Amelioration in physicochemical properties and single cell performance of sulfonated poly(ether ether ketone) block copolymer composite membrane using sulfonated carbon nanotubes for intermediate humidity fuel cells

A composite membrane composed of a sulfonated diblock copolymer (SDBC) based on poly(ether ether ketone) blocks copolymerized with partially fluorinated poly(arylene ether sulfone) and sulfonated carbon nanotubes (SCNTs) was fabricated by simple solution casting. Addition of the SCNT filler enhanced the water absorption and proton conductivity of membranes because of the increased per‐cluster volume of sulfonic acid groups, at the same time reinforced the membranes' thermal and mechanical properties. The SDBC/SCNT‐1.5 membrane exhibited the most improved physicochemical properties among all materials. It obtained a proton conductivity of 10.1 mS/cm at 120°C under 20% relative humidity (RH) which was 2.6 times more improved than the pristine membrane (3.9 mS/cm). Moreover, the single cell performance of the SDBC/SCNT‐1.5 membrane at 60°C and 60% RH at ambient pressure exhibited a peak power density of 171 mW/cm² at a load current density of 378 mA/cm², while the pristine membrane exhibited 119 mW/cm² at a load current density of 294 mA/cm². Overall, the composite membrane exhibited very promising characteristics to be used as polymer electrolyte membrane in fuel cells operated at intermediate RH.     

Chlorella vulgaris Attenuates Dermatophagoides Farinae-Induced Atopic Dermatitis-Like Symptoms in NC/Nga Mice

Atopic dermatitis (AD) is a chronic and inflammatory skin disease that can place a significant burden on quality of life for patients. AD most frequently appears under the age of six and although its prevalence is increasing worldwide, therapeutic treatment options are limited. Chlorella vulgaris (CV) is a species of the freshwater green algae genus chlorella, and has been reported to modulate allergy-inducible factors when ingested. Here, we examined the effect of CV supplementation on AD-like symptoms in NC/Nga mice. CV was orally administrated for six weeks while AD-like symptoms were induced via topical application of Dermatophagoides farinae extract (DFE). CV treatment reduced dermatitis scores, epidermal thickness, and skin hydration. Histological analysis also revealed that CV treatment reduced DFE-induced eosinophil and mast cell infiltration into the skin, while analysis of serum chemokine levels indicated that CV treatment downregulated thymus- and activation-regulated chemokine (TARC) and macrophage-derived chemokine (MDC) levels. In addition, CV treatment downregulated mRNA expression levels of IL-4 and IFN-γ. Taken together, these results suggest that CV extract may have potential as a nutraceutical ingredient for the prevention of AD.     

A traffic control system for IEEE 802.11 networks based on available bandwidth estimation

To support Quality of service (QoS)‐sensitive applications like real‐time video streaming in IEEE 802.11 networks, a MAC layer extension for QoS, IEEE 802.11e, has been recently ratified as a standard. This MAC layer solution, however, addresses only the issue of prioritized access to the wireless medium and leaves such issues as QoS guarantee and admission control to the traffic control systems at the higher layers. This paper presents an IP‐layer traffic control system for IEEE 802.11 networks based on available bandwidth estimation. We build an analytical model for estimating the available bandwidth by extending an existing throughput computation model, and implement a traffic control system that provides QoS guarantees and admission control by utilizing the estimated available bandwidth information. We have conducted extensive performance evaluation of the proposed scheme via both simulations and measurements in the real test‐bed. The experiment results show that our estimation model and traffic control system work accurately and effectively in various network load conditions without IEEE 802.11e. The presence of IEEE 802.11e will allow even more efficient QoS provision, as the proposed scheme and the MAC layer QoS support will complement each other. Copyright © 2006 John Wiley & Sons, Ltd.     

Density‐adaptive network reprogramming protocol for wireless sensor networks

Network reprogramming is a process used to update program codes of sensor nodes that are already deployed. To deal with potentially unstable link conditions of wireless sensor networks, the epidemic approach based on 3‐way advertise‐request‐data handshaking is preferred for network reprogramming. Existing epidemic protocols, however, require a long completion period and high traffic overhead in high‐density networks, mainly due to the hidden terminal problem. In this paper, we address this problem by dynamically adjusting the frequency of advertisement messages in terms of the density of sensor nodes, which is the number of sensor nodes in a certain area. We compare the performance of the proposed scheme, called DANP (Density‐Adaptive Network Reprogramming Protocol), with a well‐known epidemic protocol, Deluge. Simulations indicate that, in the grid topologies, DANP outperforms Deluge by about 30% in terms of the completion time and about 50% in terms of the traffic overhead. Significant performance gain is observed in random topologies as well. The performance of DANP is further confirmed via measurements in an experimental test bed. Copyright © 2009 John Wiley & Sons, Ltd.     

