Zeolitic-imidazolate frameworks-derived Co3S4/NiS@Ni foam heterostructure as highly efficient electrocatalyst for oxygen evolution reaction

Transition metals sulfide-based nanomaterials have recently received significant attention as a promising cathode electrode for the oxygen evolution reaction (OER) due to their easily tunable electronic, chemical, and physical properties. However, the poor electrical conductivity of metal-sulfide materials impedes their practical application in energy devices. Herein, firstly nano-sized crystals of cobalt-based zeolitic-imidazolate framework (Co-ZIF) arrays were fabricated on nickel-form (NF) as the sacrificial template by a facile solution method to enhance the electrical conductivity of the electrocatalyst. Then, the Co₃S₄/NiS@NF heterostructured arrays were synthesized by a simple hydrothermal route. The Co-ZIFs derived Co₃S₄ nanosheets are grown successfully on NiS nanorods during the hydrothermal sulfurization process. The bimetallic sulfide-based Co₃S₄/NiS@NF-12 electrocatalyst demonstrated a very low overpotential of 119 mV at 10 mA cm^?2 for OER, which is much lower than that of mono-metal sulfide NiS@NF (201 mV) and ruthenium-oxide (RuO₂) on NF (440 mV) electrocatalysts. Furthermore, the Co₃S₄/NiS@NF-12 electrocatalyst showed high stability during cyclic voltammetry and chronoamperometry measurements. This research work offers an effective strategy for fabricating high-performance non-precious OER electrocatalysts.     

Iron(II) Sulfate(VI) from Titania Production as a Raw Material for Preparation of Hydrogen Sulfide Sorbents

A hybrid sorbent material for removal of hydrogen sulfide from air was developed. The material is based on activated carbon and iron compounds obtained from waste iron(II) sulfate(VI) heptahydrate. The iron salt is deposited on the carbonaceous support and subjected to oxidation (Fe²⁺ to Fe³⁺) using atmospheric oxygen under alkaline conditions. An effect of H₂O₂ addition to the process on the composition of the resultant material was also examined. X-ray diffraction (XRD) analyses confirmed easy conversion of waste FeSO₄·7H₂O to iron oxides Fe₃O₄ and FeOOH. The activated carbon supporting iron oxides revealed a higher efficiency in H₂S elimination from air compared to the commercial activated carbon, without any modification.     

三种硫化氢吸收剂吸收效率对比及碘酸钾体系吸收条件优化研究

硫化氢具有腐蚀性与毒性，采用吸收剂吸收硫化氢气体是重要的脱硫处理方式。不同的吸收剂在吸收效率上存在较大差别。首先对比了三氯化铁体系、碘酸钾体系和碱性铁氰化钾体系三种不同硫化氢吸收剂的吸收效率。在此基础上重点优化了碘酸钾体系吸收条件参数，讨论了包含浓度、温度、pH、气体流量及时间等因素对硫化氢吸收效率的影响。并建立了四因素三水平正交试验研究较优吸收条件，得到正交试验优化吸收条件为：温度55℃，pH 6.01，硫化氢流量0.3 L·min^-1，吸收时间1 min，该条件下8%（质量）碘酸钾体系的三级吸收效率为51.56%。研究结果对硫化氢吸收处理提供了理论参考，也为间接电解法循环处理研究提供了支持。     

郴州某复杂硫化铅锌矿阶段磨浮试验研究

针对郴州某复杂硫化铅锌矿资源的性质特点,采用铅快速浮选后尾矿再磨再选的阶磨阶选工艺,较好地实现了铅锌的高效浮选回收。研究了磨矿方式、捕收剂和调整剂种类及用量等因素对该矿石浮选的影响,确定了最佳浮选条件,通过小型闭路浮选试验,得到了铅品位60.05%、回收率89.63%的铅精矿和锌品位47.01%、回收率88.14%的锌精矿。     

