Growth of ZnSe∶Mn Nanocrystals from Vapour Phase

ZnSe∶Mn nanocrystals were grown by chemical vapour transport method using the matrix of SiO2 aerogels. The cubic structure of the nanocrystals was confirmed by powder X-ray diffraction (XRD) and electron diffraction (ED) studies. The size of the crystals was observed using transmission electron microscope (TEM). The oxidation state of Mn in ZnSe nanocrystal was found using electron spin resonance (ESR) spectrum. The room temperature luminescence measurements show the peaks corresponding to both bandgap of the material and Mn in ZnSe.     

Metallo-organic deposition of tungsten oxide films from alkylammonium tungstate solutions

This paper describes a simple and inexpensive metallo-organic deposition (MOD) process for forming electrochromic tungsten oxide (WO₃) films on glass. The thin films of WO₃ were made by air firing (500–700°C) films from xylene/2-propanol solutions of bis-(di-n-octylammonium) tetratungstate, [(n-C₈H₁₇)₂NH₂]₂[W₄O₁₃]. The process coats glass with undoped films ranging in colour from faint yellow to dark brown, and can be used to make gradients of these colours. The colour is determined by the firing parameters and results from residual carbon and tungsten suboxides in the film due to incomplete firing. Increased firing temperatures or longer firing times removes the carbon and produces films with higher crystallinity. Electrochemical doping with acid (H⁺) switches the colour gradient films to a uniformly blue colour.     

Synthesis and characterization of liquid crystalline polymers containing aromatic ester mesogen and a nonmesogenic ferrocene unit in the spacer

A new series of liquid crystalline polymers containing aromatic triad ester mesogen and 1,1′‐disubstituted ferrocene as a nonmesogenic unit along with polymethylene spacer was synthesized. The polymer was synthesized by a room temperature polycondensation reaction between bis(4‐chloroformyl phenyloxy alkyl ferrocene dicarboxylate) and quinol. The alkyl groups have been varied by an even number of methylene groups with a range from two to ten groups. All the polymers were found to possess liquid crystalline properties. The identification of the mesophase is more transparent with an increase in the spacer. The thermal characteristics were studied using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results reveal that the thermal stability of the polymers was decreased with increasing spacer length. The T_g, T_m, and T_i of the polymers decreased with increasing methylene groups. The incorporation of the ferrocene moiety also has a considerable effect on the glass transition temperature. The char yield of the polymer decreases with an increasing methylene chain length. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3494–3501, 2002     

A tungsten-trioxide/prussian blue complementary electrochromic cell with a polymer electrolyte

Optically variable windows (smart windows), which control the transmission of light into buildings and vehicles, are of interest both for the control of solar heat load and for privacy applications. Such windows are likely to utilize electrochromic technology to achieve optical control. An electrochromic device consisting of a cathodically colouring tungsten trioxide (WO₃) film, an anodically colouring Prussian blue (PB) film, and a polymer electrolyte was made. The polymer electrolyte was prepared from polyvinyl alcohol doped with H₃PO₄ and KH₂PO₄ to accommodate the conduction of both H⁺ and K⁺ ions. The electrochromic WO₃ and PB films functioned in a complementary way such that the device was coloured or bleached by the application of –0.5 V or +0.5 V (WO₃ films vs PB film), respectively. The spectral characteristics of the coloured device confirmed the complementary colouration of WO₃ and PB in the device.     

Design of observer based nonlinear model predictive controller for a continuous stirred tank reactor

Model predictive control (MPC) schemes are now widely used in process industries for the control of key unit operations. Linear model predictive control (LMPC) schemes which make use of linear dynamic model for prediction, limit their applicability to a narrow range of operation (or) to systems which exhibit mildly nonlinear dynamics.

In this paper, a nonlinear observer based model predictive controller (NMPC) for nonlinear system has been proposed. An approach to design NMPC based on fuzzy Kalman filter (FKF) and augmented state fuzzy Kalman filter (ASFKF) has been presented. The efficacy of the proposed NMPC schemes have been demonstrated by conducting simulation studies on the continuous stirred tank reactor (CSTR). The analysis of the extensive dynamic simulation studies revealed that, the NMPC schemes formulated produces satisfactory performance for both servo and regulatory problems. Simulation results also include an inferential control case, where the reactor concentration is not measured but estimated from temperature measurement and used in the NMPC based on FKF and ASFKF formulations.     

Certain Investigation on Healthcare Monitoring for Enhancing Data Transmission in WSN

International Journal of Wireless Information Networks - Wireless Sensor Networks are often to perform autonomous sensing and controlling the real world objects through the sensor nodes across the...     

Network Lifetime Enhancement of Wireless Sensor Networks Using EFRP Protocol

This paper presents a novel transceiver architecture for in-band full duplex radio. A transceiver for full duplex radio requires a self-interference (SI) canceler to remove the SI occurring from the transmitter to the receiver, and a full duplex transceiver generally has two SI cancelers: one at the analog RF stage and the other at the baseband stage. The output from the SI canceler at the RF stage includes much residual SI, and it decreases the number of bits allocated to the analog baseband signal at the analog-to-digital converter. A 1-tap analog baseband SI canceler that uses a replica signal including only the direct path component of the residual SI has been presented for preventing degradation. However, the architecture cannot remove the SI well due to the high Ricial K-factor. To address the problem, the presented architecture has an SI canceler at the analog baseband stage, and this canceler employs a replica signal that is output from a digital-to-analog converter. Because the replica signal is generated in the digital domain, the architecture can generate a multipath replica signal, and improved performance can be expected. Numerical and theoretical analyses are shown to validate the effectiveness of the presented architecture.

     

Detection of Malicious Profiles and Protecting Users in Online Social Networks

Wireless Personal Communications - Everyone today actively uses online social networks to get in touch with their friends, for career opportunities, and business also. Some of the most popular...     

An automatic query expansion based on hybrid CMO-COOT algorithm for optimized information retrieval

The World Wide Web(WWW) comprises a wide range of information, and it is mainly operated on the principles of keyword matching which often reduces accurate information retrieval. Automatic query expansion is one of the primary methods for information retrieval, and it handles the vocabulary mismatch problem often faced by the information retrieval systems to retrieve an appropriate document using the keywords. This paper proposed a novel approach of hybrid COOT-based Cat and Mouse Optimization (CMO) algorithm named as hybrid COOT-CMO for the appropriate selection of optimal candidate terms in the automatic query expansion process. To improve the accuracy of the Cat and Mouse Optimization (CMO) algorithm, the parameters are tuned with the help of the Coot algorithm. The best suitable expanded query is identified from the available expanded query sets also known as candidate query pools. All feasible combinations in this candidate query pool should be obtained from the top retrieved documents. Benchmark datasets such as the GOV2 Test Collection, the Cranfield Collections, and the NTCIR Test Collection are utilized to assess the performance of the proposed hybrid COOT-CMO method for automatic query expansion. This proposed method surpasses the existing state-of-the-art techniques using many performance measures such as F-score, precision, and mean average precision (MAP).