), followed by rapid thermal processing (RTP), resulting in phase‐pure, highly crystalline films after 10 min at 650 °C, is reported. Conventional furnace annealing of similar films for 72 h at 500 °C do not result in phase‐pure CuBi₂O₄. The combined PLD and RTP approach allow excellent control of the Bi:Cu stoichiometry and results in photoelectrodes with superior electronic properties compared to photoelectrodes fabricated through spray pyrolysis. The low photocurrents of the CuBi₂O₄ photocathodes fabricated through PLD/RTP in this study are primarily attributed to their low specific surface area, lack of CuO impurities, and limited, slow charge transport in the undoped films. Bare (without protection layers) CuBi₂O₄ photoelectrodes made with PLD/RTP shows a photocurrent decrease of only 26% after 5 h, which represents the highest stability reported to date for this material. The PLD/RTP fabrication approach offers new possibilities of fabricating complex metal oxides photoelectrodes with a high degree of crystallinity and good electronic properties at higher temperatures than the thermal stability of glass‐based transparent conductive substrates would allow.     

Cognitive Mapping and Planning for Visual Navigation

International Journal of Computer Vision - We introduce a neural architecture for navigation in novel environments. Our proposed architecture learns to map from first-person views and plans a...     

Repurposing the Pummerer Rearrangement: Determination of Methionine Sulfoxides in Peptides

The reversible oxidation of methionine residues in proteins has emerged as a biologically important post-translational modification. However, detection and quantitation of methionine sulfoxide in proteins is difficult. Our aim is to develop a method for specifically derivatizing methionine sulfoxide residues. We report a Pummerer rearrangement of methionine sulfoxide treated sequentially with trimethylsilyl chloride and then 2-mercaptoimidazole or pyridine-2-thiol to produce a dithioacetal product. This derivative is stable to standard mass spectrometry conditions, and its formation identified oxidized methionine residues. The scope and requirements of dithioacetal formation are reported for methionine sulfoxide and model substrates. The reaction intermediates have been investigated by computational techniques and by ¹³C NMR spectroscopy. These provide evidence for an α-chlorinated intermediate. The derivatization allows for detection and quantitation of methionine sulfoxide in proteins by mass spectrometry and potentially by immunochemical methods.     

Exploring Social Norms as a Group‐Level Phenomenon: Do Political Participation Norms Exist and Influence Political Participation on College Campuses?

This research explores the relationship between campus political norms and student political participation. This study conceptualizes norms as a group‐level construct by collecting data at several universities (k = 32 universities, n = 1,389 students) where norms vary without campaign intervention. Multilevel modeling reveals that perceptions of political norms converge within universities. Further, frequency of political communication at the group‐ and individual‐level explains increases in normative perceptions. This increase is meaningful because norms at the group level were predictive of political behaviors at the individual level. This research documents the existence of political norms beyond the individual level of analysis and highlights the important role of political norms, political communication, and social context in understanding political participation.     

THE TWO-MESSAGE PROBLEM IN CIPHER TEXT AUTOKEY. PART II

This is Part II of a two-part paper on the problem of the title. In this part the analysis of the two-message problem started in Part I is completed. In addition a brief discussion is given of a computer-assisted solution. A list of twelve two-message problems involving several types of conditions is attached for the benefit of the reader.     

APPLICATIONS OF THE DRAZIN INVERSE TO THE HILL CRYPTOGRAPHIC SYSTEM. PART III.

In this part it is shown how the scalar unit coefficient a appearing in the W key formula (see Part I) can be replaced by an invertible matrix coefficient Γ. (A similar discussion with respect to the V key will appear In Part IV.) Various examples illustrate in detail the different procedures involved. Some examples in the encipherment and decipherment calculations are left as problems for the reader. The Appendix contains a proof of the main theorem.