全文获取类型
收费全文 | 760篇 |
免费 | 43篇 |
国内免费 | 18篇 |
专业分类
电工技术 | 6篇 |
综合类 | 11篇 |
化学工业 | 265篇 |
金属工艺 | 8篇 |
机械仪表 | 10篇 |
建筑科学 | 30篇 |
矿业工程 | 5篇 |
能源动力 | 15篇 |
轻工业 | 90篇 |
水利工程 | 2篇 |
石油天然气 | 8篇 |
武器工业 | 3篇 |
无线电 | 52篇 |
一般工业技术 | 56篇 |
冶金工业 | 7篇 |
原子能技术 | 4篇 |
自动化技术 | 249篇 |
出版年
2023年 | 7篇 |
2022年 | 6篇 |
2021年 | 28篇 |
2020年 | 19篇 |
2019年 | 20篇 |
2018年 | 21篇 |
2017年 | 31篇 |
2016年 | 21篇 |
2015年 | 20篇 |
2014年 | 26篇 |
2013年 | 69篇 |
2012年 | 37篇 |
2011年 | 58篇 |
2010年 | 36篇 |
2009年 | 70篇 |
2008年 | 55篇 |
2007年 | 54篇 |
2006年 | 47篇 |
2005年 | 33篇 |
2004年 | 25篇 |
2003年 | 27篇 |
2002年 | 21篇 |
2001年 | 6篇 |
2000年 | 8篇 |
1999年 | 14篇 |
1998年 | 3篇 |
1997年 | 6篇 |
1996年 | 8篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1993年 | 7篇 |
1992年 | 7篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有821条查询结果,搜索用时 312 毫秒
1.
Malondialdehyde (MDA) was selected to represent a secondary by-product of lipid peroxidation during rice ageing. This study aimed to investigate the effects of MDA modification on the structural characteristics of rice protein. The results showed that as MDA concentration increased, rice protein carbonyl and disulphide groups increased, but sulphydryl content decreased. The blue shift of maximum fluorescence peak, the decrease of rice protein intrinsic fluorescence intensity and the reduction of surface hydrophobicity indicated the formation of protein aggregates caused by MDA oxidative modification. The results of molecular weight distribution and particle size distribution showed that MDA modification resulted in the formation of soluble protein aggregates, and the decrease of rice protein solubility indicated that insoluble protein aggregates were formed. Results of protein electrophoresis showed that MDA modification contributed to rice protein aggregation via non-disulphide covalent bonds. The results showed that rice protein gradually aggregated with increasing MDA concentration. 相似文献
2.
B. Ma P.I. Djurovich S. Garon B. Alleyne M.E. Thompson 《Advanced functional materials》2006,16(18):2438-2446
Efficient blue‐, green‐, and red‐light‐emitting organic diodes are fabricated using binuclear platinum complexes as phosphorescent dopants. The series of complexes used here have pyrazolate bridging ligands and the general formula C∧NPt(μ‐pz)2PtC∧N (where C∧N = 2‐(4′,6′‐difluorophenyl)pyridinato‐N,C2′, pz = pyrazole ( 1 ), 3‐methyl‐5‐tert‐butylpyrazole ( 2 ), and 3,5‐bis(tert‐butyl)pyrazole ( 3 )). The Pt–Pt distance in the complexes, which decreases in the order 1 > 2 > 3 , solely determines the electroluminescence color of the organic light‐emitting diodes (OLEDs). Blue OLEDs fabricated using 8 % 1 doped into a 3,5‐bis(N‐carbazolyl)benzene (mCP) host have a quantum efficiency of 4.3 % at 120 Cd m–2, a brightness of 3900 Cd m–2 at 12 V, and Commission Internationale de L'Eclairage (CIE) coordinates of (0.11, 0.24). Green and red OLEDs fabricated with 2 and 3 , respectively, also give high quantum efficiencies (~ 6.7 %), with CIE coordinates of (0.31, 0.63) and (0.59, 0.46), respectively. The current‐density–voltage characteristics of devices made using dopants 2 and 3 indicate that hole trapping is enhanced by short Pt–Pt distances (< 3.1 Å). Blue electrophosphorescence is achieved by taking advantage of the binuclear molecular geometry in order to suppress dopant intermolecular interactions. No evidence of low‐energy emission from aggregate states is observed in OLEDs made with 50 % 1 doped into mCP. OLEDs made using 100 % 1 as an emissive layer display red luminescence, which is believed to originate from distorted complexes with compressed Pt–Pt separations located in defect sites within the neat film. White OLEDs are fabricated using 1 and 3 in three different device architectures, either with one or two dopants in dual emissive layers or both dopants in a single emissive layer. All the white OLEDs have high quantum efficiency (~ 5 %) and brightness (~ 600 Cd m–2 at 10 V). 相似文献
3.
