Photoactive Polyesters Containing o-Nitro Benzyl Ester Functionality for Photodeactivatable Adhesion

The fabrication of modern microelectronic silicon devices mechanically challenges these thin silicon substrates during manufacturing operations. Melt and solution polyesterification enabled the synthesis of polyesters containing photoreactive o-nitro benzyl ester units for use as a potential photocleavable adhesive. Melt transesterification provided a solvent-free method for synthesis of 2-nitro-p-xylylene glycol (NXG)-containing polyesters of controlled molecular weights. ¹H NMR spectroscopy confirmed the chemical composition of the photoactive polyesters. Size exclusion chromatography (SEC) determined the number-average molecular weights (M_n) of the polyesters synthesized in the range of 6000 to 12000 g/mol. ¹H NMR spectroscopy confirmed increasing levels of photocleavage of the o-nitro benzyl ester functionality with increasing exposure to broad wavelength UV irradiation, and exposure levels ranged from 0–187 J/cm² UVA. Photocleaveage of approximately 90% of the o-nitro benzyl ester (ONB) units within the backbone of the polymer occurred at maximum dosage. Wedge fracture testing revealed approximately a two-fold decrease in fracture energy upon UV irradiation, suggesting that these structural adhesives offer potential for commercial “flip bonding” applications.     

A machine learning approach for imputation and anomaly detection in IoT environment

The problem of anomaly and attack detection in IoT environment is one of the prime challenges in the domain of internet of things that requires an immediate concern. For example, anomalies and attacks in IoT environment such as scan, malicious operation, denial of service, spying, data type probing, wrong setup, malicious control can lead to failure of an IoT system. Datasets generated in an IoT environment usually have missing values. The presence of missing values makes the classifier unsuitable for classification task. This article introduces (a) a novel imputation technique for imputation of missing data values (b) a classifier which is based on feature transformation to perform classification (c) imputation measure for similarity computation between any two instances that can also be used as similarity measure. The performance of proposed classifier is studied by using imputed datasets obtained through applying Kmeans, F-Kmeans and proposed imputation methods. Experiments are also conducted by applying existing and proposed classifiers on the imputed dataset obtained using proposed imputation technique. For experimental study in this article, we have used an open source dataset named distributed smart space orchestration system publicly available from Kaggle. Experiment results obtained are also validated using Wilcoxon non-parametric statistical test. It is proved that the performance of proposed approach is better when compared to existing classifiers when the imputation process is performed using F-Kmeans and K-Means imputation techniques. It is also observed that accuracies for attack classes scan, malicious operation, denial of service, spying, data type probing, wrong setup are 100% while it is 99% for malicious control attack class when the proposed imputation and classification technique are applied.     

SRIHASS - a similarity measure for discovery of hidden time profiled temporal associations

Mining and visualization of time profiled temporal associations is an important research problem that is not addressed in a wider perspective and is understudied. Visual analysis of time profiled temporal associations helps to better understand hidden seasonal, emerging, and diminishing temporal trends. The pioneering work by Yoo and Shashi Sekhar termed as SPAMINE applied the Euclidean distance measure. Following their research, subsequent studies were only restricted to the use of Euclidean distance. However, with an increase in the number of time slots, the dimensionality of a prevalence time sequence of temporal association, also increases, and this high dimensionality makes the Euclidean distance not suitable for the higher dimensions. Some of our previous studies, proposed Gaussian based dissimilarity measures and prevalence estimation approaches to discover time profiled temporal associations. To the best of our knowledge, there is no research that has addressed a similarity measure which is based on the standard score and normal probability to find the similarity between temporal patterns in z-space and retains monotonicity. Our research is pioneering work in this direction. This research has three contributions. First, we introduce a novel similarity (or dissimilarity) measure, SRIHASS to find the similarity between temporal associations. The basic idea behind the design of dissimilarity measure is to transform support values of temporal associations onto z-space and then obtain probability sequences of temporal associations using a normal distribution chart. The dissimilarity measure uses these probability sequences to estimate the similarity between patterns in z-space. The second contribution is the prevalence bound estimation approach. Finally, we give the algorithm for time profiled associating mining called Z-SPAMINE that is primarily inspired from SPAMINE. Experiment results prove that our approach, Z-SPAMINE is computationally more efficient and scalable compared to existing approaches such as Naïve, Sequential and SPAMINE that applies the Euclidean distance.     

ASTRA - A Novel interest measure for unearthing latent temporal associations and trends through extending basic gaussian membership function

Time profiled association mining is one of the important and challenging research problems that is relatively less addressed. Time profiled association mining has two main challenges that must be addressed. These include addressing i) dissimilarity measure that also holds monotonicity property and can efficiently prune itemset associations ii) approaches for estimating prevalence values of itemset associations over time. The pioneering research that addressed time profiled association mining is by J.S. Yoo using Euclidean distance. It is widely known fact that this distance measure suffers from high dimensionality. Given a time stamped transaction database, time profiled association mining refers to the discovery of underlying and hidden time profiled itemset associations whose true prevalence variations are similar as the user query sequence under subset constraints that include i) allowable dissimilarity value ii) a reference query time sequence iii) dissimilarity function that can find degree of similarity between a temporal itemset and reference. In this paper, we propose a novel dissimilarity measure whose design is a function of product based gaussian membership function through extending the similarity function proposed in our earlier research (G-Spamine). Our approach, MASTER (Mining of Similar Temporal Associations) which is primarily inspired from SPAMINE uses the dissimilarity measure proposed in this paper and support bound estimation approach proposed in our earlier research. Expression for computation of distance bounds of temporal patterns are designed considering the proposed measure and support estimation approach. Experiments are performed by considering naïve, sequential, Spamine and G-Spamine approaches under various test case considerations that study the scalability and computational performance of the proposed approach. Experimental results prove the scalability and efficiency of the proposed approach. The correctness and completeness of proposed approach is also proved analytically.