LaZSM5-Al-Mg催化剂上乙烯与甲苯烷基化制对甲基乙苯

以LaZSM5沸石为基质,添加铝和镁的氧化物所制得的择形催化剂,可大大提高乙烯与甲苯烷基化制甲基乙苯中对甲基乙苯选择性。考察了稀释气和反应产物的添加对烷基化反应的影响。失活后的催化剂可烧炭再生。     

Magnetic effects of direct ion implantation of Mn and Fe into p-GaN

In p-GaN implanted with Mn (3×10¹⁶ cm⁻² at 250 keV), the material after annealing shows ferromagnetic properties below 250 K. Cross-sectional transmission electron microscopy (TEM) revealed the presence of platelet structures with hexagonal symmetry. These regions are most likely Ga_xMn_1−xN, which produce the ferromagnetic contribution to the magnetization. In p-GaN implanted with Fe, the material after annealing showed ferromagnetic properties at temperatures that were dependent on the Fe dose, but were below 200 K in all cases. In these samples, TEM and diffraction analysis did not reveal any secondary phase formation. The results for the Fe implantation are similar to those reported for Fe doping during epitaxial growth of GaN.     

稀疏气泡流动的粒子跟踪测速技术研究

采用动态阈值技术实现了对气泡图像的正确分割，利用灰度加权方法提高了气泡颗粒的定位精度。根据稀疏气泡流动图像的特点，提出了一种新的基于相关的粒子跟踪测速算法（2-HPTV）。通过进行两时刻中围绕待研究气泡所取的两个小的诊断窗口的相关运算，成功实现了气泡颗粒的轨迹追踪。实验表明本文算法较传统的PIV技术在测速精度上有很大程度的提高，与4帧粒子跟踪测速算法相比，降低了对摄像机帧频的要求，具有较强的实用性。     

镀锌层银盐黑色钝化工艺

在含ＡｇＮＯ３０．５～１ｇ／Ｌ，ＣｒＯ３５～１０ｇ／Ｌ，Ｈ２ＳＯ４０．５～１ｍｌ／Ｌ，光泽控制剂１０～２５ｍＬ／Ｌ的钝化液中处理镀锌层，可获得结合力良好、光亮的黑色钝化膜。     

植物油、脂肪酸和植物油甲酯在塔河稠油掺稀降黏中的应用评价

稠油由于富含沥青质、胶质等重质组分而具有很高的黏度，给稠油的开采和运输带来了很大的困难。降低稠油黏度进而改善其流动性成为一项十分重要的工作。以植物油、脂肪酸及植物油甲酯为掺稀介质，以塔河油田稠油为研究对象，考察对比了3种不同的掺稀介质对稠油的掺稀降黏效果。研究结果表明，3种掺稀介质对稠油具有良好的掺稀降黏效果，在同一掺稀比下，植物油甲酯对稠油的降黏效果最显著，其次是脂肪酸，再次是植物油。通过斑点试验考察了掺稀介质和稠油的相容性和体系稳定性。结果显示，植物油甲酯与稠油相容性和稳定性最好，脂肪酸和植物油与稠油的相容性和稳定性相对较差。     

Transport properties of critical dilute solutions

On the basis of the isomorphism of critical phenomena, the behavior of transport properties of binary mixtures in the vicinity of the vapor-liquid critical line is considered. In particular, the renormalization of the singularity of the thermal conductivity in dilute critical solutions has been analyzed in detail. It is shown that the behavior of the thermal conductivity is determined by the critical background, i.e., the fluctuation-induced regular part, which diverges at the critical point of a solvent.     

随动式动态混合器掺稀混合性能研究

针对稠油掺稀过程中原混合器混合效果不佳的问题,选择满面式螺旋叶片作为混合元件,增加动力叶轮,以增强叶片对流体的剪切能力和转动频率。基于CFD仿真软件,对影响动态混合器混合效果的叶片螺距和动力叶轮两参数进行数值模拟分析,并以管内稀油体积分布情况作为评价标准,研究混合过程中混合元件几何结构的变化对混合器性能的影响规律。结果表明,叶片螺距过小将阻碍流体在管内流动,导致混合速率降低,过大则会产生流体前窜现象;动力叶轮过少则会降低元件转动频率,过多则会阻碍流体向前流动。最后将优化后的新型随动式动态混合器与原混合器混合性能进行对比,新型随动式动态混合器内稀油体积分布更为均匀,能够更好地增强稠油掺稀混合效果,有利于稠油资源的开采。     

古交西山发电厂2×660 MW机组脱硝稀释风系统的改造与优化

针对古交西山发电有限公司2×660 MW超超临界直接空冷机组脱硝系统稀释风量降低导致喷氨量增加、氨逃逸增大的问题,从设计、设备选型、施工安装等多方面进行了分析,找到了导致稀释风量降低的原因,并提出了相应的改造与优化措施。措施实施后,稀释风量显著增加,氨逃逸明显降低,在保证机组净烟气NOx达标排放的同时提高了机组运行的安全经济性。     

醋酸丁酸纤维素淡酸分离装置的技术改造

针对醋酸丁酸纤维素淡酸分离装置操作难以稳定,无法进行连续生产且达不到淡酸分离要求的问题,分析了问题产生的原因,并对原装置进行技术改造,增强了操作控制手段,增设了轻相液体分布器,将脱酯塔提馏段改为板式结构并使用耐酸材料等。改造后,装置运行稳定,淡酸分离各项技术指标均达到设计要求。     

Investigation of transport phenomena in a hybrid ion exchange-electrodialysis system for the removal of copper ions

Hybrid ion exchange electrodialysis processes allow the removal of metal ions from dilute waste liquids and the recovery of more concentrated solutions. The work reported here was aimed at investigating the two steps in the treatment process, namely, adsorption of metal ions onto the packed bed of resin and electromigration (i.e., the transport of these ions in the complex system under the applied electrical field). The case of copper sulfate was investigated. Dowex resins with a cross-linking degree of 2 and 8% were used. The flux of copper through the resin bed and the current efficiency for ion transfer to the cathode compartment were determined as a function of potential gradient and copper ionic fraction in the bed. Apparent diffusion coefficients of Cu²⁺ in the overall system were deduced from the experimental data.