Heat transfer enhancement of concentrated solar absorber using hollow cylindrical fins filled with phase change material

A concentrated solar absorber with finned phase change materials was experimentally studied using a Scheffler type parabolic dish concentrator. The absorber's inner surface was fixed with hollow cylindrical containers filled with phase change material (PCM) for heat transfer augmentation. The absorber's selected PCM was acetanilide (Melting point of 116 °C)—the cylindrical capsules protruding into the fluid side to create turbulence and mixing and acting as fins. The absorber surface temperature was observed to be about 130–150 °C during the outdoor tests while passing fluid through the absorber. The fluid flow rate varied from 60 to 100 kg/h during the outdoor experiments. The peak energy and exergy efficiency of parabolic dish collector (PDC) at the fluid flow rate of 80 kg/h with PCM integrated solar absorber was found to be about 67.88% and 6.96%, respectively. The integration of cylindrical PCM containers resulted in more heat transfer augmentation in the solar absorbers. The optimized solar absorber could be suitable for various applications like steam generation, biomass gasification, space heating, and hydrogen generation.     

Conformation Analysis of GalNAc‐Appended Sugar Amino Acid Foldamers as Glycopeptide Mimics

Sugar amino acid (SAA)‐based foldamers with well‐defined secondary structures were appended with N‐acetylgalactosamine (GalNAc) sugars to access sequence‐defined, multidentate glycoconjugates with full control over number, spacing and position. Conformation analysis of these glycopeptides by extensive NMR spectroscopic studies revealed that the appended GalNAc units had a profound influence on the native conformational behaviour of the SAA foldamers. Whereas the 2,5‐cis glycoconjugate showed a helical structure in water, comprising of two consecutive 16‐membered hydrogen bonds, its 2,5‐trans congener displayed an unprecedented 16/10‐mixed turn structure not seen before in any glycopeptide foldamer.     

An index to characterize gas-solid and solid-solid mixing from average volume fraction fields

A mixing index based on solid volume fraction fields is developed for gas-solid flows. Conventional mixing indices are based on particle realizations of granular mixing and are applicable to experimental data or discrete element method simulations. However, these indices cannot be used as-is for multifluid models, and an index for characterizing mixing in gas-solid flows from continuous fields is needed. The performance of the new mixing index is tested in two applications. The first is a 3D simulation of the mixing of biomass and sand in a fluidized bed reactor, and the second is a 2D simulation of binary particle segregation in a fluidized bed. The simulations are performed using OpenFOAM®. The mixing index is used to quantify gas-solid mixing using solid volume fractions and solid-solid mixing using solid fractions. The formulation of conventional mixing indices is extended to be used with solid volume fractions fields, and methods for performance improvement are presented.     

Alpha‐Synuclein Binds to the Inner Membrane of Mitochondria in an α‐Helical Conformation

The human alpha‐Synuclein (αS) protein is of significant interest because of its association with Parkinson's disease and related neurodegenerative disorders. The intrinsically disordered protein (140 amino acids) is characterized by the absence of a well‐defined structure in solution. It displays remarkable conformational flexibility upon macromolecular interactions, and can associate with mitochondrial membranes. Site‐directed spin‐labeling in combination with electron paramagnetic resonance spectroscopy enabled us to study the local binding properties of αS on artificial membranes (mimicking the inner and outer mitochondrial membranes), and to evaluate the importance of cardiolipin in this interaction. With pulsed, twofrequency, double‐electron electron paramagnetic resonance (DEER) approaches, we examined, to the best of our knowledge for the first time, the conformation of αS bound to isolated mitochondria.     

Development of sensitive and specific multiplex PCR method for the detection of microcystin producing cyanobacteria in spirulina food supplements

Food Science and Biotechnology - Spirulina has emerged as the next-generation dietary supplement owing to its health benefits. Despite the advantages, there have been reports of contamination by...     

Best Minimum Summation Scheduler for Long Term Evolution

Resource scheduling in Long Term Evolution (LTE) is an open and rising issue. It has an enormous impact on the entire system performance. Due to the nature of LTE system, the scheduler has to be designed carefully. It has to overcome many challenges such as limited processing time and the high dynamic behavior. This paper proposes a novel scheduling policy for the MAC layer in LTE called the Best Minimum Summation (BMS). The main aim of this scheduling policy is to achieve high performance with low complexity. Three sub-schedulers have been developed. Each one of these schedulers deals with scheduling table in different dimension. The first one operates on the scheduling table through the user dimension (BMS.UE); while the second one operates on the scheduling table through the resource block dimension (BMS.RB). The third scheduler operates on the scheduling table correlating both of these dimensions (BMS.2D). All of the proposed solutions were intensively evaluated in a system level simulator. Three performance metrics were used which are throughput, error rate and fairness. The results have shown that the ability of the BMS.UE scheduler to outperform other existing schedulers of LTE.     

Ion-Exchange Behavior of New and Novel Zirconium(IV)-Based Composite Cation-Exchangers

The synthesized polyaniline-Zr(IV) selenoiodate and polyaniline-Zr(IV) selenomolybdate composite ion exchangers were characterized by Fourier transform infrared spectroscopy, UV spectra, X-ray diffraction, scanning electron microscope, thermogravimetric analysis, and conductivity studies. The ion-exchange capacities, effect of eluent concentration, elution time, elution behavior, and pH on ion-exchange capacity were also studied to exploit the ion-exchange capability of the composites. The study revealed that polyaniline-Zr(IV) selenoiodate and polyaniline-Zr(IV) selenomolybdate ion exchangers are having excellent ion-exchange capacity values for K⁺ ion 1.36 and 1.44?meq?g^?1, respectively. The organic polymeric part of the composites provides mechanical and chemical stability, whereas the inorganic part supports the ion-exchange behavior and thermal stability. The increase in electrical conductivity is due to the inorganic and organic parts. A mechanism for the formation of the polyaniline-Zr(IV) selenoiodate and polyaniline-Zr(IV) selenomolybdate composite ion exchangers is discussed, which may also be applied for the preparation of other composite ion exchangers. Sorption behavior of metal ions on the composites was studied in different solvent systems. On the basis of distribution coefficient values (K_d), it has been found that the cation-exchange materials are highly selective for Pb(II)-ions. Such modified composite materials can be applied as an electrochemically switchable ion exchanger for water treatment, especially water softening.