Combination of nuclear magnetic resonance spectroscopy and nonlinear methods to analyze the copolymerization of phosphonic acid derivatives

We demonstrate in this study that the combination of modern inline monitoring methods [here: inline nuclear magnetic resonance (NMR)] with simulations gains more exact and profound kinetic results than previously used methods like linearization without that combination. The ¹H-NMR spectroscopic data (more than 100 data points) are used to construct the copolymerization diagram. The reactivity ratios are obtained applying the van Herks nonlinear least square method. The examination of the radical copolymerization of 2-hydroxyethyl methacrylate (HEMA) with (2-{[2-(ethoxycarbonyl)prop-2-en-1-yl]oxy}ethyl) phosphonic acid (ECPPA) as important adhesive monomer used in dentistry yields reactivity ratios of r_HEMA = 1.83; r_ECPPA = 0.42. The copolymerization diagram reflects nonideal, non-azeotropic copolymerization. The sequence distribution of the obtained by Monte Carlo simulation indicates the generation of statistical copolymers. As an important finding, it is demonstrated that the repeating units responsible for etching and adhesion are arranged over the whole polymer chain, which is necessary to achieve proper functionality. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48256.     

7-羟基全氢化噁唑并噁嗪鞣剂的合成及其鞣性研究

报导了新型鞣剂 7-羟基全氢化唑并嗪 (以下简称 OX- Z)的合成方法。试验确定合成的最佳条件为 :在氮气保护下 ,将等摩尔量的二乙醇胺在 10℃水浴中缓慢滴入乙二醛中 ,滴加时间 0 .5 h,在 2 0℃水浴中继续反应 1.5 h,产率为 6 2 .9%。 OX- Z对浸酸绵羊皮单独鞣制 ,可使收缩温度升高到 87℃。最佳鞣制条件为 :p H10 .0 ,OX- Z用量 5 % ,鞣制时间 8h。在对 OX- Z与皮胶原的结合类型的研究中证明它们之间是以化学键结合的。     

C/O能谱测井数据预处理的两点改进意见

简单介绍了碳氧比测井的原理及通常的数据处理方法。分析了由常规数据处理所得曲线仍然存在的问题及可能的成因 ,并给出了可行的修正办法。讨论了另一种可行的曲线异常数据的检测、剔除方法。实践表明 :文章讨论的两点建议都是可行的 ,并且在提高测量曲线质量的同时也提高了地层含油饱和度的解释精度。     

大港白水头地区低阻油气层测井评价

在对白水头地区低阻油层的地质特征、物性特征及成因环境进行了分析研究后 ,应用测井曲线特征集法 ,把白水头油田常规油气层、低阻油气层、油水同层、水层等看成是独立的地质事件 ,建立了它们与测井曲线特征之间的对应关系 ,利用这种关系对未知地质事件进行了预测划分。最后根据所建模型定量计算储层各种参数 ,收到了良好的地质效果 ,表明测井曲线特征集法对于识别多成因的低阻油层是一种有效方法     

Morphology and properties of poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene]/silica nanoparticle hybrid films

Poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene] (MEH‐PPV)/silica nanoparticle hybrid films were prepared and characterised. Three kinds of materials were compared: parent MEH‐PPV, MEH‐PPV/silica (hybrid A films), and MEH‐PPV/coupling agent MSMA/silica (hybrid B films), in which MSMA is 3‐(trimethoxysilyl) propyl methacrylate. It was found that the hybrid B films could significantly prevent macrophase separation, as evidenced by scanning electron and fluorescence microscopy. Furthermore, the thermal characteristics of the hybrid films were largely improved in comparison with the parent MEH‐PPV. The UV‐visible absorption spectra suggested that the incorporation of MSMA‐modified silica into MEH‐PPV could confine the polymer chain between nanoparticles and thus increase the conjugation length. The photoluminescence (PL) studies also indicated enhancement of the PL intensity and quantum efficiency by incorporating just 2 wt% of MSMA‐modified silica into MEH‐PPV. However, hybrid A films did not show such enhancement of optoelectronic properties as the hybrid B films. The present study suggests the importance of the interface between the luminescent organic polymers and the inorganic silica on morphology and optoelectronic properties. Copyright © 2004 Society of Chemical Industry     

Expressive Facial Gestures From Motion Capture Data

Human facial gestures often exhibit such natural stochastic variations as how often the eyes blink, how often the eyebrows and the nose twitch, and how the head moves while speaking. The stochastic movements of facial features are key ingredients for generating convincing facial expressions. Although such small variations have been simulated using noise functions in many graphics applications, modulating noise functions to match natural variations induced from the affective states and the personality of characters is difficult and not intuitive. We present a technique for generating subtle expressive facial gestures (facial expressions and head motion) semi‐automatically from motion capture data. Our approach is based on Markov random fields that are simulated in two levels. In the lower level, the coordinated movements of facial features are captured, parameterized, and transferred to synthetic faces using basis shapes. The upper level represents independent stochastic behavior of facial features. The experimental results show that our system generates expressive facial gestures synchronized with input speech.     

快速色谱分析技术在油气勘探中的应用

文章通过对五口井的现场应用介绍，阐述了快速色谱分析技术在油气层识别和解释方面的准确性，探讨了该技术在薄油气层的发现和评价、快速钻进条件下油气层的发现、对油气层全烃组份变化的统一、水平井的地质导向以及排除钻井液添加荆对油气显示的影响五个方面的优势，从而论证了快速色谱分析技术在油气勘探中的应用价值。     

郯庐断裂带含油气性研究

郯庐断裂带是中国东部一条巨型断裂构造带,该文从其基本构造特征入手,分析了它的几何学、运动学和动力学特征,并进一步研究其含油气特点,认为:a)郯庐断裂带对中国东部诸多中新生代含油气盆地的形成及演化有重要的控制作用,不同演化阶段产生并控制了不同的沉积盆地(如松辽盆地和渤海湾盆地);b)郯庐断裂带对油气藏的形成及演化有重要的控制作用,不仅控制盆地烃源岩的发育、基本的储集层和盖层条件,以及圈闭的形成等等,而且对油气的生成、运移及聚集成藏、大中型油气田的形成及分布等有重要的控制作用.      

Results of a User Study on 2D Hurricane Visualization

We present the results from a user study looking at the ability of observers to mentally integrate wind direction and magnitude over a vector field. The data set chosen for the study is an MM5 (PSU/NCAR Mesoscale Model) simulation of Hurricane Lili over the Gulf of Mexico as it approaches the southeastern United States. Nine observers participated in the study. This study investigates the effect of layering on the observer's ability to determine the magnitude and direction of a vector field. We found a tendency for observers to underestimate the magnitude of the vectors and a counter‐clockwise bias when determining the average direction of a vector field. We completed an additional study with two observers to try to uncover the source of the counter‐clockwise bias. These results have direct implications to atmospheric scientists, but may also be able to be applied to other fields that use 2D vector fields.