Validating Real-Time Constraints in Heterogeneous Multiprocessor and Distributed Systems

A heterogeneous system or distributed system typically contains different types of processors. Some jobs can execute on certain types of processors but not other types. Processors of different types may have different speeds. We present several worst-case upper bounds and efficient algorithms for determining the completion times of independent jobs that have arbitrary timing constraints and variable execution times and are scheduled on available processors dynamically in a priority-driven manner. Bounds and algorithms take into account the effects of nonmigratability, nonpreemptability and different levels of migratability.     

Persimmon peel extract attenuates PDGF-BB-induced human aortic smooth muscle cell migration and invasion through inhibition of c-Src activity

The unregulated migration and invasion of human aortic smooth muscle cells (HASMCs) into the intima is a crucial step in the development of atherosclerosis. Recently, the oriental persimmon extract (Diospyros kaki Thunb. cv. Fuyu) has been investigated for its anti-atherogenic properties, but the molecular mechanisms involved remain unclear. We investigated the inhibitory effects of persimmon peel and flesh extract on the platelet-derived growth factor (PDGF) BB-induced MMP-1 expression using Western blot, and abnormal migration and invasion of HASMCs using a modified Boyden chamber assay and a wound healing assay. We also evaluated the inhibitory effects of persimmon peel extract on aortic vessel thickening using a rat aortic sprouting assay. Persimmon peel (PPE), but not flesh extract (PFE), inhibited PDGF-BB-induced MMP-1 expression, cell migration and invasion in HASMCs, while suppressing the rat aortic sprouting. Western blot and in vitro kinase assay data demonstrated that PPE inhibited Src kinase activity and subsequently attenuated PDGF-BB-induced phosphorylation of MAPK and Akt signalling pathways. Taken together, our results indicate that persimmon peel might possess a potential anti-atherogenic effect through attenuation of ASMCs migration and invasion and aortic sprouting by direct inhibition of the c-Src kinase activity.     

Dynamic Frame Dropping for Bandwidth Control in MPEG Streaming System

In a network environment where the available bandwidth changes dynamically, it is desirable for a streaming system to control the media quality in an adaptive way according to the dynamics of underlying network resource. This paper presents the implementation of a real-time MPEG filtering system which uses the concept of dynamic frame-drop. The filtering system drops video frames in a controlled way and reconstructs a valid MPEG system stream in real-time. The system consists of a sequence of filtering modules and each module is carefully designed to maintain the synchronization characteristics of real-time streaming. A special effort is given to the correct implementation of video and audio synchronization after frame-drop. The experiments show that the implemented system produces a valid MPEG system stream after filtering as well as the media bandwidth of a filtered stream is dynamically controlled by a given frame-drop policy.     

Improving TCP fairness and performance with bulk transmission control over lossy wireless channel

The traditional windows-based TCP congestion control mechanism produces throughput bias against flows with longer packet roundtrip times; the flow with a short packet roundtrip time preoccupies the shared network bandwidth to a greater extent than others. Moreover, the blind window reduction that occurs whenever packets are lost decreases the network utilization severely, especially in networks with high packet losses. This paper proposes a sender-based TCP congestion control, called TCP-BT. The scheme estimates the network bandwidth depending on the transmission behavior of applications, and adjusts the congestion window by considering both the estimated network bandwidth and the packet roundtrip time to improve fairness as well as transmission performance. The scheme has been implemented in the Linux platform and compared with various TCP variants in real environments. The experimental results show that the proposed scheme improves transmission performance, especially in networks with congestion and/or high packet loss rates. Experiments in real commercial wireless networks have also been conducted to support the practical use of the proposed mechanism.     

Effect of functionalized SiO2 toward proton conductivity of composite membranes for PEMFC application

Organic‐inorganic composite membranes were prepared by introducing silicon dioxide (SiO₂) or functionalized SiO₂ (?‐SiO₂) with various particle sizes into sulfonated poly (arylene ether ketone) (SPAEK) containing pendant groups, and the membrane was manufactured via directly casting which is a cost‐competitive method. The structure and morphology of the composite membranes were confirmed by ¹H NMR, FT‐IR, XRD, and FE‐SEM analysis which demonstrated that inorganic nanofillers were successfully introduced. The FE‐SEM surface images showed that SiO₂ and ?‐SiO₂ particles were very well dispersed within the membrane sheets. The water uptake and swelling ratio of the composite membranes including SiO₂ or ?‐SiO₂ almost did not change when compared with the pristine SPAEK membrane. All fabricated membranes demonstrated good thermal/dimensional stabilities, robust mechanical behavior, and excellent proton conductivity. In particular, the SPAEK/?‐SiO₂ composite membranes exhibited improved ionic conductivity compared with the pristine membrane at 70% relative humidity (RH) due to hydrogen bonding between ─SO₃H groups of functionalized inorganic filler and polymer backbone. Furthermore, the maximum power density of SPAEK/?‐SiO₂ reached as high as 273.11 mW cm^?2 at 60°C under 70% RH. Therefore, the composite membranes with ?‐SiO₂ testify to great potential as polymer electrolyte membrane.