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《能源学会志》2020,93(4):1449-1459
Oil shortage and awareness of environment pollution leads to the extensive use of biodegradable starch-based materials against synthetic plastics. The accumulated wastes of these plastics takes more time for natural recycling and the process is complex. Therefore the best option of recycling would be to convert these polymers into a source of energy by pyrolysis. So to understand the pyrolytic behaviour, kinetics of such waste plastics is studied by using thermogravimetric analysis at different heating rates of 10 °C, 20 °C, 40 °C, 60 °C, 80 °C and 100 °C in nitrogen atmosphere followed by characterization of the pyrolysis products. The kinetic parameters are obtained for two major stages of decomposition in two different temperature ranges 250–620 °C and 620–855 °C by iso-conversional methods such as Friedman, Coats-Redfern, FWO and Kissinger methods. The regression coefficient data (>0.9) of kinetic plots obtained for different methods best fits to the kinetic equation. Empirical formula of the compound is determined by ultimate analysis is CH2.214S0.0018O0.6910. Proximate analysis gives the idea of volatile component which is74.33%. The range of average value of activation energy is 120.7013 kJ/mol to 140.7707 kJ/mol for the biodegradable plastic plate with different conversion (0.1–0.6) and (0.1–0.3) respectively at two different temperatures. The pyrolysis products obtained using a semi-batch reactor are characterized to know their composition and other properties. 相似文献
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分析了污水处理厂各个不同工艺段气、液两相中恶臭有机含硫化合物的分布情况,同时运用气相色谱-质谱联用仪及吹扫-捕集系统对甲硫醇、甲硫醚、羰基硫、二硫化碳和二甲二硫等五种化合物进行了定性准确的和定量分析,并对其产生机制及来源进行了较为详实的解析.其中挥发性气体样品的采集通过动态箱收集,溶解在水体中的目标化合物运用高纯氮气吹脱收集.研究结果表明,在水相和气相中的恶臭化合物的分布在不同的处理单元呈现不同的恶臭浓度,但经过污水处理厂各工艺的深度处理后, 溶解在水体当中的恶臭含硫化合物及挥发到大气中的化合物均有明显下降,去除率均达到90%以上. 相似文献
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Ed W.B de Leer 《Water research》1985,19(11):1411-1419
In harbour sediment samples taken near an epichlorohydrin production plant, a series of highly chlorinated ethers and diethers were detected viz. three isomeric bis(dichloropropyl)ethers, several structurally closely related ethers with 9 carbon atoms (C9 ethers), a number of C12 ethers and diethers, and finally several C15 ethers. The formation of this new class of ether compounds can be explained on the basis of the chemistry of the addition of HOCl to allylchloride. After initial addition of Cl−, a reactive intermediate is formed which may react with the product dichloropropanol, to give the C6 ethers, or may polymerize with the starting compound allylchloride followed by reaction with the product, to give the C9, C12 and C15 ethers. 相似文献
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气质联用仪在气体分析中的应用 总被引:6,自引:2,他引:4
通过实验论述了气质联用在气体分析中的应用,对硫化氢、氧硫化碳气体的线性、灵敏度和数据重复性进行了考察,探讨了气质联用仪用于气体定量分析的可靠性,并给出了其它气体的色谱分析条件及谱图。 相似文献
6.
Robin Wijngaard Meritxell Perramn Marina Parra-Robert Susana Hidalgo Gina Butrico Manuel Morales-Ruiz Muling Zeng Eudald Casals Wladimiro Jimnez Guillermo Fernndez-Varo Gerald I. Shulman Gary W. Cline Gregori Casals 《International journal of molecular sciences》2021,22(9)
The metabolic ratios lactate/pyruvate and β-hydroxybutyrate/acetoacetate are considered valuable tools to evaluate the in vivo redox cellular state by estimating the free NAD+/NADH in cytoplasm and mitochondria, respectively. The aim of the current study was to validate a gas-chromatography mass spectrometry method for simultaneous determination of the four metabolites in plasma and liver tissue. The procedure included an o-phenylenediamine microwave-assisted derivatization, followed by liquid-liquid extraction with ethyl acetate and silylation with bis(trimethylsilyl)trifluoroacetamide:trimethylchlorosilane 99:1. The calibration curves presented acceptable linearity, with a limit of quantification of 0.001 mM for pyruvate, β-hydroxybutyrate and acetoacetate and of 0.01 mM for lactate. The intra-day and inter-day accuracy and precision were within the European Medicines Agency’s Guideline specifications. No significant differences were observed in the slope coefficient of three-point standard metabolite-spiked curves in plasma or liver and water, and acceptable recoveries were obtained in the metabolite-spiked samples. Applicability of the method was tested in precision-cut liver rat slices and also in HepG2 cells incubated under different experimental conditions challenging the redox state. In conclusion, the validated method presented good sensitivity, specificity and reproducibility in the quantification of lactate/pyruvate and β-hydroxybutyrate/acetate metabolites and may be useful in the evaluation of in vivo redox states. 相似文献
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The aim of this work is to study the reaction of ozone and combined ozone/hydrogen peroxide mixtures with the fluorescent brightener 28 in dilute aqueous solution using controlled experimental conditions. The kinetics were also evaluated under various experimental conditions. The main ozonation by-products have been identified by High Pressure Anionic Exchange Chromatography (HPAEC) and Gas Chromatography coupled with Mass Spectrometry (GC-MS) techniques and a reaction pathway is proposed. In order to confirm this mechanism, melamine and s-triazine have been treated under the same reaction conditions and their decomposition pathways were studied. 相似文献
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本研究对罗汉松总黄酮提取工艺进行了研究,经过筛选确认了以β-环糊精-硫酸钠体系,单因素基础上通过四因素三水平响应面实验得出对罗汉松枝叶挥发油的最佳条件为萃取时间35min,β -环糊精浓度40%,硫酸钠浓度15%,萃取温度30℃,在此条件下罗汉松枝叶挥发油得率为1.372%。在质谱图中共鉴定出其中22个化合物约占色谱面积93.72 %。萜烯及其含氧衍生物18种,占总含量的73.74 %,其中萜醇类化合物4种,萜醛类化合物2种,脂肪族化合物4种,占含量的19.98 %,其中酯类化合物2种,酸类化合物2种。取得到的挥发油中主要成分为石竹烯、α -蒎烯和β -蒎烯,含量分别为17.62%、9.78%和7.47%。 相似文献