井下乳化/水热催化裂解复合降黏开采稠油技术研究

实验考察了胜利孤东稠油井下催化水热裂解和乳化/催化水热裂解降黏效果。所用催化剂为水溶性铁镍钒体系,Fe3+∶Ni2+∶VO4+=5∶1∶1,100 g稠油与30 g 0.5%催化剂水溶液在240℃反应24小时。原始黏度(50℃)11.0和8.36 Pa.s的两种稠油裂解并静置除水后,黏度降低76.2%和75.6%,室温放置60天后降黏率下降小于3个百分点,气相色谱显示裂解后轻组分明显增加,红外光谱显示稠油组分发生脱羧反应且芳环数减少。讨论了稠油催化水热裂解反应机理。所用化学助剂JN-A在油水中均可溶,耐温达250℃,耐矿化度达50 g/L,其水溶液以30∶100的质量比与稠油混合时形成低黏度的O/W乳状液。当水相含1.0%JN-A和0.5%催化剂时,两种稠油水热裂解后的反应混合物为O/W乳状液,黏度仅为319和309 mPa.s,静置除水后的稠油降黏率增加到86.5%和87.3%,其中的轻组分含量进一步增加。该井下乳化/催化水热裂解复合降黏法成功地用于孤东两口蒸汽吞吐井,稠油井作业后初期采出的原油黏度由~9 Pa.s降低到1 Pa.s左右,随采油时间延长而逐渐升高,约50天后超过4Pa.s。图2表6参5。     

煤层气利用新方案

在介绍煤层气的常规利用方案的基础上，提出了两种利用煤层气的新方案：一是采用变压吸附技术，纯化瓦斯气，将低浓度瓦斯气浓缩为高浓度瓦斯气，加压后成为CNG，用作CNG气源或较远距离城市的天然气气源；二是在第一种方案的基础上，将高浓度瓦斯气全部采用深冷法加以液化，生产LNG，并将LNG运送至更远距离用作LNG加气站、CNG加气站气源。最后还以松藻煤电公司为例，作了新方案的工程预算     

SiGe／Si多量子阱中垂直方向红外吸收及共振色散效应

用垂直入射的中红外光束调制非掺杂SiGe/Si量子阱中光致子带间吸收，氩离子激光器作为子带间跃迁的光泵浦源在阱中产生载流子，红外调制光谱用步进式傅立叶变换光谱仪记录，实验中观察到明显的层间干涉效应与子带间跃迁有关的色散效应，理论和实验分析认为样品折射率变化造成的位相调制可以补偿吸收所造成的幅度调制。     

大庆油田套损井打通道加固技术

介绍了大庆油田近几年在套损井打通道加固技术方面取得的技术进步，在磨铣打通道技术上主要对钻铣工具的结构进行了优化设计及合理及合金刀块的优选组合，提高了磨铣效率，缩短了施工周期；在爆炸打通道技术中设计了安全隔爆装置，提高了施工的安全性，使爆炸扩径技术得到完善；Φ106mm密封加固技术的研制成功，取代了Φ100mm密封加固技术，为套损井修复后的完井工艺提供有效的技术支持，提出了大庆油田目前在套损井打通道加固方面存在的难题，结合国外在套损井打通道加固方面技术的新发展，对现有技术的局限性进行了分析，提出了今后技术攻关的方向。     

Geochemical characteristics of the Yufuin outflow plume, Beppu hydrothermal system, Japan

Thermal water at Yufuin (Kyushu Island, Japan) is tapped through about 820 shallow wells and used mainly for hot-spring bathing purposes. Chemical and isotopic data for fluids from wells and fumaroles in Yufuin and Beppu indicate that the thermal activity at Yufuin represents a dilute, westward-flowing hydrothermal outflow plume from the Beppu hydrothermal system. Two other (eastward-flowing) outflow plumes have long been recognized at Beppu, but the Yufuin outflow plume is first recognized here. The Yufuin outflow plume is apparently a mixture of two end-member fluids: (1) deep high-temperature (250–300°C) fluid from the Beppu system having high chloride concentration (1400–1600 mg/L) and a δ¹⁸O value near −6.0%, and (2) meteoric water having low chloride concentration (≤7 mg/L) and a δ¹⁸O value near −9.2%.A permeable conduit for the vertical and lateral transport of deep fluid from the Beppu system is provided by the Yufuin Fault zone, which extends westward from the southern flank of Mt. Tsurumi volcano to the town of Yufuin. Stable isotope ratios and chloride concentrations for shallow groundwaters near the eastern end of the fault, at an elevation near 700 m, are consistent with those required for the low-chloride meteoric end-member of the Yufuin thermal waters. Recharge of this meteoric water, as well as mixing with the Beppu deep fluid, may occur along the Yufuin Fault. Enthalpy-chloride relations indicate additional conductive heating of the Yufuin waters, in the amount of 350–500 kJ/kg beyond that which can be accounted for by mixing between Beppu deep fluid and meteoric water. This could be a result of conductive heating with convection to a depth of 1–2 km. Estimates of the magnitude of the heat source for the Beppu hydrothermal system should take into account the heat being discharged at Yufuin.     

沁水盆地北端煤层气储层特征及富集机制

煤层气的富集与储层特征密切相关,并受地质条件的制约。在详细研究煤储层特征及煤层气富集机制的基础上,对沁水盆地北端煤层气的开发前景进行了初步评价。煤岩、煤质、煤体结构及孔渗性、吸附性的观察和测试显示,该区煤层厚度大,热演化程度高,局部发育构造煤,裂隙较发育,吸附性能力强,含气量高,含气饱和度偏低,适合煤层气的开发。该区煤层气的富集主要受控于热演化史和埋藏史。在区域变质的背景上,叠加了岩浆热变质作用,生气强度大。另外,煤层的埋深、顶底板封闭性及水文地质条件都会影响煤层含气量的大小,煤层气富集是多因素有效配置的结果。      

The Einstein relation in nanostructured materials: simplified theory and suggestion for experimental determination

An attempt is made to study the Einstein relation for the diffusivity–mobility ratio (DMR) in quantum wells (QWs) and quantum well wires (QWWs) of tetragonal compounds on the basis of a newly formulated electron energy spectrum taking into account the combined influences of the anisotropies in effective electron mass, the spin–orbit splitting, and the presence of crystal field splitting, respectively. The results for quantum-confined III–V compounds form a special case of our generalized analysis. The DMR has also been studied for QWs and QWWs of II–VI and IV–VI materials. Taking QWs and QWWs of CdGeAs₂, InAs, CdS and PbSe as examples, it was found that the DMR increases with increasing carrier statistics and decreasing film thickness respectively in various oscillatory manners emphasizing the influence of dimensional quantizations and the energy band constants in different cases. An experimental method of determining the DMR in nanostructures with arbitrary dispersion laws has also been suggested and the present simplified analysis is in agreement with the suggested relationship. The well-known results for nanostructures with parabolic energy bands have also been obtained as special cases from this generalized analysis under certain limiting conditions.     

河口探区核销探井再评价

通过对河口探区内370口已经核销的老探井进行重新评价,认为受地质认识和采油工艺局限性的影响有21口已经核销的老探井初次试油不彻底。随着地质认识的不断完善和采油工艺的不断改进,对其中的17口井进行了重新试油均获得成功,产油量由8.94t/d增加到73.9t/d,新增探明石油地质储量6063×104t。实施核销探井再评价,不仅深化了地质认识,盘活了闲置资产,缩短了增储周期,降低了勘探成本,而且通过出油井点的突破,找到了一条高勘探成熟地区油气勘探的路子。