Mathematical modeling of falling liquid film evaporation process

A mathematical model of evaporation process from a laminar falling liquid film on a vertical plate of constant temperature is presented. The model is developed with and without interfacial shear stress due to the vapor flow at the liquid film surface. The vapor pressure drop, vapor exit velocity and cooling rate are calculated for different liquid mass flow values. It is shown that lower liquid mass flow produces higher cooling rate. The results also show that the interfacial shear stress has a considerable negative effect on the cooling rate. It is proved that there exists an optimum distance between the plates, which gives the maximum volumetric cooling rate.     

Modification of poly(N-vinyl-carbazole) thin films by bromine doping

Poly(N-vinyl-carbazole) (PVK) thin films doped with bromine has been studied by scanning electron microscopy, X-ray diffraction, infrared absorption, X-ray photoelectron spectroscopy (XPS), electron spin resonance (ESR), optical transmission (visible, near ultra violet) and conductivity measurements. The polymer has been doped at room temperature and at 373 K. It is shown by ESR, XPS and optical measurements that a charge transfer complex (CT-complex) is formed between PVK and Br. However, if some bromine acts as dopant of the polymer there is another bromine contribution, which corresponds to bromine covalently bonded to PVK and some only adsorbed. It is also shown by ESR that there is not only polymer doping by bromine but also some partial polymer degradation. Therefore, it can be said that the optimum doping condition of PVK thin films with bromine has been shown to be room temperature post-doping.     

Measurement of Activity Coefficients from Unsteady State Evaporation and Growth of Microdroplets

Techniques are presented for determination of activity coefficients of binary systems from unsteady state evaporation and growth of single microdroplets in controlled environments. A high-precision light scattering method based on resonances observed in light scattering by microdroplets was used to determine the size and composition of a microdroplet as functions of time. The techniques were validated through data on growth of glycerol microdroplets in slowly developing water vapor concentration fields and evaporation of microdroplets, containing volatile dimethylphthalate (DMP) and nonvolatile dioctylphthalate (DOP), in vapor-free atmospheres. When the water vapor concentration in the surrounding gas changes slowly a glycerol droplet maintains a dynamic equilibrium with the water vapor; thus the activity coefficient of water was determined from knowledge of the droplet composition and the water vapor saturation ratio in the gas phase. The activity coefficients of DMP were determined on the basis that the instantaneous evaporation rate of a DMP-DOP microdroplet in a vapor-free atmosphere is equal to the product of the activity of DMP and the evaporation rate of a pure DMP droplet. The activity coefficient values obtained from microdroplet experiments are highly reproducible and agree with data available in the literature.     

EVAPORATION FROM POROUS MEDIA: A CAPILLARY MODEL OF A PENETRATING FRONT

A capillary tube model was solved to investigate the influence of mass transfer coefficient, temperature, and front depth on the evaporation rate during the penetrating-front period of water-filled porous media dried in hot air. The results show that increasing the flow rate of the drying air is not so efficient as increasing the sample temperature. Due to attenuating diffusion rate, the rate of liquid front migration decreases with time. The calculations explain the falling rate period behavior of sandstone heated at 121°C. Trends depicted by the model may be useful for the design of heating conditions for drying processes.     

APPLICATION OF LINEARIZED MODELS OF MULTICOMPONENT MASS TRANSFER FOR CALCULATION OF EVAPORATION-CONDENSATION PROCESS IN TERNARY SYSTEMS

Results of calculations based on a linearized multicomponent mass transfer theory developed by Burghardt and Krupiczka are compared with experimental data of Modine for condensation-evaporation process in ternary systems. These data have been obtained for acetone-benzene-nitrogen and acetone-benzene-helium in a welted wall column. Models I and II, which take into account diffusional interactions of components in a mullicomponent mixture show good agreement with the experiments as well as with other calculation methods (Krishna-Standart and Toor-Stewart-Prober). When multicomponent mass transfer occurs in the presence of inert species, a straightforward Model II is recommended. Model I, which is more universal, requires some iterative calculations with respect to the sum of mass fluxes. According to theoretical considerations the latter model is limited to the case of low total mass flux. The results of calculations for the systems studied were reasonably good though the total mass fluxes were not small. The calculation procedure based on the presented linearized models are convergent to the proper solutions in contrast to the Krishna-Standart Model IV which in some cases can be unstable.     

