Simulation of a System of Product Knowledge Based on Catalog-Assisted Design

Conceptual models for catalog-assisted design are developed to improve semantic modeling in the automation of design problems and the extraction of knowledge from engineering documents. The conceptual models are presented graphically.     

10MW级深冷液化空气储能发电系统自动启动控制方法研究

以10 MW级深冷液化空气储能发电系统为研究对象,简要介绍了技术原理、系统构成、主要设备及工艺流程,并从自动控制视角,分别设计了储、释能阶段的启动方法。基于该自动启动方法,可完成储能阶段空气净化及压缩、空气液化、储热和蓄冷子系统的联合运行以及释能阶段储热、蓄冷和膨胀发电子系统的联合运行,实现了储能阶段自动达到额定出液量及释能阶段自动满足额定发电量的需求,提高了能量型机械储能系统对电网负荷变化的响应速度。     

Lab scale optimization of various factors for photocatalytic hydrogen generation over low cost Cu0.02Ti0.98O2-δ photocatalyst under UV/Visible irradiation and sunlight

We have demonstrated earlier that maximum H₂ generated @ 1.167 l/h/m² over Cu_0.02Ti_0.98O_2-δ photocatalyst with apparent quantum efficiency, AQE of 7.5% and solar fuel efficiency, SFE of 3.9% under sunlight. With an aim to scale-up the solar photocatalytic hydrogen process to pilot plant, optimization studies at lab scale as well as in upscaled photoreactors were performed over Cu_0.02Ti_0.98O_2-δ, photocatalyst under UV/visible and sunlight. Cu_0.02Ti_0.98O_2-δ was synthesized by facile sol-gel route and characterized by relevant techniques. Several operational parameters were investigated in order to finalize the conditions which are most favourable for photocatalytic hydrogen yield. Factors such as photocatalyst loadings, v/v concentration of sacrificial reagent, replacement of methanol by industrial waste glycerol, role of different configuration of light source with reactor, effect of stirring during the photocatalytic reaction, effect of fluctuations of solar flux at hourly basis, illumination area on hydrogen yield were studied. Contribution of each factor in determining the hydrogen yield was quantified. Relative standard deviation in hydrogen yield as a function of each factor was estimated. Our findings suggest that in addition to catalyst loadings and sacrificial reagent, improved dispersion of photocatalyst obtained by stirring the reaction mixture in horizontal geometry resulted in enhanced H₂ yield. Hydrogen yield obtained at lab scale can be appropriately extrapolated with respect to illumination area instead of weight of photocatalyst. A relative standard deviation (RSD) of ± 3.82% and ± 4.53% in H₂ yield was calculated for sunny and cloudy days in time zone of 10.30–16.30 h IST. Deviation of H₂ yield was more on cloudy days and beyond 16:30 h. These studies have provided a daily window of 11:00–15:00 h to be utilized throughout the year for a commercial scaled up process, prohibiting the illumination during less productive hours of the day for shaping the improved economics of solar hydrogen generation. Our results obtained at lab scale would be useful to perform sunlight driven scaled –up photocatalytic process using low cost visible light efficient photocatalyst, Cu_0.02Ti_0.98O_2-δ.     

Catalytic properties of dispersed iron oxides Fe2O3/MO2 (M = Zr,Ce, Ti and Si) for sulfuric acid decomposition reaction: Role of support

