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排序方式: 共有2023条查询结果,搜索用时 31 毫秒
1.
针对呼吸道系统疾病与大气 PM2:5、 SO2 浓度序列的相关性特征, 应用多重分形消除趋势波动分析法
(MF-DCCA), 对张家界市永定区呼吸道系统疾病患病人数与大气 PM2:5、 SO2 浓度序列进行了研究。结果发现该地区
呼吸道系统疾病患病人数与大气 PM2:5、 SO2 浓度的相关性具有长期持续特征和多重分形特征。随后对它们相关性
多重分形特征的动力来源进行了分析, 通过随机重排和相位随机处理, 结果表明在不同时间尺度上的长期持续性影响
是其主要动力来源。进一步研究发现该地区呼吸道系统疾病与大气 PM2:5、 SO2 浓度序列的相关性在四个季节均具
有长期持续性的多重分形特征, 且夏季多重分形特征相对强于其他季节。 相似文献
2.
Single-metal high-temperature solid sorbents for syngas cleaning using Mn, Ca, Fe, Cu, or Mo supported on γ-Al2O3 were synthesized, characterized, and tested in a fixed-bed reactor. H2S and SO2 concentrations in the gas after treatment at T = 400 to 700 °C were compared with thermodynamic calculations. The Mn-based sorbent showed the best ability to achieve a low sulfur residual in the gas, especially at temperatures above 600 °C. Sorbents with Fe, Cu, and Mo gave SO2 formation in the initial phase, but this could be avoided by a pre-reduction treatment of the sorbent material. 相似文献
3.
4.
Hashim A.
Hashim 《国际强度与非线性控制杂志
》2020,30(10):3848-3870
》2020,30(10):3848-3870
This paper introduces two novel nonlinear stochastic attitude estimators developed on the Special Orthogonal Group with the tracking error of the normalized Euclidean distance meeting predefined transient and steady‐state characteristics. The tracking error is confined to initially start within a predetermined large set such that the transient performance is guaranteed to obey dynamically reducing boundaries and decrease smoothly and asymptotically to the origin in probability from almost any initial condition. The proposed estimators produce accurate attitude estimates with remarkable convergence properties using measurements obtained from low‐cost inertial measurement units. The estimators proposed in continuous form are complemented by their discrete versions for the implementation purposes. The simulation results illustrate the effectiveness and robustness of the proposed estimators against uncertain measurements and large initialization error, whether in continuous or discrete form. 相似文献
5.
Wujie Zhang Xiangjun Li Muhammad A. Nawaz Jiahao Pan Jiancheng Cao Dianhua Liu 《加拿大化工杂志》2020,98(5):1148-1156
Polyoxymethylene dimethyl ethers (PODEn) are extremely effective diesel additives to reduce soot formation during combustion. We introduce a series of Fe-Zn composite solid acid catalysts (SO42−/xFe2O3-yZnO), for the condensation reaction of methanol and paraformaldehyde (PF) with a cheap and feasible route to efficiently synthesize PODEn. These catalysts were characterized by different characterization techniques, namely BET, XRD, SEM, EDS, FTIR, and NH3-TPD and the results showed that Fe/Zn molar ratios strongly influenced the physicochemical characteristics of catalysts, thus affecting the methanol conversion and PODE1-6 and PODE3-6 selectivity. Accordingly, the methanol conversion was decreased and the selectivity of PODE3-6 was increased after increasing the Zn molar content. Comparatively, SO42−/Fe2O3-2ZnO exhibited superior catalytic activity among the various investigated catalysts due to the high acid density of strong acid sites. The optimal reaction conditions were observed to be at a 3.0 wt% catalyst loading (catalyst/reactant mass ratio), 2.5 hours ours of reaction time, a reaction temperature of 403 K, and a molar ratio of 3:1 of CH2O to methanol, achieving a high selectivity of 99.09% PODE1-6 and 28.23% PODE3-6 with 55.16% methanol conversion during the reaction. 相似文献
6.
通过第一性原理计算,采用Dmol3模块考察了B原子分别掺杂C3N二维材料的C位(B/C-C3N)和N位(B/N-C3N)所形成的两种单原子催化剂的结构、电子性质以及催化性能。首先,分析了B掺杂C3N的两种结构的稳定性与电子性质,发现B的掺杂使两种结构的稳定性均显著增强,B/C-C3N的电子性质变化更大,由半导体变成了导体。然后,分析了C3N、B/C-C3N和B/N-C3N这3种催化剂对SO2氧化反应的催化性能,计算比较了对O2与SO2的吸附能、电荷转移量、稳定构型、态密度以及O2活化后的键长。结果显示3种催化剂对O2的吸附能均大于SO2,均服从E-R机理,其中B/C-C3N对O2的吸附能最大、O2与SO2之间吸附能之差最大,对O2的活化程度最高,表现出最利于SO2催化氧化反应的性能。态密度分析也表明,O2与B/C-C3N在费米能级附近的杂化作用最强,这更利于反应的发生。因此,B/C-C3N具有成为SO2氧化反应优良催化剂的潜力。 相似文献
7.
The configurations of molecular clusters have significant impacts on their growth into fine particles in atmosphere. In this paper, we explore the topology space of the structure of H2SO4·NH3 dimer with a novel sampling technique of meta-dynamics (MTD) method and ab initio molecular dynamics simulations. The simulations are carried out at the temperatures of both 50 K and 242 K, which represent the typical high and low latitudes of troposphere. The results show that, compared with only traditional MD simulations, the structure samplings are significantly accelerated with MTD method. Therefore, more isomers of the dimer are discovered within the same simulation time scale. In addition, the results show that MTD is more efficient for circumstances with high temperature. 相似文献
8.
9.
Shao-Fang Li Zhen-Yi Gu Jin-Zhi Guo Xian-Kun Hou Xu Yang Bo Zhao Xing-Long Wu 《材料科学技术学报》2021,78(19):176-182
In recent years,sodium-ion batteries(SIBs)have been considered as one of the most promising alterna-tives to lithium-ion batteries(LIBs).Here,a new Na-super-ionic conductor(NASICON)cathode material NaFe2PO4(SO4)2 is successfully prepared through solid state method for SIBs.While the poor electronic conductivity of iron-based materials results in its poor rate and cycle performance.Then the electro-chemical is effectively promoting via Ca2+doping.Na0.84Ca0.08Fe2PO4(SO4)2 have achieved considerable electrochemical properties.The first discharge specific capacity is 121.6mAhg-1 at 25mAg-1 with the voltage platform(~3.1 V)corresponding to Fe2+/3+.After 100 cycles,the capacity retention is 55.1%.The excellent electrochemical performance is caused by some Na+is substituted by Ca2+and leading to the fast sodium kinetics,which is well proved by the powder X-ray diffraction pattern and well corresponding to the galvanostatic intermittent titration technique and cyclic voltammetry testing result(the diffusivity values are around at 10-12 cm2 s-1). 相似文献
10.
文章于2014年4月1日~4月30日在吉林师范大学对大气污染物PM10、NOX和SO2进行监测。采暖期,PM10、NOx和SO2的浓度分别为150.9μg/m3、46.4μg/m3和27.3μg/m3,虽没有超过空气质量标准,但是其数值都比非采暖期高。采暖期PM10浓度为非采暖期的1.6倍,NOx和SO2的浓度分别为非采暖期的1.3倍和1.8倍。无论是采暖期还是非采暖期,AQI指数与PM10浓度呈强相关性,说明PM10为四平市首要大气污染物。 相似文献