碳酸盐岩岩溶储层多井评价方法及地质应用

多井评价是建立在单井精细解释对比分析基础上的预测储层及含油气性平面分布规律的技术方法,而常规测井资料无法区分碳酸盐岩岩溶储层,因而利用多井评价结果确定岩溶发育程度在平面上的分布规律就显得十分重要。为此,在岩心标定成像测井的基础上,对四川盆地高石梯—磨溪地区15口井的成像测井岩溶发育特征进行分析,建立了中二叠统茅口组岩溶发育各分带的标准成像图版,利用交会图及直方图分析各分带的常规测井响应特征,在此基础上形成了电成像测井刻度常规测井识别岩溶发育带的新方法。研究结果表明:①高石梯—磨溪地区茅口组岩溶带自上而下可划分为风化壳残积带、垂直渗流岩溶带、水平潜流岩溶带以及受岩溶作用较弱的基岩;②风化壳残积带在成像测井图像显示为"暗—亮—暗"条带状模式,垂直渗流岩溶带为垂直线状与暗色斑状组合模式,水平潜流岩溶带为水平线状—层状与斑状组合模式,基岩整体显示为亮色块状模式偶见线状或斑状特征;③有效储层主要发育在垂直渗流带和水平潜流带的顶部;④该区茅口组岩溶发育主要受裂缝发育控制,而裂缝发育又与断层关系密切。结论认为,该新方法对碳酸盐岩岩溶储层的多井评价具有普遍适用性,为四川盆地中二叠统风险探井的部署提供了技术支撑。     

Performance of LiNi1/3Co1/3Mn1/3O2 prepared from spent lithium-ion batteries by a carbonate co-precipitation method

Spherical LiNi_1/3Co_1/3Mn_1/3O₂ cathode particles were resynthesized by a carbonate co-precipitation method using spent lithium-ion batteries (LIBs) as a raw material. The physical characteristics of the Ni_1/3Co_1/3Mn_1/3CO₃ precursor, the (Ni_1/3Co_1/3Mn_1/3)₃O₄ intermediate, and the regenerated LiNi_1/3Co_1/3Mn_1/3O₂ cathode material were investigated by laser particle-size analysis, scanning electron microscopy–energy-dispersive spectroscopy (SEM-EDS), thermogravimetry–differential scanning calorimetry (TG-DSC), X-ray diffraction (XRD), inductively coupled plasma–atomic emission spectroscopy (ICP-AES), and X-ray photoelectron spectroscopy (XPS). The electrochemical performance of the regenerated LiNi_1/3Co_1/3Mn_1/3O₂ was studied by continuous charge–discharge cycling and cyclic voltammetry. The results indicate that the regenerated Ni_1/3Co_1/3Mn_1/3CO₃ precursor comprises uniform spherical particles with a narrow particle-size distribution. The regenerated LiNi_1/3Co_1/3Mn_1/3O₂ comprises spherical particles similar to those of the Ni_1/3Co_1/3Mn_1/3CO₃ precursor, but with a narrower particle-size distribution. Moreover, it has a well-ordered layered structure and a low degree of cation mixing. The regenerated LiNi_1/3Co_1/3Mn_1/3O₂ shows an initial discharge capacity of 163.5 mA h g^?1 at 0.1 C, between 2.7 and 4.3 V; the discharge capacity at 1 C is 135.1 mA h g^?1, and the capacity retention ratio is 94.1% after 50 cycles. Even at the high rate of 5 C, LiNi_1/3Co_1/3Mn_1/3O₂ delivers the high capacity of 112.6 mA h g^?1. These results demonstrate that the electrochemical performance of the regenerated LiNi_1/3Co_1/3Mn_1/3O₂ is comparable to that of a cathode synthesized from fresh materials by carbonate co-precipitation.     