Supported iron oxides have been established as an important class of catalyst for high temperature sulfuric acid decomposition. With an objective to elucidate the role of support in modifying the overall catalytic properties of dispersed iron oxide catalysts, a series of supported iron oxide based catalysts, Fe₂O₃ (15 wt%)/MO₂ (M = Zr, Ce, Ti and Si), synthesized by adsorption-equilibrium method, is investigated for sulfuric acid decomposition reaction. The structure of dispersed iron oxide phases largely depended on the nature of the support oxide as revealed by the XRD and Mössbauer studies. α-Fe₂O₃ is found to be present as a major phase on ZrO₂ and CeO₂ support while ε-Fe₂O₃ was the major phase on silica supported iron oxide. On the other hand, presence of mixed oxide Fe₂TiO₅ was revealed over TiO₂ support. Strong dispersed metal oxide-support interactions inhibited the total reduction of the dispersed phase on SiO₂ and TiO₂ as compared to complete reduction of dispersed iron oxide on CeO₂ and ZrO₂ supports during temperature programmed reduction upto 1000 °C. The order of catalytic activity at a temperature of ～750 °C is observed as Fe₂O₃/SiO₂ > Fe₂TiO₅/TiO₂ > Fe₂O₃/ZrO₂ > Fe₂O₃/CeO₂, while at higher temperatures of ～900 °C the SO₂ yield is found to be comparable for all catalysts. A relationship between the rate of sulfate decomposition and catalytic activity is established through detailed TG-DTA investigations of sulfated catalyst and support. Considerable influence of the support oxide on the composition, structure, redox properties, morphology and catalytic activities of the active iron oxide dispersed phase has been observed. Thus, the support oxides operate as a critical component in the complex supported metal oxide catalysts and these findings might influence the design and development of future high temperature sulfuric acid decomposition catalysts.     

Maximum temperature rise of fire plume ejected out of the compartment window with a horizontal eave

This study focuses on the maximum temperature rise of fire plume ejected out of the compartment window with a horizontal eave. Based on the symmetry of ejected plume and pictures recorded by the cameras in the study, the shape of ejected thermal plume out of the window under the eave is suggest as an isosceles trapezoid, and the ejected thermal plume rising at the edge of the eave is assumed to be a rectangular fire source. The dimensions of the rectangular fire source are theoretically deduced for compartment fire process of different window geometry, width of eave, and heat release rate, according to the conservation of plume mass. The previous predictive model for plume temperature proposed by Quintiere is popularized to the ejected flame above an eave by including the dimensions of the rectangular fire source as well as the width of eave. The results would provide theoretical guidance to the application of fireproof eave in high-rise building for fire protection designs.     

一种弹性足式机器人腿部结构设计与分析

针对足式机器人在实现奔跑、跳跃等极限运动时,腿部会受到地面较大反向冲击力的问题,使用仿生学方法以猫科动物腿部骨骼肌系统为仿生对象,通过引入变刚度弹性杆件对闭链连杆机构进行优化设计,设计一种结构简单、能够有效储存地面反向冲击力并将其转化为运动时动能的足式机器人腿部机构;建立数学模型,对变刚度弹性元件进行定量分析,并采用矢量回路法对连杆机构进行运动学分析;建立优化前后两种单腿机构的虚拟样机,使用MATLAB软件设计控制系统,并应用ADAMS对虚拟样机进行行走、跳跃仿真,对优化前后两种腿部机构进行对比实验;在此基础上搭建实物样机,并进行实验验证。实验结果表明:所提出的足式机器人腿部结构具备可实现性,能够将来自地面的冲击力转化为运动的动能,提升足式机器人的跳跃高度。     