Andrea Vaccaro 《Polymer》2005,46(4):1157-1167
We propose a general methodology for the estimation of the doublet formation rate constant (proportional to the stability ratio of primary particles) in colloidal dispersions from measurements obtained by common optical techniques, such as dynamic light scattering, static light scattering (nephelometry) or turbidimetry. In contrast to previous approaches relying on the initial slopes of the measured quantities, such as the mean hydrodynamic radius, scattered light intensity or turbidity, we introduce a transformation of the measurables to properly scaled quantities, which grow linearly in time with a slope proportional to the doublet formation rate. Analysis of systematic and random errors allows one to control the error in the estimated value of the aggregation rate. Using this approach, we measured the aggregation rate constant of colloidal polymer particles prepared by surfactant-free emulsion copolymerization of styrene and 2-hydroxyethyl methacrylate (HEMA). It was found that the stability ratio at constant ionic strength decreases with increasing dilution of the original polymer latex. This can be explained by the presence of non-reacted stabilizing species (most likely oxidized HEMA) that desorb from the particle surface upon latex dilution and thus diminish the repulsive interactions between particles. In order to check if the stability of latex particles is influenced by reversibly adsorbed species it is always necessary to perform aggregation experiments at various dilutions. 相似文献
4.
5.
6.
The Dual Generalized Hessenberg Representation (Dual GHR) is a canonic form for single input single output systems which identifies the input-output properties of the system. Here it is shown how the dual GHR can be used to identify almost pole-zero cancellations and small residues of the corresponding poles. This connection between the state space representation and transfer function is established using geometrical arguments. Near unobservability and near uncontrollability, measures relying on angles between subspaces, play a key role. 相似文献
7.
A new discretization method for aggregation equations is developed. It is compared to the fixed pivot technique proposed by Kumar and Ramkrishna (1996a. On the solution of population balance equations by discretization—I. A fixed pivot technique. Chemical Engineering Science 51, 1311-1332). The numerical results for aggregation problems by discretized population balances are consistently overpredicting and diverge before the gelling point in the case of a gelling kernel. The present work establishes a new technique which assigns the particles within the cells more precisely. This is achieved by taking first the average of the newborn particles within the cell and then assigning them to the neighboring nodes such that pre-chosen properties are exactly preserved. The new technique preserves all the advantages of the conventional discretized methods and provides a significant improvement in predicting the particle size distribution (PSD). In addition, it is found that the technique is a powerful tool for the computation of gelling problems. The effectiveness of the technique is illustrated by application to several aggregation problems for suitably selected aggregation kernels including physically relevant kernels. 相似文献
8.
Bonifacio Llamazares 《Information Sciences》2007,177(21):4745-4756
One of the most important issues in the theory of OWA operators is the determination of associated weights. This matter is essential in order to use the best-suited OWA operator in each aggregation process. Given that some aggregation processes can be seen as extensions of majority rules to the field of gradual preferences, it is possible to determine the OWA operator weights by taking into account the class of majority rule that we want to obtain when individuals do not grade their pairwise preferences. However, a difficulty with this approach is that the same majority rule can be obtained through a wide variety of OWA operators. For this reason, a model for selecting the best-suited OWA operators is proposed in this paper. 相似文献
9.
石油沥青质的化学和物理:Ⅳ.石油沥青质溶液的胶体化学 总被引:13,自引:2,他引:11
本文从胶体化学的角度讨论了石油青质的性质,评述了自1924年以来提出的各种沥青胶体模型,探讨了石油胶粒的形状和尺寸,形成机制以及沥青质粒子聚集的动力学行为。 相似文献
10.
Douglas A. Watkinson Colin Charles Eva C. Enders 《Journal of Great Lakes research》2021,47(3):583-591
Common carp feeding and spawning behaviours negatively impact the functioning of marsh ecosystems. In the Netley-Libau Marsh, situated on the southern end of Lake Winnipeg, water level regulations, nonpoint source nutrient pollution, and the non-native common carp are thought to be the main contributors to the degradation of the marsh habitat. Using acoustic telemetry, we analysed the movement rate, frequency and timing of suspected spawning migrations, spatial ecology, and aggregation of common carp in the Lake Winnipeg drainage over a three year time period. Common carp moved the farthest during the open water period when water temperature was >5 °C. Their annual migration into Netley-Libau Marsh was correlated to ordinal date. Common carp left the marsh in late spring/early summer, presumably feeding in Lake Winnipeg, before moving to overwintering sites situated in Traverse Bay and Lake Winnipeg, where they arrived typically by October and formed aggregations. These findings will inform habitat and fisheries managers in the effort to undertake evidence-based management actions. The predictability of the movements and the tendency for common carp to aggregate indicates that exclusion techniques and commercial fishing may represent viable management solutions. 相似文献