Population balance modeling of bubble size distributions in a direct-contact evaporator using a sparger model

The study of bubble size distributions in direct-contact evaporators was addressed both theoretically and experimentally. Recently developed models for calculating bubble coalescence and breakage frequencies in isothermal bubble columns were adapted to the population balance equation using the bubble mass as the internal coordinate which was discretized using an expansion of the number density function by impulse functions. A sparger model was developed based on experimental data for a non-coalescing system and using bubble formation models for isothermal and non-isothermal conditions. Bubble size distributions in a direct-contact evaporator operating in the quasi-steady-state regime for four different gas superficial velocities, including the homogeneous and heterogeneous regimes, together with the sparger model, were used for estimating the three empirical parameters from the population balance model, which were observed to be functions of the gas superficial velocity. In all cases considered, the population balance model fitted the experimental data rather well and the regressed parameters exhibit the physically expected behavior with changes in the gas superficial velocity.     

燃煤火力电厂脱硫废水零排放可行性研究

燃煤电厂脱硫废水因高含盐量、成分复杂、高腐蚀性、回用困难的特点成为制约燃煤电厂废水零排放的关键因素。三种脱硫废水零排放可行性技术方案,通过对比工艺流程、经济指标和占地因素等指标,发现熟石灰、碳酸钠两级软化＋卧式MVC蒸发浓缩＋卧式MVC蒸发结晶是最优方案,可获得高品质工业盐再利用,作为未来基建项目脱硫废水零排放系统工艺方案。     

Evaporation from Lake Superior: 1. Physical controls and processes

The surface energy balance of Lake Superior was measured using the eddy covariance method at a remote, offshore site at 0.5-h intervals from June 2008 through November 2010. Pronounced seasonal patterns in the surface energy balance were observed, with a five-month delay between maximum summer net radiation and maximum winter latent and sensible heat fluxes. Late season (winter) evaporation and sensible heat losses from the lake typically occurred in two- to three-day-long events, and were associated with significant release of stored heat from the lake. The majority of the evaporative heat loss (70-88%) and sensible heat loss (97-99%) occurred between October and March, with 464 mm (2008-2009) and 645 mm (2009-2010) of evaporative water loss occurring over the water year starting October 1. Evaporation was proportional to the horizontal wind speed, inversely proportional to the ambient vapor pressure, and was well described by the ratio of wind speed to vapor pressure. This ratio remained relatively constant between the two water years, so the differences in evaporative water loss between years were largely associated with differences in lake surface conditions (e.g. water temperature, ice cover, and ice duration). Since late-season water temperature decline is driven by evaporative and sensible heat loss, the potential for a negative feedback mechanism between evaporation and ice cover is discussed.     

基于三(8-羟基喹啉)铝的紫外增强薄膜研究

为了提高硅基成像器件的紫外响应,本文通过对Alq3发光机理与光致发光特性的研究,用真空蒸镀的方法制备出了基于Alq3的有机金属薄膜.通过测量Alq3薄膜的透过率、光致发光光谱和激发光谱,发现Alq3薄膜在可见波段有很好的透过性,用紫外光激发会产生较强的绿光(中心波长位于510 nm),且激发光谱宽(250～425 nm).结论表明Alq3薄膜的发射光谱能够与传统硅基成像器件的响应光谱匹配,是一种符合实际要求的紫外增强薄膜.     

An improved algorithm for disaggregating microwave-derived soil moisture based on red, near-infrared and thermal-infrared data

Accurate high-resolution soil moisture data are needed for a range of agricultural and hydrologic activities. To improve the spatial resolution of ∼ 40 km resolution passive microwave-derived soil moisture, a methodology based on 1 km resolution MODIS (MODerate resolution Imaging Spectroradiometer) red, near-infrared and thermal-infrared data has been implemented at 4 km resolution. The three components of that method are (i) fractional vegetation cover, (ii) soil evaporative efficiency (defined as the ratio of actual to potential evaporation) and (iii) a downscaling relationship. In this paper, 36 different disaggregation algorithms are built from 3 fractional vegetation cover formulations, 3 soil evaporative efficiency models, and 4 downscaling relationships. All algorithms differ with regard to the representation of the nonlinear relationship between microwave-derived soil moisture and optical-derived soil evaporative efficiency. Airborne L-band data collected over an Australian agricultural area are used to both generate ∼ 40 km resolution microwave pixels and verify disaggregation results at 4 km resolution. Among the 36 disaggregation algorithms, one is identified as being more robust (insensitive to soil, vegetation and atmospheric variables) than the others with a mean slope between MODIS-disaggregated and L-band derived soil moisture of 0.94. The robustness of that algorithm is notably assessed by comparing the disaggregation results obtained using composited (averaged) Terra and Aqua MODIS data, and using data from Terra and Aqua separately. The error on disaggregated soil moisture is systematically reduced by compositing daily Terra and Aqua data with an error of 0.012 vol./vol.