Hydroisomerization of n-hexadecane over Brønsted acid site tailored Pt/ZSM-12

Hydroisomerization of n-hexadecane is performed over ZSM-12 framework having tailored Brønsted acidity to investigate the effect in terms of product selectivity and yield. For this purpose, pure phase of ZSM-12 (bulk molar ratio Si/Al ~ 60) has been synthesized using TEABr as a structure directing agent. The framework Brønsted acidity is tailored with group II elements (M) viz. Ca, Ba and Mg, by means of ion-exchange method. The samples so prepared have been characterized for phase purity, textural parameters, morphology by employing powder X-ray diffraction, nitrogen adsorption–desorption isotherm measurement at 77 K, and scanning electron microscopy technique, respectively. Similarly, % metal exchange is estimated using inductively coupled plasma technique. The quantification of Brønsted acidity for H⁺–M⁺⁺–ZSM-12 samples has been estimated by means of ammonia temperature programmed desorption (NH₃-TPD) and Fourier transform infrared spectroscopy of ammonia (NH₃-FTIR). The well characterized H⁺–M⁺⁺–ZSM-12 samples were loaded with Platinum (Pt, 0.5 wt%) and subjected to hydroisomerization of n-hexadecane using an up-flow fixed bed reactor to verify the effect of process parameters like temperature and WHSV. Pt/H⁺–Ba²⁺–ZSM-12 with tailored Brønsted acidity in the range of about 25 % demonstrated the optimum performance among all the catalysts with an increased isomer selectivity and yield (89.2 and 80.3 %, respectively) by about 4 wt% at a conversion level of about 90 % compared to Pt/H⁺–ZSM-12 framework at 568 K. Such enhancement in isomer selectivity and yield is found to be significant from commercial application point of view. Based on the obtained trend, the potential benefits of implementation of Pt/H⁺–Ba²⁺–ZSM-12 (bulk molar ratio Si/Al ~ 60) framework for cold flow property improvement of ‘bio-ATF’ have been envisaged.     

Comparison of the Revised Air Quality Index with the PSI and AQI indices

Air pollution indices are commonly used to indicate the level of severity of air pollution to the public. The Pollution Standards Index (PSI) was initially established in response to a dramatic increase in the number of people suffering respiratory irritation due to the deteriorating air quality. The PSI was subsequently revised and implemented by the USEPA in 1999, and became known as the Air Quality Index (AQI) that includes data relating to particle suspension, PM2.5, and a selective options of either 8-hour or 1-hour ozone concentration during increased O3 periods. Yet, the costs of launching a network of PM2.5 monitoring stations are prohibitively high for many countries to implement the AQI from the PSI system in the foreseeable future. Therefore, the purpose of this research is to discuss the optimal method of assessing air quality using the latest developed Revised AQI (RAQI), a system that serves as an alternative to the PSI and AQI systems. The feasibility, effectiveness, and the differences between RAQI, AQI, and PSI in their applications to several air pollution conditions are also studied in this research. The results show that southern Taiwan's suspended particulates have significantly greater impact on PM2.5/PM10 ratios than in central and northern metropolitan areas, and that the ratios are higher in Taiwan as a whole compared to many other countries. We also found that the RAQI shows more significant results compared to the PSI and AQI as it has a wider coverage of the range of pollutant concentration levels.     

Microstructure and Mechanical Property Correlation of Mg-Si Alloys

Silicon - The present work aims at understanding the microstructure and mechanical property correlation of hypo (Mg-0.5, 0.7, 1.15 wt% Si) and hyper (Mg-2, 4, 6, 8 and 10 wt% Si) eutectic binary...     

Characteristics of hemicelluloses obtained from sweet sorghum based on successive extractions

Hemicelluloses were successively extracted from sweet sorghum by hot water, dioxane, DMSO, and different concentrations of NaOH between 0.5% and 6.0%. The yields of the seven fractions together accounted for 88.6% of the original hemicelluloses. The obtained hemicellulosic subfractions were comprehensively investigated by both destructive methods such as alkaline nitrobenzene oxidation and acid hydrolysis and nondestructive techniques such as gel permeation chromatography, Fourier‐transform infrared, ¹³C‐nuclear magnetic resonance, and 2D‐heteronuclear singular quantum correlation. Sugar composition studies showed that the water‐soluble polysaccharides consisted mainly of glucose, while xylose, arabinose, and glucuronic acid were the major sugars in other hemicellulosic fractions. It was found that the hemicelluloses from sweet sorghum were l‐ arabino‐(4‐O‐methyl‐d‐ glucurono)‐xylans. Comparison with the hemicellulosic fractions dissolved by the alkali treatment, the hemicellulosic fraction extracted by DMSO had lower molecular weight. In addition, it was also found that the hemicelluloses prepared by dioxane and DMSO were more branched since that they had higher nonxylose/xylose ratios than those extracted by the alkali treatment, which were more linear and contained higher amounts xylose. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42790.