Effects of anion and cation doping on the thermoelectric properties of n-type PbS

The PbCl_xS_1-x and Pb_1-xBi_xS (x? =?0–0.05) bulks were fabricated with a facile method of hydrothermal synthesis and microwave sintering, and the effect of anionic and cationic donors on the thermoelectric performance of PbS was investigated. Although Cl^? and Bi³⁺ both effectively improved the thermoelectric properties of n-type PbS, more excellent thermoelectric performance was obtained from Cl^? doped samples because of higher electrical property and lower thermal conductivity at higher temperature (T? >?600?K). The thermoelectric figure of merit (ZT) reaches 1.04 for PbCl_0.015S_0.985 at 800?K and increases with temperature increasing without sign of saturation, which is probably the highest value ever reported for single-phase polycrystalline n-type PbS. The results also indicate that the hydrothermal synthesis and microwave sintering can realize anion doping as well as cation doping for n-type PbS at low cost, and PbS should be a robust alternative for PbTe thermoelectric materials.     

基于双转子连续混炼挤出机的PPS/CF复合材料制备及性能研究

采用双转子连续混炼挤出机并通过熔融共混法制备了碳纤维(CF)增强聚苯硫醚(PPS)复合材料，并对其微观形貌、动态力学性能、力学性能和导电性能进行了研究，且对相关的影响因素进行了分析。结果表明，适当降低挤出机转子转速、提高CF含量可以改善PPS/CF复合材料的力学性能和导电性能；当转子转速为200r/min时，采用含量为20 % (质量分数，下同)的CF制得的PPS/CF复合材料的冲击强度达到49.94 J/m，体积电阻率达到60.65 Ω·cm，均优于纯PPS。     

燃油选择性吸附脱硫的多孔材料研究进展

吸附脱硫技术具有操作条件温和、节能、不改变燃油品质和成本低等特点而备受关注。针对噻吩类难脱除硫化物的深度脱除和转化问题，综述了近年来应用多孔吸附材料选择性吸附超深度脱除燃油中噻吩类硫化物的作用机理及最新研究进展。重点分析了分子筛、金属有机骨架、多孔炭材料、复合材料等不同吸附剂的研究现状，并探讨了各种吸附材料的吸附机理、改性方式和优缺点。本文指出分子筛因优异的热稳定性、高比表面积、均一的孔道结构、低成本和易于工业化等特点，是目前最具优势的吸附剂材料。未来研究应着重阐明吸附机理、提高合成便捷性、脱硫性能以及再生能力，更全面系统的研究将为开发具有理想选择性和再生能力的高效吸附剂奠定基础。     

Method for Preparation of Semiconductor Quantum‐Rod Lasers in a Cylindrical Microcavity

An efficient method for preparation of semiconductor quantum rod films for robust lasing in a cylindrical microcavity is reported. A capillary tube, serving as the laser cavity, is filled with a solution of nanocrystals and irradiated with a series of intense nanosecond laser pulses to produce a nanocrystal film on the capillary surface. The films exhibit intense room‐temperature lasing in whispering‐gallery modes that develop at the film–capillary interface as corroborated from the spacing detected for the lasing modes. Good lasing stability is observed at moderate pump powers. The method was applied successfully to several quantum‐rod samples of various sizes.     

软锰矿氧化硫化钡制高纯碳酸锰和氢氧化钡工艺研究

软锰矿同硫化钡溶液在较低温度下进行氧化还原反应，当硫化钡含量控制在26-75g／L范围内，软锰矿与硫化钡的物质的量比为2．5-3，反应时间50-60min，软锰矿被硫化钡还原为MnO，其还原率可达93．5％以上；还原后的锰用硫酸浸取，溶液经除杂后，与碳酸铵反应而制成高纯碳酸锰。硫化钡则被氧化为氢氧化钡，经蒸发、结晶而制得入水氢氧化钡，其回收利用率高速95％。