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排序方式: 共有1215条查询结果,搜索用时 15 毫秒
1.
MC nylon-6-b-polyether amine copolymers were prepared with macro-initiator based on amino-terminated polyether amine functionalized with isocyanate via in-situ polymerization. It was found that the introduction of polyether amine delayed the polymerization process of caprolactam by increasing apparent activation energy and pre-exponential factor, resulting in the decrease of molecular weight of nylon-6. The motion of molecular chain of the copolymers was easy because of the decreased hydrogen bonds and weakened inter-molecular forces. The physical entanglement of molecular chains of the copolymers was significant and strong which increased the entanglement density. Only the nylon-6 phase crystallized in the copolymers and the crystal grain size, spherulite size and crystallinity of the copolymers decreased. A small amount of γ crystal formed at high polyether amine content. The copolymers presented obvious strain hardening behavior in stress-strain curves and the loss factor dramatically increased while the glass transition temperature and storage module decreased. The fracture surface of the copolymers became rough and presented hairy structure, indicating that the toughening mechanism of the copolymers corresponded to the multi-layer crack extension mechanism. 相似文献
2.
焊膏工艺性要求及性能检测方法 总被引:9,自引:0,他引:9
焊膏是SMT工艺中不可缺少的钎焊材料,广泛应用于再流焊中;它是由一定的合金粉末和助焊剂均匀混合而成的膏状体。主要对SMT中焊膏的组成及焊膏性能检测方法进行了简要分析。 相似文献
3.
SiC/Al合金层状复合材料的机械性能及损伤行为 总被引:5,自引:0,他引:5
张永俐 《材料科学与工程学报》1994,(4)
在室温条件下测定了Al合金以连续层状形式存在于SiC陶瓷层间并渗透入SiC陶瓷层内、Al合金浓度呈层状变化高低相间,以及Al合金和SiC陶瓷均匀分布相互渗透三种SiC含量相同而结构形式不同的SiC/Al合金复合材料的机械性能;用SEM和光学显微镜观察分析了复合材料的断口形貌及裂纹扩展过程。结果表明,在SiC陶瓷层间以连续层状形式存在的Al合金在应力作用下发生较大程度的塑性变形,在裂纹尾部被拉伸和形成桥接,引起能量耗散,减缓裂纹扩展速度,防止裂纹张开,使复合材料的韧性得到明显改善;SiC/Al合金陶瓷─金属层状复合材料的损伤形式主要是SiC陶瓷层开裂、金属层桥接和裂纹偏转。 相似文献
4.
5.
Preparation and Properties of Sintering Additives Coated Si3N4 from Heterogeneous Nucleation Processing 总被引:1,自引:0,他引:1
The sintering additives such as Al2O3 and /or Y2O3 were coated on the surfaces of Si3N4 particles via heterogeneous nucleation processing using a buffered pH solution as the precipitation reagent .They nucleated and grew only on the surfaces of Si3N4 and did not form sol particles in solution by TEM observation .The isoelectric point(IEP) of coated Si3N4 was different from that of as-received Si3N4.The IEP of Al(OH)3-coated Si3N4 occurred at pH8.4, which is close to that of alumina .When Al(OH)3-coated Si3N4 particles were coated with Y(OH)3,the IEP of coated Si3N4 powder shifted from pH8.4 to pH9.2 ,similar to that of yttria.In addition ,the rheological data showed that Al2O3 and /or Y2O3 coated Si3N4 suspension is nearly Newtonian and that added Si3N4 suspension shows a shear rate thinning behavior. 相似文献
6.
I. A. Fatile 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1985,35(2):94-100
The effect of yeast cell volumetric concentration on the rheological properties of the suspensions was measured in a pipe-flow viscometer at 30°C: at low microbial concentrations the suspensions were Newtonian; however, non-Newtonian behaviour, which could be described by the power-law equation, was observed with suspensions at high microbial volumetric concentrations. At conditions of constant microbial morphology and growth rate, the results also indicated that a relationship could be developed between the power-law constants and the microbial volumetric concentration. 相似文献
7.
Xinsheng Zhu Hansong Xu Jianmei Lu Juying Wang Shunhua Zhou 《Journal of Polymer Research》2008,15(4):295-300
Poly(ethylene terephthalate) (PET) is of excellent mechanical properties and melt processability and is widely used as raw
material for textile fibers. However, the flame retardant properties of PET were rather poor, and both reactive and additive
phosphorus- and halogen-containing compounds have been employed to enhance the reaction-to-fire properties while the meltdripping
behaviour during burning hasn’t been handled properly with the flame retardants. In this work, fluoropolymer was blended with
both pure PET (pPET) and reactive phosphorus-containing flame retarded copolyester (fPET), and the flame retardance and char
formation and mechanical properties of the resulted pPET and fPET blends were investigated. The tensile strengths of modified
pPET samples were worsen whereas those of modified fPET samples were improved at low concentrations. The initial thermal degradation
in nitrogen was accelerated remarkably for the two polyesters with fluoropolymer. The oxygen indices of the all modified samples
were reduced while char formation and meltdripping suppression were encouraged. The apparent melt viscosity and elasticity
for the two polyesters were gained much with antidripping agent. Therefore, fluoropolymer improved char formation of the two
polyesters based on the gaseous phase mechanism while the partial suppression of meltdripping behavior and the decrease of
mechanical properties mainly originated from the increase of melt viscosity via fibrillation for pPET. 相似文献
8.
本文从流变学的观点出发,分析粘合剂在配制及粘结过程中,反映出不同的流变特性,而粘合剂本身的流动、粘度、触变性与涂胶及其粘合的质量关系重大。 相似文献
9.
高含水油包水乳化液稳定性机理及实验研究 总被引:2,自引:0,他引:2
本文在对油包水乳化液的微观机构进行分析的基础上,对高含水油包水乳化液的稳定性机理进行了实验研究,初步分析了它的流变性质。本文的研究对于油包水乳化液降低成本,提高性能的发展具有重要的理论意义。 相似文献
10.
通过自制的双筒旋转粘度计对过共晶ZL117合金的表观粘度进行了研究。结果表明,随着保温温度的降低,即固相率的升高,ZL117合金浆料的表观粘度随之增加;随着搅拌电流的增加,其表观粘度先降低,在搅拌电流为14A左右时达到最低,然后增大;随着冷却速度的增大,其表观粘度增大。 相似文献