Synthesis and characterization of SrFeOx hetero-film resistance-switching device with low operation voltage

As a critical topological phase transition material, SrFeO_x could play an essential role in the field of resistive memory. How to implement resistance-switching more softly and ensure the stability of materials has always been a relevant research hotspot. Regulating the oxygen environment during the deposition process of the films can effectively control the stoichiometry of the functional layer and then improve the resistance-switching characteristics of the device. In this paper, a SrFeO_x hetero-film was prepared by oxygen pretreatment on the SrRuO₃ surface before SrFeO_x deposition, and the as-assembled micrometer-scale device exhibits a low set operating voltage of 0.6 V and favorable cycling characteristics. The SrFeO_x hetero-film reveals a vertical brownmillerite superlattice-like structure with ～20 nm perovskite buffer layer, which benefits the connection and rupture of conductive filament. Additionally, XPS and UV–vis were used to analyze the bonding energy and band gap of SrFeO_x hetero-film, and offers the experimental basis for the explanation of the conductive mechanism. Therefore, the device based on SrFeO_x hetero-film with low operation voltage provides a reference for low power consumption research on topological phase transition material.     

重整装置首次开工关键因素探讨

阐述了做好重整装置首次开工的几个关键因素：做好预处理开工工作，确保重整进料合格；做好重整催化剂的处理工作；把好重整进油后480℃温度关；遵守操作规程，平稳操作。     

The PAR(p) Interconfigurations model used by the Brazilian Electric Sector

This study discusses the characteristics of the Periodic Autoregressive model, PAR(p), which is used to generate synthetic series of inflow energies that serve as entries for computer platforms that implement the planning and expansion of the operations of the BES – the Brazilian Electric Sector (SEB – Sistema Elétrico Brasileiro). The methodology for the design of a generating plant is presented in addition to the fundamentals of the “PAR(p) Interconfigurations” Model, which is referred to as the Inflow Energy Generation Model (IEGM) in this study. The major contribution of this study is to provide the first scientific discussion of the representation of multiple configurations using the PAR(p) model. For this purpose, several topics related to the time series are discussed, such as the definition of the model order, the matter of stationarity and the need to address possible outliers. Finally, a case study is presented, wherein the results of the estimation and generation of the described model’s scenarios are demonstrated.     

The operation types and operation window for high-purity hydrogen production for the sorption enhanced steam methane reforming in a fixed-bed reactor

The operation types and operation window for high-purity H₂ production for the sorption enhanced steam methane reforming (SE-SMR) with Ni/Al₂O₃ catalyst and CaO sorbent in a fixed-bed reactor are investigated by an experimentally verified 2D numerical method. Four chemical reactions including steam reforming, water gas shift, global steam reforming, and CO₂ sorption are considered. The operation window is defined as the H₂ and CO molar fractions at outlet satisfying both y_H2,out ≥ 90% and y_CO,out ≤ y_CO,allow (= 1%, 2% or 3%) in dry base. Under the conditions of y_H2,out and y_CO,allow, there are six operation types, of which 2 types are within the operation window and 4 types are not within the operation window as the temperature, weight hourly space velocity (WHSV) and steam to methane (S/C) molar ratio vary. For a common case of S/C = 3, the operation windows for y_CO,allow = 3% at WHSV = 8.5 h^?1 and 42.5 h^?1 are located at 570–670 °C and 640–690 °C respectively, based on the parameters in this work. The operation window of temperature is wider with decreasing WHSV, and it becomes wider remarkably as the S/C ratio increases. The lowest temperature inside the operation window is 550 °C. The effects of the temperature, WHSV and S/C ratio on the operating types, y_H2,out and y_CO,out are also presented and discussed in details.     

Fast and stable operation approach of ship solid oxide fuel cell-gas turbine hybrid system under uncertain factors

This work focuses on investigating the adaptability of solid oxide fuel cell-gas turbine (SOFC-GT) hybrid system for ship application under uncertain factors. The effect of rapids, wind and waves on the performance of ship SOFC-GT is analyzed. In addition, a novel control system combining fuzzy logic theory, temperature feedforward and coordination factor on-line adjustment is proposed to address the problem of load disturbances caused by uncertain factors. The results show that the proposed operation strategy can shorten the thermal response time inside fuel cell stacks by almost 49.97%, meanwhile, reducing the maximum temperature changing rate at the electrochemically active tri-layer cell composed of anode, electrolyte, and cathode (PEN structure) by around 17.86%. Moreover, the reasonable matching between air flow and fuel flow is an essential prerequisite to ensure the safe and efficient operation of ship SOFC-GT. While the SOFC-GT is working at full load, the results indicate that the fuel to air ratio cannot exceed 2.56?10^?2 g/g. Finally, an application scenario of the 5000-ton river-to-sea cargo ship sails from Nanjing Port to Yangshan Port (Eastern China) is conducted to analyze the operation characteristics of ship SOFC-GT under uncertain factors. Two set of 1000 kW SOFC-GT systems with the electrical efficiency of 64.66% is designed for the target ship, the results conclude that the operation strategy of each SOFC-GT system supports 50% load is beneficial in reducing the power tracking time and SOFC temperature overshoot. The average electrical efficiency of 61.45% and 61.04% are achieved in winter and summer typical days respectively in the whole voyage.     

悬挂系统参数对轨交车辆运行平稳性的影响分析

介绍了轨交车辆悬挂系统的组成与作用,分析了轨交车辆运行平稳性及其指标。以某型轨交客车为研究对象,应用SIMPACK软件建立车辆动力学模型,分析悬挂系统参数对轨交车辆运行平稳性的影响。通过分析,得到空气弹簧刚度、阻尼系数及其它悬挂关键参数对轨交车辆运行平稳性的影响规律。     

设备检修作业指导书的编制

机电制修厂自开展设备检修业务以来，发展很快，但是由于专业检修人员少、青工多，导致职工技术素质及业务能力难以满足机修厂的快速发展，面对困难，该厂积极转变观念。探索通过设备作业指导书来保证、促进职工检修工作规范化、标准化，取得了令人满意的效果。下面根据机修厂的实践，简单介绍如何编制作业指导书，供同行参考。     

浅议地质灾害防治工程施工监理中的质量控制方法

中结合实例阐述了地质灾害防治工程施工监理中质量控制的关键是质量预控，工序控制是重要的质量控制方法。     

社区建筑

编者按:本期本栏发表的8篇中外专家论文,选自建筑与地域文化国际研讨会暨中国建筑学会2001年学术年会论文。全文详见年会论文集。今后本刊还将陆续选载部分年会论文。     

推进中国建筑师的职业化

中国建筑设计市场是巨大的,但又是极不规范的。中国建筑师的工作标准和行业规范也较模糊,职业素质和意识有待提高。为了建立完善规范的行业标准,推动中国建筑市场的良性运作,建筑师的职业化成为当今建筑设计市场的一大需求。