碳酸盐岩储层裂缝评价方法探讨

对于碳酸盐岩储层，裂缝是非常常见的一种储集空间类型，因此，裂缝以及裂缝类型的识别显得尤其重要。通常认为，识别裂缝最有效的方法是利用成像测井进行直观解释，不足之处就是测井成本较高，尤其对于已开发油气田来说。因此如何利用低测井成本方法识别裂缝，是能否提高碳酸盐岩油田开发能力的重要途径。以中东某油气田大量的常规以及成像资料为基础，以成像测井刻度常规测井，运用交会图技术建立了以常规测井为基础的裂缝以及裂缝类型识别方法，并在TAB油田取得很好的应用效果。     

深层裂缝性碳酸盐岩储层混氮酸压技术

塔河油田奥陶系碳酸盐油藏 ,埋藏深、温度高 ,酸液滤失大 ,酸岩反应缓速困难。通过对混气酸压降滤、缓速、助排、造缝作用机理的研究 ,总结出该技术的工艺特点、控制要点、混注程序及注气量。在塔河油田现场应用 ,能提高残酸的返排能力 ,降低酸液的滤失系数     

铝锆酸酯偶联剂对超微碳酸钙表面性能的影响

用铝锆酸酯偶联剂对超微碳酸钙粉体进行表面改性。讨论了改性前后超微碳酸钙的润湿性、沉降体积、糊粘度、吸油率等表面性质的变化。结果表明：改性的超微碳酸钙与水的接触角增大，能很好地分散在有机介质中，糊粘度减小，吸油率减小，适合用于塑料和橡胶。     

高分辨力地震是提高中国南方碳酸盐岩地震勘探效能的基础——一个由失败到成功的史例

南方碳酸盐岩复杂地区的地震工作经历了长期艰难曲折的道路,其中异常判别的经验教训极为深刻。本文从地震异常分析入手,揭示其实质,寻求问题的关键,探讨解决的办法,介绍高分辨率地震方法技术,展示高分辨率地震新成果,以得出有意义的结论和建议。     

江汉盆地盐湖碳酸盐岩成藏条件及潜力——以新沟地区新沟嘴组下段Ⅱ油组为例

在物源、古地形、古气候的控制下,江汉盆地新沟嘴组下段Ⅱ油组自北而南发育有砂岩相、泥岩相、碳酸盐岩相、硫酸盐以及氯化盐岩相,盆地中南部斜坡带为碳酸盐岩的主要分布区,具有碳酸盐岩与薄层泥岩频繁互层沉积特征;其中碳酸盐岩晶间孔发育,具有较好的储集条件,泥岩有机质丰度高,具有较好的生烃能力,生储配置关系良好;新沟嘴组下段Ⅱ油组碳酸盐岩成藏条件优越,油气成藏主要受有利烃源岩分布范围、岩性岩相、物性控制,具有烃源岩控藏、岩性物性控富的特征;江汉盆地碳酸盐岩油藏分布广泛,具有较好的勘探开发前景。     

Modeling and analysis of wormhole formation in reactive dissolution of carbonate rocks

A two-scale continuum model is used to simulate reactive dissolution of carbonate rocks in radial flow. The three main types of patterns observed in linear and radial flow experiments, namely, compact, wormhole and uniform patterns are numerically simulated. The fractal nature of wormholes observed in laboratory experiments is established and confirmed through simulations and the fractal dimension is quantitatively matched. The dependence of wormhole fractal dimension, optimum injection rate and minimum pore volumes required to breakthrough the medium on heterogeneity magnitude and aspect ratio is investigated. A new criterion to predict the optimum injection rate for wormhole formation in radial flow is derived and validated. It is observed that the wormhole penetration depth increases with injection time as t^b, where the exponent b is found to be approximately 0.66, as observed in the experiments. A critical level of heterogeneity magnitude seems to exist below which the minimum pore volumes required to breakthrough are much higher.     

鲁南碳酸盐岩丘陵贫水区典型地下水赋存模式分析——以沂南、费县为例

根据山东省沂南、费县两县的抗旱找水打井工作,利用物探定井、成井以及水文地质试验过程,对松林、西柳沟、响井、颜河庄4个村的水文地质条件进行了深入分析,总结了鲁南碳酸盐岩分布区两种典型的地下水蓄水模式,即断层蓄水构造模式和裂隙-岩溶蓄水构造模式。断层蓄水构造主要分布于该区中下寒武统地层,分布并不均匀和普遍,出水效果主要取决于断层的分布、张扭性质以及地下水径流方向的补给源,与地形情况关系不大;裂隙-岩溶蓄水构造在该区主要分布于奥陶系及上寒武统地层,裂隙岩溶发育,富水性好,发育较为广泛和普遍,打井出水成功概率高。对于两种典型地下水赋存模式的深入分析,可以为今后碳酸盐岩丘陵贫水区的地下水勘查工作提供思路。